MSE/ECE 310 MSE/ECE 310 Phonons Phonons Longitudinal Lattice Wave (phonon) Phonon Dispersion Relation for a monatomic lattice vg = s+p = specific plane us+p = displacement Knowlton ∂ω = 0 at the Brillouin zone boundaries. ∂k p = whole number Kittel, Introduction to Solid State Physics, 6th Ed (Wiley, 1986) Ch. 4 1 Knowlton Kittel, Introduction to Solid State Physics, 6th Ed (Wiley, 1986) Ch. 4 2 1 MSE/ECE 310 MSE/ECE 310 Phonons Phonons Phonon Dispersion Relation for Diatomic Linear Lattice 1 ⎡ ⎛ 1 1 ⎞⎤ 2 ⎢ 2c ⎜ + ⎟⎥ m m 2 ⎠⎦ ⎣ ⎝ 1 2c m2 2c m1 − π π a a McKelvey, Solid State Physics for Engineering & Materials Science, (Krieger, 1993) Ch. 3 Knowlton Kittel, Introduction to Solid State Physics, 6th Ed (Wiley, 1986) Ch. 4 3 Knowlton 4 2 MSE/ECE 310 MSE/ECE 310 Phonons Phonons u k u & k Are perpendicular for a transverse phonon Blakemore, Solid State Physics, 2nd Ed (Cambridge, 1985) Ch. 2 Whether a vibrational mode is longitudinal or transverse, a given atomic amplitude of motion requires much more energy for a long wave optical than acoustic mode. Why? B/c optical modes minimize changes in 2nd n.n. separation by maximizing separation between n.n.’s. N.n. interaction greater than any other n.n. interaction, therefore, energy required for n.n. separation greater than any other separation. Knowlton U = dF/dx integrate under curves to get energy. 5 Knowlton 6 3 MSE/ECE 310 MSE/ECE 310 Phonons Dispersion Curves Phonons P.Y. Yu & M. Cardona, Fundamentals of Semiconductors, (Springer, 1996) Ch. 3 Knowlton Blakemore, Solid State Physics, 2nd Ed (Cambridge, 1985) Ch. 2 7 Knowlton 8 4 MSE/ECE 310 MSE/ECE 310 Phonon Imaging Phonons Phonon Transmission study: Phonon Combination Bands (two phonon overtone bands) 9 65% transmission of ballistic phonons fast transverse <111> slow transverse <110> unbonded border side between top & bottom unbonded side Blakemore, Solid State Physics, 2nd Ed (Cambridge, 1985) Ch. 2 Dark Matter Detector Sensing Phonon Using Ge:Au:Ge Eutectic Bonding Knowlton 9 Knowlton 10 5 MSE/ECE 310 MSE/ECE 310 Phonon Imaging Phonon Imaging Phonon Transmission study: Phonon Transmission study: 9 Sample configuration 9 Time of flight 2750 Integration: FTA Spectrum - Side Without Interface Area Peak at Width Height 377.64547 1.57617 0.21094 1269 2500 Ballistic 900μm Integration: FTA Spectrum - Side With Interface Area Peak at Width Height 693.59764 1.49414 0.19922 2515 2000 1750 % Phonon Transmission = Area1/Area2 x 100 = 55% 1500 Laser Pulse 3mm 4mm Transition Edge Detector Phonon PhononImage ImageSide Side 380μm E In utec te ti rfa c ce Bolometer Intensity (arbitrary units) 2250 1250 1000 FTA TOF - No Bond (A1) FTA TOF - With Bond (B1) 750 500 250 0 -250 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 Time (μs) • • • • Laser LaserPulse PulseScan ScanSide Side Dark Matter Detector Sensing Phonon Using Ge:Au:Ge Eutectic Bonding Knowlton 11 Knowlton Fast tranverse optical phonon Slow transverse optical phonon If we examine TOF data from phonon imaging study Notice that time at peak max is no more than 1 μs Dark Matter Detector Sensing Phonon Using Ge:Au:Ge Eutectic Bonding 12 6 MSE/ECE 310 MSE/ECE 310 Phonon Imaging Phonons – Local Vibrational Modes Phonon Transmission study: Si 9 Prototype Dark Matter Detector 9 Really a phonon detector Oi O interstitial Si [111] Si Si Si Energy (meV) 62 100 150 200 250 300 350 400 450 496 λ (μm) 20 15 10 5 2.5 4000 Transmittance (arb. units) 6000 Transmittance (arb. units) 5000 4000 3500 3000 2500 2000 1100 1110 1120 1130 1140 1150 1160 1170 3000 2000 1000 1136.4 cm -1 0 Knowlton Dark Matter Detector Sensing Phonon Using Ge:Au:Ge Eutectic Bonding 500 Knowlton LVM of O 13 Knowlton 1000 1500 2000 2500 -1 3000 3500 4000 Wave Number (cm ) Knowlton, U.C. Berkeley, ~1995 14 7