Odour/VOC Removal Filters Frequently Asked Questions Q1: What are Volatile Organic Compounds (VOCs)? VOCs refer to a class of organic chemical compounds that have significant vapour pressures (volatile) at room temperature (vapour pressures greater than 0.07 kPa). Many contain oxygen, nitrogen, sulphur or halogen atoms. Due to the different physical and chemical properties of the individual VOCs, they are affected in varying degrees by VOC destruction techniques. In general, the main factors in selecting the right treatment technology are: • The VOC and its physical and chemical properties • The volume/concentration of the contaminants • Presence of other contaminants Q2: What are tricresyl phosphates (TCPs)? The TCPs are organophoshate compounds. They are present as anti-wear additives in certain formulations of aircraft turbine engine oils and some aircraft hydraulic fluids, which typically contain 1 to 5 % TCP by weight. (ref: ASHRAE Guideline 28 “Air Quality within Commercial Aircraft”) Although the ortho isomer of TCP, tri-ortho-cresyl phosphate (TOCP), has often been studied in the past, there are a total of 10 different isomers. Q3: Do carbon filters remove odours/VOCs? CH3 CH3 O O P O O CH3 For aircraft cabin air, and other industrial transport systems, gaseous removal is typically performed using adsorption devices. A popular adsorbent is activated charcoal, which has a high internal surface area, and the pollutant molecules attach to active sites on these internal surfaces. It is effective at removing VOCs associated with engine oil/oil degradation. The Pall carbon adsorbent is effective at adsorbing volatile organic compounds. Test results have shown a removal efficiency of 65-73 % when challenged with TCPs in the gaseous phase at the Fraunhofer Institute in Germany in 2010. The Pall carbon adsorbent has an initial removal efficiency of >80 % with toluene (ISO11155-2). Toluene is the standard challenge in laboratory testing of adsorbents Q4: Do carbon filters only remove the smell and not remove the associated harmful chemicals? The Pall carbon adsorbent is effective at adsorbing VOCs. Where harmful chemical compounds exhibit detectable odours, removal of these compounds from the cabin air by adsorption on to carbon based filters will, of course, eliminate the smell. Q5: Do carbon filters remove ozone, carbon monoxide (CO) and carbon dioxide (CO2 )? Carbon adsorbents have some effectiveness with ozone but not with carbon monoxide and carbon dioxide. FAR 25.831 specifies the maximum allowable levels of CO and CO2. These have been monitored in other air sampling programmes and have been found to be within acceptable levels. (ref EN 4618:2009 “Aircraft internal air quality standards, criteria and determination methods”). Q6: Do High Efficiency Particulate Air (HEPA) filters remove TCPs? HEPA filters are designed to remove particulate, not gaseous, contamination. Although TCP vapours will not be removed, aerosolized droplets can be adsorbed on the HEPA filter media and therefore used cabin air filters (and other aircraft surfaces) may contain small residue of TCPs. Note: HEPA filters are usually rated at 99.99% sodium flame test efficiency or the equivalent 99.97% D.O.P. (Di-Octyl Phthalate) efficiency. According to ASHRAE Standard 161-2007 “HEPA filters….. shall meet or exceed the requirements of Institute of Environmental Science and Technology IEST-RP-CC007.2 Filter Type "A," or MERV 17 or H13 according to EN 1822-1, and shall provide a minimum of 99.97% collection efficiency for 0.3 micron particles”. Q7: Where are the filters fitted in the environmental control system (ECS)? In a typical commercial aircraft, the air supplied into the main cabin consists of approximately 50% outside air from either the engine’s compressor stage (engine ‘bleed air’) or the Auxiliary Power Unit (APU), which is mixed with approximately 50% of filtered, recirculated air. (Note however, that some aircraft designs are now moving to ‘bleed air free’ ECS). The cabin air filters are located in the recirculation loop and these can be either HEPA filters or combined HEPA/Carbon filters. However, some particulate contamination, odour causing compounds and VOCs and semi-volatile organic compounds (SVOCs) may enter from the outside air system where filtration is not normally provided. The air supplied to the cockpit can come from a number of sources (e.g outside air from the engine or APU or a combination of outside air and recirculated air from the mixing chamber) and the supply is dependant on the aircraft ECS configuration. Q8: What is the recommended filter element change-out interval? There is no definitive time interval for replacing a HEPA filter or an odour removal filter element. The time interval varies between aircraft types and between aircraft systems. Pall will work with the airlines and the aircraft manufacturers to determine the optimum service interval for the specific operating environment. Q9: Which aircraft are fitted with odour/VOC filters? At present, Pall has designed combined HEPA/Carbon filters as an option on the Airbus A320 family and Airbus A330/A340 family where they are fully inter-changeable with the existing particulate HEPA cabin air filter elements. Pall is also carrying out an in-service evaluation of a combined Particulate/Carbon filter on a commercial aircraft where it is designed to filter the cockpit supply air. Q10: Is there a danger to the maintenance personnel by removing used odour removal filters? There is no more risk involved in replacing a used HEPA or carbon filter than carrying out general maintenance on any aircraft part that has been in service for a number of years. Maintenance staff who may be concerned about the general accumulation of dust and debris on cabin air filters should wear the same personal protective equipment as for other similar aircraft maintenance tasks. Pall Aeropower Visit us on the Web at www.pall.com/areospace 10540 Ridge Road New Port Richey, FL 34654 +1 727 849 9999 telephone +1 800 933 3111 toll free US Pall Corporation has offices and plants throughout the world. For Pall representatives in your area, please go to www.pall.com/contact Portsmouth - UK +44 (0)23 9230 2399 telephone +44 (0)23 9230 2203 fax areospace@pall.com Because of technological developments related to the products, systems, and/or services described herein, the data and procedures are subject to change without notice. Please consult your Pall representative or visit www.pall.com to verify that this information remains valid. © Copyright 2011, Pall Corporation. Pall and are trademarks of Pall Corporation. ® Indicates a trademark registered in the USA. Filtration. Separation. Solution.SM is a service mark of Pall Corporation. AEOVOCEN Printed in the UK. January 2011