Wayland Baptist University _________ Campus School of Mathematics and Sciences WAYLAND MISSION STATEMENT: Wayland Baptist University exists to educate students in an academically challenging, learning-focused and distinctively Christian environment for professional success and service to God and humankind. COURSE NO. AND TITLE: CHEM 3404-section; Organic Chemistry II TERM: NAME OF INSTRUCTOR: OFFICE PHONE NO. AND WBU EMAIL ADDRESS: OFFICE HOURS, BUILDING, AND LOCATION: Students are encouraged to call or stop by the office any time the instructor is available, including non-posted office hours. CLASS MEETING TIME AND LOCATION: COURSE DESCRIPTION: Continuation of CHEM 3403; emphasizes study in interpretive spectroscopy and in the synthesis, reaction mechanisms and reactions of the common functional groups and their derivatives; laboratory introduces organic qualitative analysis and continues the synthesis of organic compounds. Lecture three hours, laboratory three hours. $90 fee. PREREQUISITES: CHEM 3403 – Organic Chemistry I REQUIRED RESOURCES: John McMurry, Organic Chemistry, 8th ed. (2012) Thompson Learning Brooks/Cole, Belmont, CA. *or choose from the official booklist COURSE OUTCOME COMPETENCIES: At the conclusion of the course, the student should be able to: 1) Name and describe the role of important individuals and events in the history of organic chemistry. 2) Define, describe and identify the various terms, symbols and formulas common to organic chemistry. 3) Recognize and draw the structures (Lewis dot structures, condensed formulas, line-bond structures, skeleton structures, projections) of the various compounds and functional groups studied. 4) Recognize and name by appropriate IUPAC nomenclature and/or common name the various compounds and functional groups studied. 5) Describe the types of chemical bonding present in organic compounds and the impact of these bonds on molecular structure. 6) Utilize the basic principles of valence bond theory and molecular orbital theory to predict molecular shape, bond angles, molecular polarity and other molecular properties. 7) Estimate the relative boiling points, acidity, basicity, polarity, and physical properties of compounds from the various classes of compounds studied. 8) Utilize basic principles of thermodynamics and chemical kinetics to evaluate changes in entropy, enthalpy, free energy and reaction rate. 9) Draw and interpret progress of reaction diagrams for the common organic reactions. 10) Describe, write appropriate chemical equations and employ reaction mechanisms to show methods for the synthesis of the different classes of compounds studied. 11) Describe, write appropriate chemical equations and employ reaction mechanisms to deduce the major products in the reactions of the compounds studied. 12) Identify, define and employ the basic terms, symbols and concepts of optical activity. 13) Use spectral data to identify structures and aid in the identification of compounds studied. 14) Distinguish among the classes of compounds studied by means of simple chemical tests and derivatives. 15) Identify, setup and safely utilize the laboratory equipment and instrumentation common to organic chemistry. 16) Conduct basic organic chemistry laboratory procedures following laboratory safety guidelines, material safety data sheets and local, state and federal regulations related to the use and disposal of chemicals, reagents and hazardous chemical waste. 17) Collect, record, interpret and properly report experimental data. 18) Recognize and utilize fundamental principles of organic chemistry applicable to other areas of chemistry, biology and everyday life. ATTENDANCE REQUIREMENTS: “The University expects students to make class attendance a priority.” 1. Participation in University sponsored events is an excused absence. Other absences MAY be excused at the discretion of the instructor. 2. ALL absences (including for University sponsored events) must be discussed with the instructor BEFORE the absence or they will be unexcused. 3. If an exam or laboratory work is missed due to an excused absence, it must be made-up within a week of the scheduled date. Unexcused absences from exams or laboratory can NOT be made-up and a grade of 0% will be recorded for that exam. 4. Lab write-ups are considered to be a part of the scheduled lab time and are due before the next assigned laboratory exercise is begun. 5. If a student misses 25% of lecture classes or laboratories the student may be dropped from the class. STATEMENT ON PLAGIARISM AND ACADEMIC DISHONESTY: Wayland Baptist University observes a zero tolerance policy regarding academic dishonesty. Per university policy as described in the academic catalog, all cases of academic dishonesty will be reported and second offenses will result in suspension from the university. DISABILITY STATEMENT: In compliance with the Americans with Disabilities Act of 1990 (ADA), it is the policy of Wayland Baptist University that no otherwise qualified person with a disability be excluded from participation in, be denied the benefits of, or be subject to discrimination under any educational program or activity in the university. The Coordinator of Counseling Services serves as the coordinator of students with a disability and should be contacted concerning accommodation requests at (806) 291-3765. Documentation of a disability must accompany any request for accommodations. It is the responsibility of the student to inform the instructor of any disability that may require accommodation during the lecture or laboratory portions of the course. It is of particular importance to report any condition or disability that may affect the laboratory safety of the individual or others. Information provided for this purpose will be kept strictly confidential and will not in any way affect the individual’s course grade. COURSE REQUIREMENTS AND GRADING CRITERIA: 1. Four hour exams (40%). Hour exams will cover assigned reading and homework problems. 2. Homework (25%). Problems will be assigned for each topic covered. Problems will be collected at announced due dates, graded and returned. Late homework will not be accepted. Reading the textbook and completion of homework assignments will be required for success on the exams. Homework problems will be posted on the course Blackboard site. 3. Comprehensive final exam (15%). 4. Laboratory (20%). Laboratory work will consist of laboratory exercises, experiments, a chemical literature assignment, and laboratory reports. Unless otherwise announced, completed laboratory reports will generally be due at the beginning of the next regularly scheduled lab period. 5. Abiding by laboratory safety guidelines at all times. Failure to do so may result in dismissal from the lab and subsequent reduction in course grade. 6. All assignments turned in late will be penalized at a rate of 20% per school day. Hour Exams (HE) (4 @ 10% each) Homework (HW) Laboratory (LB) Lab Reports – 18% Literature Assignment – 2% Final Exam (FE) Final Grade COURSE EVALUATION: A 90-100% B 80-89% C 70-79% D 60-69% F 0-60% W Withdrawal I Incomplete* *An incomplete may be given within the last two weeks of the semester to a student who is passing but has not completed required work for reasons beyond the student’s control. The incomplete will be removed only if the required work is completed by the date during the next academic term given in the academic catalogue. Failure to complete the work by this date will result in the grade of F. Students shall have protection through orderly procedures against prejudices or capricious academic evaluation. A student who believes that he or she has not been held to realistic academic standards, just evaluation procedures, or appropriate grading, may appeal the final grade given in the course by using the student grade appeal process described in the Academic Catalog. Appeals may not be made for advanced placement examinations or course bypass examinations. Appeals are limited to the final course grade, which may be upheld, raised, or lowered at any stage of the appeal process. Any recommendation to lower a course grade must be submitted through the Executive Vice President/Provost to the Faculty Assembly Grade Appeals Committee for review and approval. The Faculty Assembly Grade Appeals Committee may instruct that the course grade be upheld, raised, or lowered to a more proper evaluation. TENTATIVE COURSE OUTLINE: TENTATIVE DATES CHAPTER SECTIONS MAJOR TOPICS 12 12.1-12.8 Mass Spectroscopy Infrared Spectroscopy 13 13.1-13.13 NMR Spectroscopy CMR Spectroscopy MAJOR TEST #1 14 14.1-14.9 Conjugated Dienes Diels-Alder Reaction U.V. Spectroscopy Benzene Aromaticity and Hückel Rule 15 15.1-15.8 16 16.1-16.11 Electrophilic Aromatic Substitution MAJOR TEST #2 17 17.1-17.11 Alcohols and Phenols 18 18.1-18.9 Ethers, Epoxides, Sulfides and Thiols 19 19.1-19.114 Aldehydes and Ketones MAJOR TEST #3 20 20.1-20.8 Carboxylic Acids and Nitriles 21 21.1-21.10 Derivative of Carboxylic Acids 22 22.1-22.7 Carbonyl Alpha-Substitution 23 23.1-23.13 Carbonyl Condensations MAJOR TEST #4 24 24.1-24.10 Amines FINAL EXAM LABORATORY EXPERIMENT/EXERCISE CAI* - Mass Spectroscopy/ Infrared Spectroscopy CAI* - Infrared Spectroscopy/ NMR/CMR Spectroscopy CAI* - NMR/CMR Spectroscopy Nitration of Methyl Benzoate Hydrolysis of Methyl m-Nitrobenzoate Alcohols Aldehydes and Ketones Synthesis of Cyclohexanone Keq for Esterification Amines CAI* - Qualitative Organic Analysis Qualitative Organic Analysis Qualitative Organic Analysis (continued) *CAI = Computer-assisted instruction TENTATIVE DATE ADDITIONAL INFORMATION: optional ACADEMIC HONESTY: “University students are required to conduct themselves according to the highest standards of academic honesty.” Any student guilty of cheating or other forms of academic dishonesty will be penalized at the instructor’s discretion by one or more of the following: 1. Assigning a grade of F (0%) to the work in question. 2. Assigning a grade of F for the entire course. 3. Recommendation for more severe punishment; including probation, suspension, or expulsion from the University (see student handbook for further information). Revised 03/18/15