Modeling and Development of Piezoceramic Energy Harvester for Munitions Applications A Thesis Presented to the Faculty of the Department of Electrical Engineering Villanova University In Partial Fulfillment of the Requirements for the Degree of Master of Electrical Engineering by Sean Ryan Pearson 19 April, 2006 Under the Direction of Dr. Pritpal Singh ii Student’s Full Name ___Sean Pearson________________________________________ Department __Electrical and Computer Engineering_______________ _____ Full Title of Thesis ________________________________________________________ Modeling and Development of Piezoceramic Energy Harvester for Munitions Applications Date Submitted _____April_____________2006_______ __________________ ___________________________________________________ Faculty Advisor Date __________________________________________________ Chairperson of the Department Date __________________________________________________ Dean of Engineering Date A copy of the thesis is available for research purpose at Falvey Memorial Library. ___________________________________________ Student Signature Date Date ____________ iii THESIS SUBMITTED Name ___Sean Pearson___________________________________________________ Department _Electrical and Computer Engineering_______________________ Title of Thesis Modeling and Development of Piezoceramic Energy Harvester for Munitions Applications Approved by Advisor ______________________________________________________ Name Signature Date Approved by Chairperson __________________________________________________ Name Signature Date Approved by Dean _______________________________________________________ Name Signature Date iv Table of Contents • Abstract • Introduction • Piezoelectric Theory o Physics of Piezoelectricity • Piezoelectric Materials o Crystalline Materials o Piezoelectric Ceramics o Piezoelectric Material Comparison • Previous Work • Experimental Test Materials o Advanced Cerametrics Incorporated o Omnitek Incorporated • Resonator System o Introduction o Derivation of Mechanical Model o First Generation Model – Development o First Generation Model – Initial Testing o Second Generation Model – Development o Determination of Damping Constant o MATLAB Simulink Implementation o Time-Domain System Conversion o Generating The Model o Model Verification • Piezoelectric System o Piezoelectric Device Models o Deriving the Voltage Source Model o Using the Model o Model Verification • Simulink System o Model Derivation • PSpice Model o PSpice Simulations • Model Usage and Application o Using the Model • Experimental Results and Discussion o Test Procedure o Results • Conclusions • Suggestions for Further Work • References • Appendix 1 – CMA-R Type 3 Datasheet • Appendix 2 – PZT type 5a Datasheet • Appendix 3 – PZT type 8 Datasheet • Appendix 4 – Simulink Model v 01 02 06 06 18 20 20 21 25 30 30 33 35 35 35 37 38 38 39 41 41 42 43 44 45 45 47 48 51 51 56 56 58 58 68 68 73 85 85 87 91 93 94 95 1 Abstract The electronic missile guidance, communication and sensing system mounted on a munition round needs to be powered up till the missile is guided correctly to the target. Presently, chemical batteries are used to provide the electrical energy to the on-board electronics. However these batteries are bulky and their operation is unreliable under high-acceleration environments. In addition, they are prone to leakage when subjected to extended to storage periods, rendering the armament inert. Alternate sources of energy like Radio Frequency (RF) power and Piezoelectric power are being proposed for this purpose. In this project the power is derived by harvesting the energy available from Piezoelectric sources, instead of relying on the bulky batteries for the electrical energy. This system does not need any external source of energy to drive the circuitry and hence is a self-sustained system. This project’s goal is to examine the properties of piezoelectric materials, and to develop a system that will allow a designer to use these devices in the energy harvester. The main goal is to allow simulation of the devices, with the capability to connect circuitry to the material and evaluate performance. The results of this research will be presented 2 Introduction and Background The electronic missile guidance, communication and sensing system mounted on a munition round needs to be powered up till the missile is guided correctly to the target. Presently, chemical batteries are used to provide the electrical energy to the on-board electronics. However these batteries are bulky and their operation is unreliable under high-acceleration environments. In addition, they are prone to leakage when subjected to extended to storage periods, rendering the armament inert. Alternate sources of energy like Radio Frequency (RF) power and Piezoelectric power are being proposed for this purpose. In this project the power is derived by harvesting the energy available from different sources, instead of relying on the bulky batteries for the electrical energy. Prior to the launch a RF source transmits RF power using a hornantenna. RF power is converted into electrical power by the RF-power harvester (antenna and subsystem) mounted on the munition and supplies it to the onboard electronics. After the launch, the vibration energy of the munition is harnessed and a piezoelectric transducer is used to convert the vibrational energy to electrical energy. Electrical power from this source is used as long as the munition is accelerating. During flight, the vibrations experienced are also harnessed, providing more power for the munition. Once the munition reaches apogee, final calculations for the position, velocity and direction to reach the target are done and a thermal battery is activated. The power from the thermal battery is used to fire actuators to adjust the final trajectory. This system does not need any external source of energy to drive the circuitry and hence is a self- 3 sustained system. This project’s goal is to examine the properties of piezoelectric materials, and to develop a system that will allow a designer to use these devices in the energy harvester. The main goal is to allow simulation of the devices, with the capability to connect circuitry to the material and evaluate performance. Piezoelectric materials operate as transducers, allowing for energy transfer between mechanical and electrical energy sources in a predictable method. These materials can be found naturally, but are also man-made. There are two main modes of operation for these devices. The first mode of operation, known as the Direct Piezoelectric Effect, is where a mechanical loading of the material leads to the creation of an electric field. The second mode of operation, known as the Converse Piezoelectric Effect, is where the application of an electric field leads to a mechanical deformation of the material. For an energy harvester project, the materials will be used in the Direct Effect, with the goal of converting the mechanical energy of the firing of the round to electrical energy which can be easily used or stored. Piezoelectric Materials There are two main types of material which exhibit piezoelectric properties, Quartz, and Piezoceramics. Quartz occurs naturally, but can be expensive to harvest, and has limitations in which ways it may be used. Piezoceramics are more versatile in their usage and can be shaped to specific geometries, however they experience some limitations in what environments they may be used. 4 A good piezoelectric material will exhibit certain properties. It will have a high piezoelectric constant, which is a measure of the correlation between mechanical and electrical output. It will show a high electro-mechanical coupling coefficient. This coefficient measures how efficiently the material transfers mechanical energy to electrical energy, or vice versa. A good value for the electro-mechanical coupling coefficient is greater than .65. Finally, the third measure of a piezoelectric material is the Curie Temperature. This temperature is the thermal point where the material will loose all of its piezoelectric properties. If a material has a low Curie Temperature, its thermal operating range will be very limited. Simulation Tools The goal of this research is to develop a design tool for piezoelectric materials. The first task was to examine the problem. Piezoelectric materials have two distinct sides, the first being the mechanical side, the second being the electrical side. Any accurate simulation of the materials would have to incorporate both sides of the problem. To solve this problem, certain simulation tools were utilized. The first tool used was MATLAB®, with the Simulink package. This software was used to simulate the mechanical side of the piezoelectric material, along with a resonator used in one of the materials. Simulink also was used to simulate the internal voltage generation of the piezoelectric material. To complete the electrical simulation of the materials, an equivalent circuit model was used along with ORCAD PSpice. The output from MATLAB was imported into PSpice, and the electrical simulations were 5 completed. Together these two software packages give a complete simulator for a piezoelectric material. Material Testing Accurate testing methods were critical to this project. The linearity of the output in these materials needed to be verified, and test data needed to be generated to verify the accuracy of the model. Certain difficulties in developing test methods needed to be developed. The first challenge was in determining how to excite the materials. Some materials needed to be compressed, while others needed to be set into oscillation. In addition, all materials needed to be tested in an environment similar to that of the gun barrel. High-g test methods that replicated the acceleration curve of a gun firing were also developed. The materials were tested in various ways, using both high-g impact tests, and low-g steady state tests. The steady state tests used a variable frequency shaker table to excite the material, allowing for continuous testing of electronics such as DC to DC voltage converters. This testing method also allowed peak power transfer testing of the material to determine the optimal loading. The highg impact tests were used to simulate the high accelerations experience during a gun firing. This is useful in verifying material survivability and also output at higher accelerations. To replicate the gun firing acceleration curve more accurately, a cushion was developed to be used in the high-g test. This cushion accurately replicates the acceleration curve of the gun-firing, with a lower peak acceleration amplitude. 6 Piezoelectric Theory History of Piezoelectricity Curiosity about the piezoelectric effect dates back thousands of years. It was first noticed in rocks which would repel other rocks when they were heated. These rocks, which were actually Tourmaline crystals, eventually found their way into Europe. Once the crystals arrived in Europe, they were scrutinized by the scientists of the day. In the mid 1700’s, this effect was given the name of Pyroelectricity, which means electricity by heat [1]. Further examination of the Pyroelectric crystals led to the discovery of Piezoelectricity. Pierre and Jacques Curie were the first to discover the direct piezoelectric effect. This title means the correlation between input mechanical force and output electrical energy. They first published their research results on August 2, 1880 [2]. The converse piezoelectric effect, which means mechanical deformation by application of an electric field, was predicted in 1881 [3]. The first applications of piezoelectricity were in the area of sonar, where quartz plates were used to emit high frequency waves, on the order of 50 kHz. These waves would bounce off an object and return to a receiver, indicating to the operator the presence of an object below the surface of a body of water. Today, major applications of piezoelectric materials are in sensors, where their linear response makes them ideal for making mechanical measurements. Some examples of piezoelectric sensors are acceleration transducers made by several companies including PCB Piezotronics and Bruel and Kjaer, amongst others. A growing field for these devices is in actuators, where piezoelectrics are used to cause a 7 mechanical movement [1]. One such application is the use of piezoelectric actuators for helicopter rotor control [4]. By flexing a piezoelectric material, the rotor pitch can be adjusted to allow for control of an aircraft. Physics of Piezoelectricity Piezoelectricity means “electricity by pressure”. An electric field is generated when the material is mechanically deformed. When a piezoelectric material is strained, it polarizes, creating an electric field. Figure 1 shows how the polarization of the material occurs. As the material is compressed, the symmetry of the atomic structure is disrupted, resulting in poles occurring in atoms of the material. These poles lead to the creation of the electric field. The converse effect works in much the same way. When an electric field is applied across the material, it will cause polarization of the material, which in turn will deform it. Figure 1 - Atomic distortion of Piezoelectric material [1] 8 Piezoelectric materials can express both an isotropic and anisotropic characteristic. An isotropic material is one in which the physical properties of the material, such as the dielectric constant and Electro-Mechanical Coupling coefficient are uniform, no matter which axis of the material is being examined. An anisotropic material is one in which the physical properties are not independent of the physical axis examined. They are isotropic when they are unloaded, and therefore, their properties are not dependent on which axis of the material is being examined. When the material is loaded, however, it will exhibit anisotropic properties. Therefore, it is important in which direction one examines the material. The piezoelectric constants are defined as Xab, where X is the constant symbol, a is the axis where one is examining the electrical properties, and b is the axis where one is examining the mechanical properties. These are shown in figure 2. Here, all axes are labeled, and shown are the different linear directions, 1, 2, and 3, and the radial directions, 4, 5, and 6. An example of this axis nomenclature is K13 , the electro-mechanical coupling coefficient, where the electrical characteristic is on the X axis, and the mechanical characteristic is on the Z axis [5]. Therefore, if the material is being mechanically excited on the Z axis, the electrical output is being measured on the X axis. Figure 2 – Axis Nomenclature [5] 9 There is one characteristic equation which governs all piezoelectric devices. It is called the piezoelectric equation, and it is given in equation 1 [5]. This equation relates the compressive force per unit area (pressure) to the Electric Displacement. This is the basic equation used in analysis of piezoelectric devices. Di = d ij ⋅ σ j = d ij ⋅ where: F A (1) Di = Electric Displacement; dij = Piezoelectric Constant; σj = Mechanical Stress; F = Force; A = Area The Curie brothers noticed that the piezoelectric effect is linear, so that the electric field produced is directly proportional to the stress to which the material is subjected. These two properties are linked by the piezoelectric strain coefficient. This same coefficient is used for the converse piezoelectric effect. Figure 3 shows different loading situations of piezoelectric materials, including both the direct effect and the converse effect. The upper row shows the direct piezoelectric effect. The light colored box in each drawing shows the original shape of the material, and the dark box shows the final shape of the material. In both cases it is seen how the material reacts to the given excitation, either mechanical or electrical. 10 Figure 3 – Piezoelectric Loading [1] Figure 4 shows different loading situations for piezoelectric materials. Additionally, it also shows how these materials can be cut and oriented. Column A shows plate-shaped elements. The loading is perpendicular to the plane of the plate. This is referred to as “longitudinal loading”. Column B shows plateshaped elements for the shear effect. Column C shows rod-shaped elements for the transverse effect. Column D shows elements in the shape of a hollow cylinder or a truncated cone. Such elements can only be made of piezoelectric ceramics. They can be polarized either radially for the longitudinal effect or in axial direction for the shear effect. Column E shows bimorph elements as bending beams (exploiting the transverse effect). Column F shows torsionsensitive elements (exploiting the shear effect). [1] 11 Figure 4 – Various Piezoelectric Elements and their possible loadings [1] Piezoelectric materials also exhibit electrical properties, which can be modeled by equivalent circuits comprising capacitive and resistive elements. They have a defined capacitance, resistance, and inductance, and therefore exhibit an electrical resonance, where the electro-mechanical coupling peaks. These characteristics are directly related to the area and the piezoelectric modulus e [6]. The equivalent circuit element equations for a piezoelectric material at electromechanical resonance are shown in equations 2, 3 and 4 for the resistance, inductance and capacitance, respectively [6]. Equation 6 shows the natural capacitance of the material, formed by a dielectric material sandwiched between two metal plates. Figure 5 shows the total equivalent circuit for the material at resonance. Rm = Lm = ηl Ae 2 ρ sl 2 2 Ae 2 = K Rη (2) = KL ρs (3) 12 Cm = Ae 2 1 = KC = KC s cl c C0 = where: εA (4) (5) l c = elastic constant; s = compliance coefficient; e = piezoelectric stress constant; A = area; l = height of the material; ps = surface mass density; η = viscosity Cm Lm Rm Co Figure 5 – Piezoelectric Material Equivalent Circuit Model Table 1 shows all of the common piezoelectric constants, with descriptions of the constant and its units. These constants are used by manufacturers to characterize their devices. In addition, these constants are used in models governing the behavior of the piezoelectric devices. Using these models, the output from piezoelectric devices can be accurately predicted, allowing simulations to be completed. The most important parameters are the piezoelectric constant “dij”, the coupling coefficient “kij”, and Young’s modulus “Yaij”. 13 Piezoelectric Constant εr Table 1 – Piezoelectric Material Constants Description Relative Dielectric Constant • Used in calculating the capacitance of the material Loss Tangent tan δ • A frequency dependent ratio between the real and imaginary parts of the impedance of a capacitor. • A large dielectric constant implies a lot of dielectric absorption [7] kij Coupling Coefficient • A measure of the coupling between the mechanical energy converted to electrical charge, and the mechanical energy input Di Electric Displacement • Dielectric constant times the electric field dij Piezoelectric Constant (C/N) • The piezoelectric charge coefficient is the ratio of electric charge generated per unit area to an applied force [5] gij Piezoelectric Voltage Constant (Vm/N) • The voltage constant is equal to the open circuit field developed per unit of applied stress, or as the strain developed per unit of applied charge density or electric displacement [8] eij Piezoelectric Modulus (C/m2) • The ratio of strain to applied field, or charge density to applied mechanical stress [8] Ni Frequency Constant (m/s) • The frequency constant is the product of the resonance frequency and the linear dimension governing the resonance. [9] Qm Quality Factor • Measure of how well a system will resonate at or close to its resonance frequency [6] Density (kg/m3) ρ • Ratio of mass to volume E Poisson’s Ratio σ • A measure of how, when a material is stretched in one direction, it becomes thinner in the other two [6] saij Elastic Compliance (m2/N) • The inverse to Young’s Modulus • Ratio of mechanical strain to stress [9] a Y ij Young’s Modulus (Pascals) • Ratio of mechanical stress to strain *See fig 4 for explanation of “ a ” 14 All strains in the material are constant or mechanical deformation is blocked in any direction. All stresses on material are constant or no external forces. Electrodes are perpendicular to 3 axes. Relative dielectric constant ($3s/$0). Stress or strain is equal in all directions perpendicular to 3 axis Electrodes are perpendicular to 1 axis. Relative dielectric constant ($1T/$0). Stress or strain is in shear from around 2 axis. Electromechanical coupling factor Electrodes are perpendicular to 1 axis. Electromechanical coupling factor. Applied stress, or piezoelectrically induces strain is in 3 direction. Hydrostatic stress or stress is applied equally in all directions. Electrodes are perpendicular to 3 axis (Ceramics). Piezoelectric charge coefficient. Applied stress, or the piezoelectrically induced strain in shear form around 2 axis. Electrodes are perpendicular to 3 axis. Piezoelectric charge coefficient. Applied stress, or the piezoelectrically induced strain is in the 1 direction. Electrodes are perpendicular to 1 axis. Piezoelectric voltage coefficient. Compliance is measured with closed circuit. Electrodes are perpendicular to 3 axis. Piezoelectric voltage coefficient. Compliance is measured with open circuit. Stress or strain is shear around 3 direction. Strain or stress is in 3 direction Elastic compliance. Stress or strain is in 1 direction. Strain or stress is in 1 direction Elastic compliance. Figure 6 – Piezoelectric Symbol Terminology [10] Figure 7 shows a piezoelectric material loaded compressively through its thickness. It is assumed that the material is solid and cylindrical, and that it is being compressed between two rigid masses. Equation 6 shows the stress component exerted on the material [1]. Using this stress, and assuming the terminals of the piezoelectric material are short-circuited the electric flux density can be calculated using equation 7 [1]. Finally, the charge placed on the terminals can be calculated from equation 8 [1]. All of these calculations are based on the fundamental piezoelectric equation. T1 = F π ⋅ rK2 (6) 15 D1 = d11 ⋅ T1 = d11 F π ⋅ rK2 Q = d11 ⋅ F where: (7) (8) T1 = Mechanical Stress; F = The force exerted on the material; rk = the radius of the material; D1 = Electric Displacement; d11 = Piezoelectric Constant; Q = Charge Figure 7 – Piezoelectric Material Loaded Longitudinally Figure 8 shows a piezoelectric material which is loaded compressively through its length. Again, the same equations apply, although instead of the material being cylindrical, it is instead a rectangular bar. Equation 9 is used for the stress component of the material [1]. Equation 10 is used for the flux density, and equation 11 calculates the charge on the terminals, which are assumed to be connected to the top and bottom of the material [1]. Again, these equations are a more specific application of the fundamental piezoelectric equation. F a ⋅b (9) D1 = d12 ⋅ T2 (10) T1 = 16 Q = D1bl = d12 bl l F = d12 F ab a (11) T1, T2 = Mechanical Stress; F = The force exerted on the material; a = Width of the material; b = Height of the material; D1 = Electric Displacement; d12 = Piezoelectric Constant; Q = Charge; l = Length of the material where: Figure 8 - Piezoelectric Material Loaded Transversely [1] All of these formulas are summarized by the diagram shown in figure 9. This diagram shows how the various electrical and mechanical parameters are related to one another. It is seen how the electric field is derived by the stress T, or the strain S. From these measurable quantities, it is also seen how all of the piezoelectric constants, given in Table 1, are interrelated. Using this information, a piezoelectric material’s behavior can be fully calculated for use under any situation. 17 Figure 9– Relation of Piezoelectric Constants [11] 18 Piezoelectric Materials There are two main types of piezoelectric materials, crystalline materials and ceramic materials. Crystalline materials, such as quartz, occur naturally. They were found to exhibit piezoelectric properties as long as 100 years ago [1]. Recent advancements have yielded man-made materials that also exhibit piezoelectric properties [1]. These materials have begun to be used in many applications, from sensor applications to powering remote electronics in areas where other power sources are unavailable [1]. Figure 10 shows a comprehensive list of general piezoelectric material applications. Figure 10 – Piezoelectric Material Applications [1] 19 An example of such an application is the use of sensors on bridges. For older bridges, monitoring of modern loads on the bridge has become an important area of research. For existing structures, having to retrofit the structure with wiring for a monitoring system is expensive and time-consuming [11]. Using sensors powered by piezoelectric materials, which transmit their data using a RF link in a burst at periodic intervals, the real time load and stresses on a bridge can be determined. This capability enables an easy retrofit, and is a very costeffective way to monitor physical structures. [12] Figure 11 shows a basic topology of this type of system. The mechanical vibrational energy of the bridge is harvested, and used to power the onboard electronics. These electronics include the sensors, an A/D converter, a microcontroller for data processing, and the necessary RF devices to transmit the data to a remote receiver. Figure 11 – Piezoelectric Powered Wireless Sensor Array [12] 20 Crystalline Materials Crystalline materials were the first materials identified to exhibit piezoelectric properties. These materials, particularly quartz, are found naturally, especially in areas of the South Pacific [1]. Since these materials are crystalline, they are especially sensitive to their cut and orientation, and they exhibit different piezoelectric properties depending on the crystal orientation [1] Since the advent of piezoelectric sensors, the demand for quartz crystals has outstripped the natural supply. Therefore it became necessary to develop ways to artificially create the crystals. Methods were developed and many Quartz piezoelectric materials today are grown artificially in autoclaves. It was found that with a pressure between 1 and 2 kilo Bars and at a temperature of between 350 to 450 OC, Quartz can be grown [1]. There are, however, problems with artificially creating quartz. One such problem is the effect of twinning. This occurs when Quartz of two different crystal orientations intergrow. Twins can also form under loading, affecting the piezoelectric coefficient. It is best that this occurrence be avoided and must be considered when designing, or designing with, piezoelectric materials [1]. Piezoelectric Ceramics Another common group of piezoelectric materials other than quartz is a ceramic material which has been developed more recently. Piezo-ceramic materials are man-made, and come in many different types. These materials exhibit high coupling coefficients, and are very flexible, so they are very suited to custom applications. Another advantage of ceramic piezoelectric materials is 21 that since they are man made, they do not suffer from the problems which natural materials have regarding scarcity, and crystal orientation (having to cut the crystal on a certain geometric plane for optimal output). The ceramic material studied through the course of this research is lead-zitronite-titanate (PbZrO3,PbTiO3), commonly referred to as PZT material. PZT Materials are manufactured by sintering a finely ground power mixture. The powder is usually made of ferroelectrics of the oxygen-octahedral type, which are first shaped into the desired shape [1]. Piezoelectric ceramics are formed of a number of ferroelectric grains (crystallites), each containing domains in which the electric dipoles are aligned [1]. To properly demonstrate piezoelectric properties, the material must be polarized by heating the material to a high temperature and applying a strong electric field [1]. The PZT materials can be manufactured into various subtypes. These subtypes can be custom-designed for different uses and environments. The subtype materials are created by doping, or introducing impurities into the materials. By controlling the amount and types of impurities introduced, the physical properties of the material, such as the dielectric constant, coupling coefficient, and piezoelectric constant, can be modified to the designer’s needs. The subtypes are given a standard designation, such as PZT-5A. For the research conducted at Villanova, the materials examined were PZT-5A and PZT-8 [9]. Piezoelectric Material Comparison Some general considerations for selecting crystalline or ceramic piezoelectric materials for certain applications are presented next. Ceramic 22 materials are much cheaper than crystalline materials to use. They do not have to be grown, nor do they have to be cut properly. They manufactured by several companies such as Noliac and Advanced Cerametrics amongst others. Natural crystals can be rare, artificial crystals are difficult to use for applications which have space requirements, and finding the proper one for a specific application can be difficult. Finally, the ceramic materials are usually much more sensitive than the crystalline materials. [1] Table 2 shows some of the typical piezoelectric constant values for some common materials. The materials shown, from left to right are Tourmaline, a type of quartz material, Ceramic Multilayer Actuator – Ring (CMAR), which is a piezo-ceramic manufactured by Noliac, and PZT type 5a and 8 materials, which are manufactured by several companies. 23 Table 2 – Common PZT Material Properties Tourmaline (Quartz) Noliac CMAR PZT 5A PZT 8 7.5 1325.63 1875 1000 0.003 0.02 0.004 330 370 300 kp 0.568 0.62 0.51 kt 0.471 0.45 0.45 k31 0.327 0.34 0.3 k33 0.684 0.67 0.64 k15 0.553 0.69 0.55 Symbol Unit ε3,r tan δ TC > (3X) ºC d31 C/N 3.40E-13 -1.28E-10 -1.76E-10 -9.70E-11 d33 C/N 1.83E-12 3.28E-10 4.09E-10 2.25E-10 d15 C/N 3.63E-12 3.27E-10 5.85E-10 3.30E-10 dh C/N 2.51E-12 7.24E-11 5.80E-11 3.10E-11 g31 V m/N -1.09E-02 -1.10E-02 -1.09E-02 g33 V m/N 2.80E-02 2.57E-02 2.54E-02 g15 V m/N 3.89E-02 3.82E-02 2.89E-02 Np m/s 2209.94 2000 2340 Nt m/s 2038.09 1940 2060 Nc m/s 1015.41 930 1070 60 7750 1000 7600 Qm,t ρ kg/m 3100 372.71 7700 s11E m2/N 3.85E-12 1.30E-11 1.67E-11 1.15E-11 s12E s33E 2 m /N -4.80E-13 -4.35E-12 -5.20E-12 -3.60E-12 2 m /N 6.36E-12 1.96E-11 1.72E-11 1.35E-11 2 8.66E-12 s66 s11D s12D s33D Y11E Y33E Y11D Y33D 3 m /N 3.47E-11 4.37E-11 2.83E-11 2 m /N 1.16E-11 1.50E-11 1.01E-11 2 m /N -5.74E-12 -7.10E-12 -4.80E-12 2 m /N 1.05E-11 9.40E-12 8.50E-12 GPa 76.93 61 87 GPa 50.92 53 74 GPa 86.16 69 99 GPa 95.61 106 118 There are drawbacks to the ceramic materials. For some PZT materials, their sensitivity can degrade over time, an effect called “aging”. For applications 24 where consistent and reproducible measurements are necessary over a long period of time, such as sensors, this is a most undesirable trait [1]. The ceramic materials usually exhibit very high temperature sensitivity, making their thermal operating range very limited. This makes these materials unsuitable for more extreme environments, especially high temperature ones. At high temperatures the piezoelectric properties of these materials such as the coupling coefficient and the piezoelectric constant change and tend to degrade as temperature increases. This change becomes complete when the ambient temperature increases to the Curie temperature of the material [1]. At this point, the material will lose all of its polarization, losing its piezoelectric properties. Typical Curie temperatures for PZT materials are on the order of 200 oC. Finally, ceramic materials as well as certain quartz materials are pyroelectric, so when being used in sensors, electric noise will increase as their temperature increases. These materials exhibit a lower resistivity than the quartz materials, which can be a potential problem for designers. In sensor applications, a high resistance is needed in applications where the measurand is quasistatic to ensure a reliable output, making piezoceramic materials unsuitable for certain applications [1]. 25 Previous Work A number of research groups have examined piezoelectric materials, in both an academic sense and also in examining them for practical applications. The main focus of both research attempts has been in the sensor and actuation areas. Some work has focused on constructing piezoceramics. These materials can be custom designed for specific applications, and a group from Japan headed by Y. Hosono focused on developing piezoceramic materials with high Curie Temperatures and high piezoelectric constants. They examined a new piezoceramic material, PbZr03-free relaxor-lead titanate (PT), and compared it to the classical PZT material. They found that the new material had a much better electro-mechanical coupling coefficient and a larger piezoelectric constant. These materials however have a very low Curie temperature which must be overcome for these materials to become practical. The research team identified a material (PINMT) which showed a high electro-mechanical coupling coefficient, piezoelectric constant, and also a high Curie temperature [13]. Eric Prechtl from MIT examined the use of piezoelectric materials for use in helicopter rotor blades as an actuator. Flexing of the rotor is accomplished by placing the actuator in the trailing edge of the helicopter rotor. By deflecting the rotor blade, the pitch of the rotor can be adjusted, which is critical to the control of the helicopter. The device was built and tested at MIT, and results showed that a it was possible to achieve a 5 degree rotation at 90 percent of the span on an operational helicopter [4]. 26 Another research group from the National Taiwan University focused their research on applying piezoelectric materials as a generator for remote sensors. In certain regions, there is a major need to monitor the health of older bridge structures. As these structures age, they fatigue, and loose their structural strength. This is further accelerated by modern loads, such as heavy trucks and cars, being placed upon the bridge. Current bridge monitoring involves manned inspections, which are time consuming, and costly, especially on bridges in remote areas. Their solution to the problem was to harvest the vibrational energy of the bridge itself using a piezoelectric material. This energy will power electronics which measure the strain on the bridge, and will also power a RF transmitter to relay the information to a remote receiver in short bursts. This solution will provide the necessary data to monitor the load on the bridge, without the need to continuously send manned teams to check the bridge health [11] A research group from the University of Brescia in Italy conducted research on using piezoelectric materials for power harvesting. In a paper titled “Modeling, fabrication and performance measurements of a piezoelectric energy converter for power harvesting in autonomous Microsystems”, they presented their findings. Using PZT piezoceramic materials mounted in a cantilever position, they attempted to use these materials for remote sensors. They succeeded in developing models for these devices, and were able to harvest tenths of a microwatt, which when stored over time was sufficient to power electronics needed for a RF transmitter [14]. 27 A group from Pennsylvania State University, headed by Geffrey Ottman conducted research on harvesting energy from piezoelectric energy from piezoelectric materials and using DC to DC converter to perform power transfer operations and store the energy harvested. Two of the papers were titled “Adaptive Piezoelectric Energy Harvesting Circuit for Wireless Remote Power Supply” and “Optimized Piezoelectric Energy Harvesting Circuit Using StepDown Converter in Discontinuous Conduction Mode”, and were presented in the IEEE Transactions on Power Electronics [15][16]. In these papers, the researchers used PZT materials, a full bridge rectifier and a DC to DC converter to harvest the energy from the PZT Materials. They concentrated on looking at the duty cycle of the converter versus peak power output. They developed techniques for determining optimal duty cycle, and found that as the mechanical excitation increases, the optimal duty cycle becomes constant [16]. Another group from the University of Nevada conducted research into using piezoelectric materials for energy harvesting. This research focused not on the piezoelectric material itself, but on how the energy is harvested and stored. They used a rectifier, a storage capacitor, and power conversion circuitry to use the piezoelectric material as a stable electrical power source. The researchers further continue to discuss constructing a wireless sensor network with piezoelectric materials as a possible power source [17]. A group from the University of Missouri – Columbia has done extensive research into the electrical modeling of piezoelectric materials, and correlating their excitation to their mechanical output through their physical properties and 28 the compressive force that they are subjected to. The team has written a series of papers detailing their research, in which they first developed modeling techniques for the piezoelectric materials themselves, and then used those techniques to develop various generators for use. In a paper titled “Electrical Power Generation Characteristics of Piezoelectric Generator Under Quasi-Static and Dynamic Stress Conditions”, they presented their results for their model. They examined the material, and modeled it as a mechanical resonator comprising of a mass, spring and a damper. Using the conservation of energy, they concluded that the total energy of the system must comprise the electrical and mechanical energies. Using this, they modeled the electrical structure of the material itself as an ideal voltage generator, a capacitance and two resistances. They determined methods to calculate the component values, and also the internal voltage generation based on the compressive force exerted on the material and the materials physical properties. They verified the model using testing of existing materials [18]. Further research this team conducted took the model that they created previously and extended it to the examination of maximum power transfer in a piezoelectric pulse generator. In papers titled “Maximum Power Generation in a Piezoelectric Pulse Generator”, “Energy Conversion and High Power Pulse Production Using Miniature Piezoelectric Compressors”, “Design, Modeling, and Implementation of a 30-kW Piezoelectric Pulse Generator”, “Scaling Relationships and Maximum Peak Power Generation in a Piezoelectric Pulse Generator”, the research team examined various methods of determining 29 maximum power transfer, and then described some possible applications of the methods developed [19] [20] [21] [22]. To maximize the power generated, the team connected the material to a spark gap and an inductor. By varying the thickness to area ratio (TAR), they were able to maximize energy transfer from the material. The researchers sought to optimize the product of voltage and current. They found that the voltage of the material increased linearly with respect to the TAR, however, the current changed with an exponential trend with regard to the TAR. Thus there is a clearly defined maximum to the data, and optimal physical dimensions for the material. Using this information, the researchers continued to design high power pulse generators. One such generator designed yielded a peak current, peak power and power density of 58.2 A, 28.4 kW, and 517 kW/cm respectively [22]. For the present research project, the goal is the modeling and simulation of piezoelectric devices for an energy harvester application. This project encompasses the research presented here, but extends it in the use of piezoelectric materials in a munitons environment characterized by a short operational life and very high accelerations. Testing new materials in this environment can be prohibitively expensive, and therefore a low cost testing tool was needed. In addition, this project uses a mechanical mass-spring resonator to store energy mechanically, and this capability needed to also be modeled. This previous research was used as a stepping point to begin the examination of piezoelectric materials in this new environment with the purpose of modeling an energy harvester. 30 Experimental Test Materials Initial testing of the piezoelectric devices consisted of tests conducted on various sample materials supplied to the project. These materials came from Advanced Cerametrics Incorporated (ACI) [23], and Omnitek [24]. Advanced Cerametrics Incorporated The materials from ACI were in the form of bare materials, i.e. the piezoelectric ceramic materials themselves. They came in several varieties, and several material subtypes. These varieties included the “soft” material, which is loaded transversely, and also a “hard material”, which is loaded longitudinally. For this project, the subtypes examined were the PZT 5a and PZT 8. The materials examined were all ceramic materials, created artificially. They came in two main types. ACI manufactures the actual piezoelectric fibers. When these fibers are subjected to mechanical stresses, they generate electricity. The fiber materials are then embedded into ceramic matrices that allow them to be custom formed to whatever geometry is necessary. The first type, referred to as the “hard” material, is a hard piece of material which generates an electric field when it is compressed. This material is shown in figure 12. Figure 13 shows a technical drawing of the material, with the physical dimensions of the material. The term hard does not refer to the Figure 12 – Hard PZT 5a Material 31 Figure 13 – “Hard” Material Diagram and Loading; Units are in Inches piezoelectric type, but merely to its physical characteristics. This material is one in which the piezoelectric fibers are embedded along the vertical axis of the material, as shown in figure X as the “Z” axis. When the material is compressed, the fibers are also compressed vertically, causing an electric field to be generated at the ends of the fibers, or the top and bottom plates of the material. The second material is referred to as the “soft” material because of its flexibility. Figure 14 shows a photograph of the soft material. Figure 15 shows a dimensioned technical drawing of the soft material. Again, the term “soft material” does not refer to the piezoelectric type, but its physical characteristics. 32 In this material, the piezoelectric strands are oriented along the length of the material, so that when the material is bent along its “y” axis, as shown in figure 15, the strands are stretched, and placed under tension. This action causes an electric field to be generated. The soft materials come in two different varieties, the regular material, and a bi-morph material. The bi-morph material is one in which two of the regular soft test materials are placed in a sandwich, with a hard piece of material in between. The sandwich material is less than .06 inches thick. Essentially the device is two “soft” materials connected in parallel. The middle material is much harder than the regular test materials, and since the piezoelectric elements are bonded to it, a greater strain is placed upon the materials and therefore higher output voltage is seen from this device. Figure 14 – Soft PZT Type 5a Material Figure 15 – “Soft” PZT Loading Diagram; Units are in Inches 33 Omnitek Incorporated Omnitek is another company which manufactures piezoelectric devices. However, they have taken a slightly different approach to the problem. Instead of simply using a bare material, a more complex system was designed with the hope of harvesting more energy. They designed and constructed a mechanical resonator that, when subjected to acceleration, will absorb and store the energy in a mechanical system. As that energy is released, it is absorbed within the piezoelectric material and thus allows the generation of an AC voltage. A cutthrough schematic diagram of the type 3000 resonator is shown in figure 16. Figure 16 - Resonator Drawing; Units are in Millimeters Three types of resonators were examined. First is the type 1000 resonator. In this resonator, the mass is 10 grams, and the spring constant is 2 x 106 N/m. The mass of the resonator is comprised of the mass of the spring, supplemented by an additional brass mass that has been press fitted into the bottom of the mass spring material. The type 3000 resonator is very similar to 34 the type 1000 resonator, with the main difference being that the press-fit mass has been removed. This results in a spring constant of 2 x 106 N/m, and a mass of 3.75 grams. Finally, the third type of resonator is the type 2000 resonator. This resonator uses an external spring. The spring constant of this resonator is 0.5 x 106 N/m, and the mass used is 4 grams. 35 Resonator Model Introduction Basic control theory was used to develop a model for the mechanical mass-spring resonator [25]. This allowed the research of the transfer functions representing mechanical systems and their time-domain counterparts. Using this information, the mass-spring resonator (MSR) was modeled as a single axis of motion mechanical system, consisting of a spring, with a mass attached to its free end. When a force is applied to the mass, the mass spring system starts to oscillate. The piezoelectric material is placed between the spring and the rigid attachment. It was assumed that there was no deviation in the physical dimensions of the piezoelectric material, such as thickness, radius, and Young’s Modulus. This is not perfectly the case, but since the actual deviations are minute, on the order of nanometers, this is an appropriate approximation. The force that is transmitted through the piezoelectric material is then found by calculating the force exerted through the spring. This is done by taking the deflection of the spring and multiplying it by the spring constant. Derivation of Mechanical Model The first steps taken were to analyze the mechanical system itself. The system consists of a housing, in which a ring shaped piece of PZT material is mounted. This material is sandwiched between the housing and the mass spring unit. The mass spring unit consists of a machined piece of metal which has been cut in such a way that it works as a spring with a high spring constant, on the order of 106N/m. This spring has a mass associated with it, on the order of 36 several grams. The combined mass-spring system will oscillate when it is subjected to an input force. This oscillation will compress the piezoelectric material and thus the piezoelectric material will generate a voltage. The mass spring material is shown in figure 17. The equivalent mechanical model for the system is shown in figure 18. Figure 17 - Mass -Spring Resonator Material Figure 18 – Mass-Spring Resonator Diagram 37 Some assumptions were made about the system to make analysis easier. It was assumed that the system was one dimensional, meaning that it would not be responsive to any excitations that are exerted upon it outside of its primary axis. Secondly, the deflection of the piezoelectric material was ignored. Lastly, the internal damping of the materials was also ignored. It was assumed that the contribution of this effect is very small, and of little consequence to the overall performance of the system. First Generation Model - Development Primary research into how to approach developing a real-time model for the resonator concentrated in the area of mechanical system representations. Using the fact that force is conservative, equations 12 and 13 were written [25]. where: d 2 x(t ) M + Kx(t ) = f (t ) dt 2 (12) Ms 2 X ( s ) + KX ( s ) = F ( s ) (13) M – Mass; K - Spring Constant of the resonator; x(t) - Position of the oscillating spring relative to its static position; X(s) - Denotes the frequency-domain representation of the spring position. From these equations a relationship may be established which relates the position of the spring to the external force applied to the mass-spring system. This relationship is called the mass-spring system transfer function, and is critical because with it, the exact position of the spring can be known in real-time. Equation 14 shows the transfer function for this mass-spring system [25]. G ( s) = 1 X ( s) = 2 F ( s ) Ms + K (14) 38 First Generation Model - Initial Testing This representation was found to be inadequate when testing was started. The main discrepancy was in the resonant frequencies. In the lab, one resonant frequency would be identified through steady state testing, while the model would predict another. In addition, for the model’s resonant frequency, the oscillations would grow to impossible amplitudes. It was therefore decided that there was some internal damping that was not being accounted for. Figure 19 shows the model response for the un-damped mass-spring system at resonance. Fig 19 – Undamped Force Simulation at Resonant Frequency Second Generation Model - Derivation Once these problems were identified, it was decided that the internal damping of the spring was not inconsequential, and therefore needed to be accounted for. To accomplish this, the derivation procedure used previously for the undamped mass spring resonator was again used. The new equations are 39 shown in equations 15 and 16. The difference between these two equations, and the equations derived previously is the presence of the fv term, which is the damping constant [25]. M d 2 x(t ) dx(t ) + fv + Kx (t ) = f (t ) 2 dt dt Ms 2 X ( s ) + f v sX ( s ) + KX ( s ) = F ( s ) (15) (16) Again the system transfer function needed to be calculated. The only difference between the undamped and damped transfer function is the presence of the fv term in the damped function. Shown in equation 17 is the damped transfer function [25]. G (s) = X (s) = F (s) Ms 2 1 + fvs + K (17) Another difference is that the input force to the system was changed. It was realized that since the system is not attached to a fixed object, but rather is moving itself, that change must be accounted for. Shown in equation 18 is the input force to the system. “y” is the position of the system in space, and is calculated by taking the double integral of the acceleration of the system. “x” is the position of the spring in relation to the system. Therefore, the spring extension is the difference between “y” and “x”. F ( s ) = Ky + f v y& (18) Determination of the Damping Constant The next task was to determine the damping constant of the internal damping of the material. There is one type of sensor which closely resembles the resonator being examined. This sensor is also a mass-spring mechanical 40 system like the resonator, in which the mechanical damping of the resonator is calculated. In research material discussing this sensor, a series of formulas which allow the internal damping to be calculated from the observed resonance frequency are provided [1]. This data was implemented into the model and the resonator system. ω ωd = k m = ( (19) s ) ( k 1 − ϑ 2 = ω0 1 − ϑ 2 ms ϑ where: 0 = ) α 2 m (21) s ϑ = fading constant ⎛ d 2x ⎞ ⎛ dx ⎞ ms ⎜⎜ 2 ⎟⎟ + α ⎜ ⎟ + kx = F (t ) ⎝ dt ⎠ ⎝ dt ⎠ where: (20) ms - mass; α - damping constant; k - spring constant Fig 20 – Damped Force Simulation at Resonant Frequency (22) 41 MATLAB/Simulink Implementation Time-Domain System Conversion With the transfer function created, it is now possible to relate the force input to the extension of the spring. The problem arose however of the fact that the transfer function is implemented in the frequency domain, and all simulations were to be completed in the time domain as the input acceleration data is based in the time domain. This made it necessary to convert the transfer function to the time domain using the inverse Laplace transform. The process of converting the transfer function is shown is the series of equations below. First, the transfer function is rewritten, as shown in eq 23. Then the inverse Laplace transform is taken, as shown in eq 24. Next the state variables are chosen. These variables are the representations of the differential equation of varying orders. These equations are shown in eq 25. Next, the state and output equations are calculated. This is done by using the state variables, and differentiating both sides of the equation. This is shown in eq 26. Finally, x(t) is calculated from eq 27 [25]. (s 2 + fv K 1 s + ) X (s) = F (S ) M M M &x& + fv K 1 x& + x= f M M M x 1 = &x& x 2 = x& (23) (24) (25) 42 x&1 = x2 K x1 M fv x2 M 1 f M (26) f M 1 ( &x& + v x& − f (t )) = x(t ) K M M (27) x& 2 = − − + x = x1 − where: M – Mass; K – Spring Constant; fv – Damping Constant; f(t) – Input Force Generating the Model The mass-spring-damper system was integrated as a whole to complete the system level model. Since the input data to be used in simulations is the measured acceleration data, and the models all work on force data, this input had to be converted to a force. The input acceleration is first converted to position data by integrating it twice. The position data is then multiplied by the spring constant. The damping constant is then multiplied by the velocity data, and then these two values are summed together to calculate the input force. Using state equations, the equations of motion were calculated for the system. Using the frequency-based equations of motion, which represent how the mass will move continuously for any input force, it is easy to calculate the force impingent on the piezoelectric material by multiplying the spring constant by the spring deflection. The spring deflection is calculated from the difference between the position of the system during flight (y) and the position of the end of the spring during flight (x). 43 1 fin 2 m Fin/m 1 s 1 s Integrator Integrator1 1 unlimited spring output 2 3 Fv/M fv/m K/M k/m vx 4 Figure 21 – Time Domain Mechanical System Representation Model Verification Using the damping equations as mentioned earlier, the mass-springresonator system was tested to ensure that it was working properly. A step input acceleration was used as the system input acceleration. The peak of this acceleration was 30,000 g’s. This was done because information from Omnitek stated that for this acceleration, the type 3000 resonator would have a deflection of .5 mm. This was verified as the simulator produced a deflection of .55 mm, and thus confirmed that the resonator model was indeed working properly. The output for the tests is shown in figure 22. Fig 22 – Model verification based on resonator specifications 44 Piezoelectric Device Models The device models for the piezoelectric materials are simple electrical equivalent circuits consisting of a voltage source connected in series with a capacitance and a loss resistance. The value of the voltage source in the equivalent circuit model is directly related to two things, the area of the piezoelectric material and the compressive force applied to the material. This information, along with the physical properties of the material allows the material’s output voltage to be predicted. The capacitance is calculated from the relative dielectric constant of the piezoelectric material, and the height and area of the material. The loss resistance represents the losses from the current traveling across the surfaces of the material to the electrical leads. The leakage resistance represents the losses as current travels through the material. As a rule, the loss resistance is relatively small, on the order of tens of ohms, and the leakage resistance is high, on the order of megaohms, depending on the thickness of the material. The loss resistance of the material is the resistance seen as current moves out of the material. It is defined by the loss tangent of the piezoelectric material, the operating frequency and the capacitance of the material [18]. Rloss = C stack = tan(∂ ) ωC stack ε oε r A h piezo (28) (29) 45 The electrical model for the material is shown in figure 23. Rleakage is measured experimentally, and Rloss and Cstack are calculated as above. Va is calculated, and the formula is derived later in this paper. Figure 23 - Electrical Model for Piezo Material [18] Deriving the Voltage Source Model Following Keawboonchuay and Engel a mechanical model for the piezoelectric material, based on a mass-spring-damper system representation, as shown in fig 24 was derived [18]. The mechanical system of equations were written for this system. These are shown in equation 30. m piezo &x&piezo + c piezo x& piezo + k piezo x piezo = F (30) In this equation, mpiezo is the mass of the piezoelectric material, cpiezo is the internal damping of the piezoelectric material, and kpiezo is the spring constant of the piezoelectric material [18]. 46 Figure 24 - Mechanical Representation of the Piezo Material [18] For any given compression, the mechanical energy stored in the system is shown in equation 31. By relating Young’s modulus to the spring constant of the system, it is possible to rewrite the stored mechanical energy of the system in terms of the piezoelectric constants. This is shown in equation 32 [18]. Wmech = Fx piezo Wmech 2 1 F h piezo = 2 YA (31) (32) The next step is to evaluate the electrical energy generated in the material. This is shown in equation 33. By equating the mechanical energy to the electrical energy, and solving, it is possible to calculate the internal voltage generation. This is shown in equation 34 [18]. 47 Welec = Va = 1 q2 2 C stack k 33 Fh piezo A (.5Yε o ε r ) −1 / 2 (33) (34) Using the Model The piezoelectric system model takes the input compressive force generated by the mechanical resonator model and static input data, such as the material’s physical properties and electrical properties, and uses the information to compute the voltage waveform. This block uses the electrical model to calculate the voltage generated by the piezoelectric material. This electrical model uses material properties and impingent forces to convert the mechanical energy to electrical energy. For simplicity, and because this is a two part model (mechanical and electrical components), only the voltage generation characteristics of the material are accounted for in Matlab/Simulink, not the internal losses inherent to the piezoelectric material. It was decided that these losses would be accounted for when the design work was completed in PSpice. This decision was also made because any coupling issues between the generator and the load can also be simulated in PSpice, making the simulation more accurate. The model was created using MATLAB with Simulink. To use the model, the user must first have one set of data, the input acceleration data as a function of time. If a comparison to an existing set of test data is to be completed, an output voltage data set as a function o time is also necessary. Figure 25 shows the complete piezoelectric model as implemented in Matlab/Simulink. 48 In1 .69 In2 k33 In3 8.43e10 youngsmod In4 Out1 In5 Vout .002 In6 Product1 del\R3output_dr hpiezo (m) Vout In7 1800 er ln8 In9 0 Piezo System Lpiezo (m) 0 Wpiezo L W Or .006 Ir fcn 0 C er Outer Radius (m) Cp (Farads) h Piezo Capacitance .002 Inner Radius (m) .003 Loss Tangent lt c fcn 0 Rl f Rloss (ohms) Loss Resistance 1200 rloss Operating Frequency fcn V0ratio 0 rleakage L Or Ir .45 Conductivity Voltage Divider Ratio Output Voltage Divider Ratio W fcn 0 R p Rleakage (ohms) h Leakage Resistance Figure 25 – Electrical System Model Verification The final task in the development of the model was to verify its operation. Using the information and test data taken by the researchers who developed the piezoelectric electrical model, the Simulink model was tested [18]. First, an input force was created as a pulse. This pulse was fed into the model, and using material properties given, the output was generated. This output is shown in 49 figure 26. The output from the model was compared to that given in the research paper, shown in figure 27 [18]. Figure 26 – MATLAB Test Data Figure 27 – Measured Test Data [18] 50 The Simulink simulation showed a peak output voltage of 88 volts. This is the output from the internal voltage source, and therefore does not account for internal losses. The stimulus for this test was a pulse representing a compressive force of 500 Newtons, the same peak force measured in the reference data [18]. The reference data showed a measured peak output of approximately 70 volts for the same input force. The data in the research paper, however, takes into account internal losses. In comparison, there was a difference between the reference data, and the data generated by the model developed. This difference was attributed to the difference in accounting of losses between the two data sets. With this difference in mind, it is determined that the model is working. 51 Model Derivation The overall system model was generated by integrating the mechanical model and the electrical model. As these two models were developed separately, they needed to be interconnected and tested to verify their operation. The two individual models were placed into the same Simulink workspace, and then interconnected, as shown in figure 28. Then the testing of the total simulator commenced. X(t) Xt F(t) A(t) g's Fin A(t) F(t) Piezo Length Limit Fin Position M K fv y Force vy tor input data\R -9.8 Subtract a f in k y Gain fv 0 Step f_piezo 1 vy FPiezo Coupling Factor Resonator System Y System .699 k33 k31 Data Mean 0 162.9 Lpiezo (m) m fcnf 0 k f0 0 Wpiezo 1250 .006 fd fv fcn ms k Embedded MATLAB Function1 Observed Resonant Frequency (Hz) Outer Radius (m) .00375 .002 M resonator (Kg) hpiezo hpiezo (m) 3676 f0 (Hz) fv Vout .000067 L W Or Ir fcnVstack or output data\R A fcn Vout A Area Calc 43.10e9 y oungsmod Vout_ref er Y33 Force to Voltage conversion Inner Radius (m) 1050 2e6 er3 A K resonator (N/m) Created: Thu Apr 14 15:23:25 2005 Model Version: 2.224 Last Modified: 05-Feb-2006 23:01:22 T his model is designed to simulate the Omnitech Piezoelectric resonator -Developed by: Sean Pearson -Input acceleration should be in meters per second squared -If acceleration is in g's, adjust the gain on the input to 9.8, if m/s^2, make it 1 -if output is of wrong polarity, input acceleration may be inverted using gain stage to correct problem 0.0001005 er A (m^2) h fcn 1.394e-008 C .5e-3 Spring Extension Limit (m) Cp (Farads) Piezo Capacitance .003 Loss Tangent lt c fcn 27.4 Rl f Rloss (ohms) Loss Resistance l a 10e10 Resistivity fcn 6.665e+010 R p RLeakage(ohms) Leakage Resistance Figure 28 – Complete System Model Data was taken from the resonator, comprising of the voltage vs, time measurements. This data was taken with the resonator open-circuited. Then all of the relevant parameters were input into the model. These parameters are items such as the mass and spring constant of the resonator, the physical dimensions of the material, and the actual material properties such as the 52 coupling coefficient, dielectric constant and Young’s modulus. Simulations were run, and the voltage output was generated. Once the system was integrated, several small problems appeared which needed to be solved. Once of these problems was an order of magnitude difference between the output of the model and that which had been measured in the lab. The difference between the measured output and the simulated output is shown in figure 29. Figure 29 – Incorrect Simulator Output After extensive research, it was found that this error stems from the internal construction of the Noliac CMAR3 material. Shown in figure 30 is a cut away drawing of the material. The material is not uniform throughout its vertical axis, but rather is constructed of layered thin piezoelectric materials. After 53 communicating with the engineers at Noliac, it was found that these materials are made of 24 thin piezoelectric rings, each being 67 microns thick. The rest of the space in the material is filled with inactive material. Figure 30 - Noliac CMAR Material Cutaway Drawing These changes were implemented into the model by changing the height of the material from 2 cm, to 67 microns. The rest of the constants, such as k33 and Young’s modulus were assumed to still be constant throughout the material. The results from the new simulation are shown in figure 31. The simulated results are the dashed line, and the measured are the solid line. The peak voltages do not match up exactly, but they are very close with one another. The expected voltage is 0.69 volts, and the model is producing a peak of .55 volts. This is an overall root mean square error of approximately 2.91%. To compensate for this small difference, a correction factor was placed in between 54 the mechanical and electrical stages. This is a linear adjustment, and is approximately 1.255 for the type 3000 resonator tested. Using the correction factor, the output can be artificially corrected so that further simulations and extrapolations are accurate. 0.6 0.5 0.4 0.3 0.2 0.1 0 -0.1 0.33 0.331 0.332 0.333 0.334 0.335 0.336 0.337 0.338 0.339 Figure 31 – MATLAB Simulink Output, Type 3000 Resonator Another resonator was tested, a type 2000, and the results were similar. The measured peak voltage was 1.005 volts, and the simulated peak voltage was 0.61. The root mean squared error is 3.62%, and the correction factor is 1.64. 1 0.8 0.6 0.4 0.2 0 0.315 0.32 0.325 0.33 0.335 0.34 0.345 0.35 0.355 0.36 Figure 32 – MATLAB Simulink Output, Type 2000 Resonator 55 The correction factors were designed to compensate for a small difference between the measured material voltage output and that produced by the simulator. It was seen that the model was very sensitive to the physical constants of the material. For example, a 20 percent increase in the thickness of piezoceramic to 80 microns for a type 3000 resonator yielded an almost perfect match at the peak voltage point, however the overall root mean squared error was 3.13%. A 6 percent increase in the type 3000 resonator mass to 4 grams yielded similar results, with an overall root mean square error of 2.97%. It was therefore decided that the inaccuracies noted were due to these effects. Final verification of the accuracy of the model came in the form of the internal circuit parameters calculated by the Simulink model. The Simulink model calculated the internal capacitance of the material to be 12.12 nF. The datasheet for CMAR3 states that the capacitance of the material is 350 nF + 15%. This gives a capacitance range of 298 nF to 402 nF. If 24 of these thin piezoelectric rings are connected in parallel, the capacitances will sum to form the total capacitance. To calculate this, the internal capacitance of a single plate needs to be multiplied by 24. Therefore, the total capacitance of the material is 290.88 nF. This is close to the range specified by the material datasheets. Using the nominal value of 350pF, the percent error is approximately 17%. Using the closest value in the range, 298pF, the percent error is 2.68%. 56 PSpice Simulations Another issue with the Simulink model is that the voltage generator implemented in Simulink does not simulate the open circuit voltage of a material, it simulates the internal voltage generator, shown in figure 33 as V4. It is therefore necessary to develop a model that can simulate the terminal voltage of the material, and, better yet, be able to accommodate any additional circuitry. To accomplish this, PSpice was examined as a possible alternative. The first task was to find a way to get the voltage output from Simulink into PSpice. This was accomplished using the VPWL_File voltage source. This source will take a comma separated value (*.csv) file and import the data into PSpice. Adding the capability for the Simulink model to calculate the loss resistance R_Loss (see figure 33) and material capacitance C_Stack (see figure X) completes the PSpice model for the material. With all of this done, PSpice could be used to determine the terminal voltage for the device. Figure 33 – PSpice Piezoelectric Material Model 57 Once the material model was implemented, simulation could begin. The user must set the time length of the simulation. This length can be either shorter, the same length, or longer than the input data. If the simulation length is longer, PSpice will make the voltage source equal to 0 after the input data ends. The length of the input data can be found from the time length of the MATLAB® simulation, or it can be seen in the last data value for the input data set. The user can then add any type of circuit elements that they choose. Common components are a full bridge rectifier, utilizing low turn-on voltage germanium diodes or silicon Schottky diodes, a filter capacitor, and then a load. Another type of loading is to use a DC to DC converter on the output of the device. This will allow the high output voltage of the piezoelectric material to be chopped and then rectified and used as a stable value with good source current capabilities. 58 Using the Model All data necessary to use this model must be input using “.mat“ files. These are the files that MATLAB® uses to store the data it generates. In the lab at Villanova, all of this data was collected using the Agilent® 54622D oscilloscope with the GPIB interface. This data collection system allows the data collected by the oscilloscope to be interfaced with Microsoft® Excel©. The data collection tool is shown in figure 34. An Excel© file has been created to accept this input data. The file is labeled template.xls. There is one place to input the raw data, and the spreadsheet takes care of the remaining calculations. The spreadsheet automatically calculates the converts the acceleration data from volts to meters/second2 and calculates the peak input acceleration. Figure 34 – Data Retrieval Tool 59 When the data is placed into the spreadsheet, the user must enter two pieces of additional information. The first is on the first sheet, titled “Acceleration Data”. Cell F5 contains the parameter which relates the voltage data to the acceleration units. This data comes from the collection device, which in the tests that we conducted was the Bruel & Kjaer Charge Amplifier Type 2635. Normal values for this parameter were 1 mV / (m/s2). The second piece of information needs to be entered on the worksheet titled “Voltage Data” and this is the load placed on the resonator. This data is used to determine the power output. The maximum power transfer load was previously determined by the load impedance tests. When this is all done, the file should be saved with an appropriate file name. The template sheet is shown in figure 35. Figure 35 – Microsoft Excel Data Collection Sheet 60 With this information now in place, all the data is correctly formatted, and the conversion to mat files can now occur. The next step is to locate the file called “inputtemplate.xls”. This sheet is shown in figure 36. This file is located in the same folder as the model files. With this file open, three sets of information need to be copied into it, overwriting the existing data. Column A is the time data measured, in seconds. Column B is the acceleration data, in either units of m/s^2 or g’s, and finally column C is the voltage data, in volts. When pasting the data into the file, use the paste special command and only paste the values, not the formulas. This file should then be saved under the same file name. In cell E4 of this file is a MATLAB command line, this should be first edited so that it has the appropriate file and directory name of where the inputtemplate.xls file is located, and then the command should be copied into MATLAB. Figure 36 – MATLAB® Data Input Sheet 61 When the command is entered into MATLAB, it will be executed immediately. Two new files will appear in the workspace after execution. The MATLAB user window is shown in figure 37 after data load. One will be called input, and the other output. These files will be automatically saved to the directory outlined in the command as input.mat and output.mat. Appropriate file names are selected, and the files are renamed. The file naming format is month.day.year_test number_material type_material number_input or output_accelerations units_terminal load.mat. Now open up the file titled “sysmod_v4.mdl” is opened. Simulink will start and open the file. Figure 37 – MATLAB Window after Data Load Before executing the simulation, several modifications must be made to the Simulink file. The first is to modify the input path. This is the leftmost box in the model. Double click on the box, and edit the file name and path to the appropriate one for the input file being used. The input box window is shown in 62 figure 38. In addition, the sample time for the input data needs to be adjusted to fit the data which is being used. If the sample time is unknown, input -1. The same must be done then for the output file. Locate the output file box on the right hand top part of the screen, again double click. Perform the same action as before, although modify the output filename this time. The output dialog box is shown in figure 39. Figure 38 – Input File Window Figure 39 – Output File Window 63 The simulation configuration parameters must also be adjusted. This is located in the toolbar section of the program, in the center of the screen. The configuration box is shown in figure 40. Default units are seconds, and the user simply needs to enter the time length of their data into this spot. The user must also choose the type of solver that they wish to use. A fixed time solver is necessary since the PSpice is unable to accurately recognize the data produced by the variable time solvers. The final adjustment is the type of input acceleration units used. The input units to the model must be meters per second squared. If the measurement units are in g’s, the gain parameter in the model must be 9.8 to convert to meters per second squared. If the measurement units are already in meters per second squared, then the gain parameter should be 1. With these operations performed, the simulation is ready to commence. 64 Figure 40 – Simulink Configuration Screen The output from the simulation comes in two forms, graphs and data sent to the workspace. The main output form is the output graphs, and an example of these is shown in figure 41. These compare the voltage data measured to the data produced from the model. From this data, the user can easily ascertain how accurate the model is and what changes need to be made to improve this accuracy. 65 Figure 41 – Output Data Graph The simulation results must first be taken from Simulink, and imported into PSpice. This is completed by using Microsoft Excel as an intermediary. To do this, the user needs to execute the following command; output = tout; output(:,2) = Vout; csvwrite('h:\research\model\pspice\input_data\input.csv',output); This command will copy the “Tout” workspace file from MATLAB® into the first column in Excel. Next, it will copy the “Vout” workspace file into Excel, placing the data into the second column. With this completed, the command will save the file using the “csvwrite” command. This is necessary since PSpice will not 66 recognize the .mat files that MATLAB® uses, nor will it recognize a ".xls" file that excel uses. It will, however recognize the ".csv" file. The user should then locate the file just created and rename it using the same naming convention used for the “.mat” files previously. The MATLAB® user window after simulation is shown in figure 42. Figure 42 – Matlab Window After Simulation With these steps completed, the next step is to open up PSpice. Look for the file titled “PIEZO”, it should be in the PSpice subdirectory of the MATLAB® model file. When this is open, navigate to the schematic page, and examine it, there should be at a minimum four components on the page, the piezoelectric capacitor, the loss and leakage resistors, and the piezoelectric voltage source. The first step is to check the voltage source. Check the file name to make sure 67 that it is pointing to the “.csv” file that was just created. If this information is correct, the user must then change the component values to those provided by the MATLAB® Simulink simulation, so that the model parameters for the piezoelectric material are correct. The PSpice window is shown in figure 43, ready for simulation. Figure 43 – PSpice Window 68 Experimental Setup The drop test was used to provide very high impact accelerations, greater than 15,000 g’s. The drop platform itself is approximately 2 meters tall, and is constructed of two steel plates, one which acts as the base plate, and one which acts as the drop plate. From the base plate, two polished metal pipes extend, and are held in parallel by a wooden clamp at the top. The second steel plate rides on these pipes using two ball bearing sleeves. The impact force can be applied through a cushion, which is designed to extend the force of the impact to better resemble the acceleration curve experienced in the gun environment. To do this, some of the acceleration amplitude must be sacrificed, but since piezoelectric device behavior is linear with force, it is easy to extrapolate the laboratory output to that of the gun environment. The cushion is positioned between the base plate and the drop plate. If the test material must also be placed between the base plate and the drop plate, the cushion is placed on top of the material. Figure 44 shows the drop platform. 69 Figure 44 – Drop Test Setup The cushion is made of rubber, layered, and held together with electrical tape. Many materials such as wood, foam, and wax were examined to be used as cushions. These materials were found to dampen the acceleration to a point where it became useless. The rubber material acted more like a spring, storing and real easing the energy of the drop, effectively reproducing the acceleration curve. Figure 45 shows the accelerometers mounted on the drop platform. When drop testing a resonator, the optimal method to excite the device is to apply acceleration to it. This action will set the resonator into oscillation, thus producing a voltage output. This is easy to do by simply mounting the resonator to the top of the drop plate. When dropping it, the impact of the plate will provide an acceleration to excite the resonator. This will set the resonator oscillating, 70 and thus generate a voltage output. Table 3 shows the channel assignment for the data recorder. Figure 45 – Drop Platform Mounting with Resonators 71 Table 3 - Test Connection Chart Channel Measurement 1 Acceleration (.945 mV/g) 2 Resonator 1 3 Resonator 2 4 Resonator 3 5 Resonator 4 (center, un-limited resonator) 6 Resonator 5 7 Resonator 6 9 Resonator 7 The tests were all conducted with the material terminals open-circuited. Probes were attached and all data was recorded. The tests were conducted using the Nicolet Vision data retrieval system, along with PCB Piezotronics 480E09 and 480E10 signal conditioners. The accelerometer was PCB Piezotronics 350B04 shock accelerometer. The accelerometer is shown in figure 46. The data retrieval system is shown in figure 47. 72 Figure 46 – Accelerometer and Charge Amplifier Figure 47 – Nicolet Data Recorder 73 Results Below are some test results that were taken on July 21, 2005 at Picatinny Arsenal. Two series of 5 drops were conducted, one for each signal conditioner, and then two additional drops were completed using the 480E09 signal conditioner along with the drop cushion. A total of 8 channels were used on the Nicolet, channels 1-7 and 9 (channel 8 would not couple correctly). A sampling rate of 100,000 samples/second was used. The data retrieval system is shown in figure 47. Operation of the system is very similar to that of a personal computer, and the retrieval system is actually based on a Windows 98 core. Figure 48 shows a sample of the data recorded from the materials. Shown in figure 48 are the results for a type 3000 resonator after it had had been run through the Simulink model. Figure 49 shows the results from the PSpice simulation of the model data. The experimental data was taken using the test setup above, with the rubber cushion in place. This data is for the R3 resonator, and was taken on the third test drop. The piezoelectric material was opencircuited. The maximum sampling rate of 100,000 samples per second was used. 74 Figure 48 – Type 3000 Resonator Matlab simulation Output Figure 49 – Type 3000 Resonator PSpice Output 75 Tests were also completed for one of the type 2000 resonators tested. Figure 50 shows the Matlab comparison between the measured data and the simulated data. The peak for the measured data was approximately 1 volt, and the peak for the simulated data was .61 volts. To correct the simulator output for this difference, the correction factor used was 1.66. Using the corrected data, the PSpice output is shown in figure 51. The peak for the corrected output is 1 volt, matching the measured data. The experimental data was taken using the test setup above, with the rubber cushion in place. This data is for the R5 resonator, and was taken on the third test drop. The piezoelectric material was opencircuited. The maximum sampling rate of 100,000 samples per second was used. 76 Figure 50 – Type 2000 Resonator Matlab simulation Output Figure 51 – Type 2000 Resonator PSpice Output 77 Figure X shows the results completed for one of the hard drop tests. In this test, the rubber drop cushion was removed, and the impact was metal against metal. This produces a much higher impact acceleration, but with much higher frequency oscillation. Figure 52 shows the results for the hard drop test. The red is the measured vales, and the yellow is the simulated results. The peaks occur at very similar magnitudes, although the graphs do not bear a lot of resemblance. The sampling rate for these tests was 100,000 samples/second. Looking at figure 52, something of note are the sharp peaks of the purple plot. The signal does really have such sharp transitions, but this is due to an under sampling of the data. This under sampling is then translated into the model data through the acceleration data, which experiences the same effect. This will therefore distort the output from the model, making the test results less accurate. Figure 53 shows the PSpice output from the simulations. 78 Figure 52 – Hard Drop Test Figure 53 – PSpice Output 79 The next simulations completed were to see what the results were if the material were subjected to the firing acceleration. Figure 54 shows the acceleration that was used to excite the resonator. To generate the acceleration data, a graph of the firing acceleration for a 155mm gun was sampled and input into Microsoft Excel. Then a fifth order polynomial was fit to the data. The equation for the polynomial was then used to generate a new data set, with a higher data sampling rate, allowing for more accurate simulation. A new Simulink simulation profile was created to allow for the simulation of the device in the gun environment. In this profile, the ability to compare the model data with the measured data was removed. This was done because there is no measured data, since the user is simulating device response in an unknown environment. The new simulation file is called “sysmod_simulator”. The PSpice output for this simulation is shown in figure 55. 80 Figure 54 – MATLAB Simulink Output Figure 55 – PSpice Output 81 The final test was to complete a new design. The goal was to charge a 47 μFarad capacitor to a voltage of 6.00 Volts. At this voltage, the energy stored in the capacitor will be 846 mJoules. To complete this design, the mass and spring constant of the resonator, the outer radius of the piezoelectric material, and the electrical circuitry connected to the material were able to be modified. The change was to increase the mass of the resonator in order to induce a higher compressive force on the material. With this completed, the spring constant was increased to keep the spring extension to a reasonable length, around .5 mm. The outer radius of the material was extended to allow the material to source a higher current. Simulations were completed, and two things were noted. The spring extension of the resonator peaked at .58mm, only slightly longer than the requirements set forth in the specifications for the existing resonators, and the output voltage was much higher, around 70 volts. Figure 56 shows the acceleration of the resonator. Figure 57 shows the extension of the resonator spring. Figure 58 shows the output voltage of the resonator. Figure 56 - Resonator Acceleration 82 Figure 57 - Resonator Spring Extension Figure 58 - Output Voltage The final spring parameters were a mass of 100 grams and a spring constant of 2*107 N/m. The new outside radius of the piezoelectric ring material was 14mm, with an inner radius of 2 mm. The thickness and construction was kept identical to that of the noliac piezoceramic material. This is 24 stacked layers of 67μmeter piezoceramic material. With this construction, the resonator 83 had an output of 70 volts at an acceleration of 116.3 m/s2. This is 11.86 kg’s. Using this data PSpice was used to create a design to best harness this energy. Because of the high voltages produced by the Piezoceramic material, a transformer was used to step down the AC voltage to something that can be used practically. The added effect of this is that it steps up the charging current to allow the capacitor to charge quicker. The turns ratio of the transformer was found experimentally to be approximately 7.07. Using a full bridge rectifier to rectify the AC voltage, and a 47 μFarad capacitor to store the energy, a circuit was constructed, shown in figure 59. R_Loss 500mH TX1 7.293 Vin D9 10mH D1N4001 D1N4001 w:\Research\Model\PSPICE\input_data\input.csv R_Leakage D12 D10 4620000 C2 C1 1.7u V D1N4001 47u Riso D11 100000k D1N4001 R3 1k 0 Figure 59 - PSpice Circuit During simulations, a 47 μFarad capacitor was charged to a peak voltage of 7.25 volts, shown in figure 60. At this voltage, the stored energy is 1.235 mJoules. In addition, a 1 kiloohm resistor was placed in parallel with the capacitor to discharge it. The peak current through this resistor is 7.25 mA, shown in figure 61. The peak power dissipated through the resistor is 53 mW, shown in figure 62. This design meets all the criteria laid out for the design, and since the peak acceleration is lower than that seen in the actual munition firings, higher currents, voltages and powers are likely to be seen. 84 Figure 60 - Capacitor Voltage Figure 61 - Resistor Current Figure 62 - Resistor Power Dissipation 85 Conclusions In conclusion, this project has reached its goals of examining Piezoelectric materials, characterizing them, validating the mathematical equations for them, and then developing a real-time model for the materials. The work completed in the independent study involving the characterization and testing of piezoelectric devices was extended into the research demonstrated in this report. The development of the model realizes the goal of determining a technique for optimizing the materials, and also developing the ability to simulate them in a circuit simulator such as PSpice. This model is comprehensive, allowing the simulation of the materials of both the mechanical and electrical components of the piezoelectric material. In addition, it allows the future development of electrical energy conversion components in a low cost simulation environment. Suggestions for Further Work Further work on this project would concentrate on the development and streamlining of the modeling tool, and utilizing the model to design a better resonator, with an emphasis on optimizing the power output. Currently the modeling tool is rather complicated to use, with many steps involved, and many areas for user error. Streamlining and automating the process would greatly improve the model and make it much easier for the user to use. It would allow for faster simulations, which would improve the effectiveness of the model. 86 Another area for further work would involve better evaluation of the piezoelectric materials, and more development of the electrical model used. Better determination of the material properties such as young’s modulus and the dielectric constant would yield a much more accurate simulation. An advantage of the model is that it quickly correlates the mechanical input to the electrical output in real time. Using this information, one can take data measured for a specific environment, and determine the optimal resonator parameters for that environment. Then they can find the optimal piezoelectric material and optimize its physical characteristics. Developing the techniques for this would be a great area of improvement and future work. 87 REFERENCES [1] Gautschi, Gustav. “Piezoelectric Sensorics”. Berlin: Springer – Verlag, 2004 [2] Curie, Jaques. Curie, Pierre. “C. R. 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New York: John Wiley & Sons, Inc. 2000 91 Appendix 1 – CMAR 3, S1 Material Symbol Unit H1 ε1,r ε3,rX ε1,rS ε3,rS X S1 S2 1193.04 1795.99 2438.00 1325.63 1802.77 2874.16 828.30 1129.69 1341.00 699.67 913.73 1221.61 0.003 0.017 0.016 330 350 235 kp 0.568 0.592 0.643 tan δ TC > (3X) ºC kt 0.471 0.469 0.524 k31 0.327 0.327 0.370 k33 0.684 0.699 0.752 k15 0.553 0.609 0.671 d31 C/N -1.28E-10 -1.70E-10 -2.43E-10 d33 C/N 3.28E-10 4.25E-10 5.74E-10 d15 C/N 3.27E-10 5.06E-10 7.24E-10 dh C/N V m/N V m/N V m/N 7.24E-11 8.50E-11 8.82E-11 -0.0109 -0.0107 -0.0096 0.0280 0.0267 0.0226 g31 g33 g15 e31 e33 0.0389 0.0373 0.0321 2 -2.80 -3.09 -5.06 2 14.7 16.0 21.2 2 11.64 3.82E+08 13.40 4.68E+08 C/m C/m e15 C/m h31 V/m 9.86 4.52E+08 h33 V/m 2.37E+09 1.98E+09 1.96E+09 h15 V/m 1.34E+09 1.16E+09 1.13E+09 Np m/s 2209.94 2011.08 1970.47 Nt m/s 2038 1953 1966 N31 m/s 1500 1400 1410 N33 m/s 1800 1500 1500 N15 m/s 1018 896 822 776 89 76 74 7700 0.389 195 7460 0.340 Qm,p ρ σE kg/m 373 7700 0.334 s11E m2/N 1.30E-11 1.70E-11 1.70E-11 s12E s13E 2 m /N -4.35E-12 -6.60E-12 -5.78E-12 2 -7.05E-12 -8.61E-12 -8.79E-12 Qm,t 3 m /N 92 s33E s44E = s55E m2/N 1.96E-11 2.32E-11 2.29E-11 m2/N 3.32E-11 4.35E-11 5.41E-11 s66 2 m /N 3.47E-11 4.71E-11 4.56E-11 s11D m2/N 1.16E-11 1.51E-11 1.47E-11 2 m /N -5.74E-12 -8.41E-12 -8.10E-12 2 m /N -3.47E-12 -4.08E-12 -3.30E-12 2 m /N 1.05E-11 1.19E-11 9.94E-12 m2/N 2.31E-11 2.73E-11 2.98E-11 2 1.68E+11 1.47E+11 1.34E+11 2 1.10E+11 1.05E+11 8.97E+10 2 9.99E+10 9.37E+10 8.57E+10 2 N/m 1.23E+11 1.13E+11 1.09E+11 N/m2 3.01E+10 2.30E+10 1.85E+10 s12D s13D s33D s44D = s55D c11E c12E c13E c33E c44E = c55E N/m N/m N/m c66 2 N/m 2.88E+10 2.12E+10 2.20E+10 c11D N/m2 1.69E+11 1.49E+11 1.36E+11 c12D N/m2 1.12E+11 1.06E+11 9.21E+10 2 9.33E+10 8.75E+10 7.58E+10 2 N/m 1.58E+11 1.44E+11 1.51E+11 N/m2 4.34E+10 3.66E+10 3.36E+10 GPa 76.93 58.98 58.82 GPa 50.92 43.10 43.65 GPa 86.16 66.04 68.13 GPa 95.61 84.25 100.57 c13D c33D c44D = c55D Y11E Y33E Y11D Y33D N/m 93 Appendix 2 – PZT Type 5a Material 94 Appendix 3 – PZT Type 8 Material 95 Appendix 4 – Matlab Simulink Code 96 97 98