The Atomic Nucleus Bloomfield Sections 14.1, 14.2, and 14.3 (download) 4/13/04 ISP 209 - 13A 1 What is matter made of? Physics is a reductionist science. Beneath the surface, nature is simple! All matter is composed of elements. There are 91 stable elements, and about 20 more unstable elements which decay by radioactive processes. 4/13/04 ISP 209 - 13A 2 1 4/13/04 ISP 209 - 13A 3 The Atom How big is an atom? How can we measure the size of an atom? What fundamental factors determine the size of an atom? 4/13/04 ISP 209 - 13A 4 2 Jean Baptiste Perrin and Avogadro’s number N Perrin used Brownian motion to measure Avogadro’s number, in 1909. The theory had been worked out in 1905 by Einstein. Brownian motion is the random jittery motion of a small particle suspended in a fluid, due to collisions with the molecules of the fluid. The properties of the motion depend on temperature, molecular weight, and number density. From the observations Perrin could deduce the value of N. He got the Nobel prize in 1926. Today N is determined by X-ray scattering. N = 6.02 x 1023 atoms 4/13/04 ISP 209 - 13A 5 How big is an atom? The mass density of solid carbon (diamond) is 3.52 g/cm3. Calculate the number density The volume occupied by a single carbon atom in diamond is V = 1/n ; the atomic radius R is related to V by V = 4/3 π R3. 4/13/04 n= ρ atomic mass = 3.52 g/cm 3 12 g/mol mol 6.02 × 10 23 atoms = 0.293 × cm 3 1 mol 23 = 1.77 × 10 atoms/cm 3 ISP 209 - 13A 1/ 3 3V ⎞ atomic radius = ⎛⎜ ⎟ ⎝ 4π ⎠ = 1.10 × 10 −8 cm 6 3 Result: The typical order of magnitude of an atomic radius is 10−10 m = 0.1 nm. What determines this size? It comes from the quantum dynamics of electrons interacting with the Coulomb force of attraction to the nucleus. Simplest example is a hydrogen atom. potential energy V (r ) = kinetic energy K = − e2 4πε 0 r p2 1 ⎛ h ⎞ = ⎜ ⎟ 2m 2m ⎝ 2πr ⎠ 4/13/04 2 Heisenberg Uncertainty Principle ISP 209 - 13A 7 kinetic energy K(r) ∝ 1/r2 The state of lowest energy has radius = Bohr radius h2 4πε 0 = me 2 (2π )2 E(r) V(r) ∝ −1/r = 0.53 × 10 −10 m potential energy Full quantum theory – the Schroedinger equation. 4/13/04 ISP 209 - 13A 8 4 4/13/04 ISP 209 - 13A 9 The Atomic Nucleus The discovery of the nuclear structure of the atom. 4/13/04 ISP 209 - 13A 10 5 4/13/04 ISP 209 - 13A 11 Rutherford scattering Scatter alpha particles (produced by a decay of polonium) from a thin gold foil. The observation of large-angle scattering implies that the atom has a very small massive core — the nucleus. 4/13/04 ISP 209 - 13A 12 6 corresponding scattering angle α – Au scattering Rutherford calculated the scattering rate based on classical mechanics for the scattering process, assuming all the positive charge of the Au atom is concentrated in a nucleus. varying impact parameter The result is perfect agreement with the measured scattering rate. 4/13/04 ISP 209 - 13A 13 How big is the nucleus? What determines its size? From electron-nucleus scattering, we know that the radius R of a nucleus is approximately given by the formula R = (1.2 fm )A1/ 3 A = the number of nucleons That is, A ∝ R3 ; because the nucleons are packed pretty densely in the nucleus. nuclear radius ~ 10−5 x atomic radius 4/13/04 ISP 209 - 13A 14 7 Dictionary Nucleus: The massive and positively charged particle at the center of an atom Electron: The negatively charged constituent of atoms. Proton: The positively charged constituent of nuclei. Neutron: The electrically neutral constituent of nuclei. particle Charge Mass Electron −e 9.109 381 88(72) × 10−31 kilogram Proton +e 1.672 621 58(13) × 10−27 kilogram Neutron 0 1.674 92 x 10−27 kilogram The electron is much lighter than the proton. The neutron is slightly heavier than the proton. 4/13/04 Isotopes ISP 209 - 13A 15 Each nucleus is characterized by 2 numbers: Z = number of protons A = number of nucleons (protons and neutrons) Chart of the Nuclides 4/13/04 ISP 209 - 13A 16 8 proton neutron Isotopes hydrogen 1 1 H 3 1 He 4 2 H 3 2 helium carbon 2 1 H 12 6 C Z=1 He 13 6 C Z=2 14 6 C Z=6 Z=92 uranium 235 92 U 238 92 U and others 4/13/04 ISP 209 - 13A 17 4/13/04 ISP 209 - 13A 18 9 Radioactive decays 238 92 U → Th + α 234 90 α decay 9 half - life = 4.5 × 10 yr 14 6 C → 14 7 N + e +ν β decay half - life = 5730 yr 4/13/04 Half life ISP 209 - 13A 19 We cannot predict with certainty when an unstable nucleus will decay. Radioactive decay is a random process like dice. The half life τ is the mean time for one-half of the atoms in a radioactive sample to decay. Dating t N (t ) ⎛ 1 ⎞ τ =⎜ ⎟ N (0 ) ⎝ 2 ⎠ " age" = t = τ × log[N (0) / N (t )] log[2] Measure N(t)/N(0), i.e., fraction of the unstable isotope that remains at time t. The “age” is the time that has passed since the death of the plant. 4/13/04 ISP 209 - 13A 20 10 4/13/04 ISP 209 - 13A 21 THE STRONG NUCLEAR FORCE α particle = a nucleus of helium P N N P What holds it together? The electric force of two protons is a repulsion (like charges repel). But the nuclear force (between pp or pn or nn) is an attraction, and is much stronger than the electric force. What are the fundamental forces? 4/13/04 ISP 209 - 13A 22 11