Direct and Inverse CO Modeling in Santiago de Chile Francisca Muñoz Bravo http://www.cmm.uchile.cl/umesam MSc Computer Science Centro de Modelamiento Matematico (CMM) Universidad de Chile (UMR CNRS 2071) E-mail: fmunoz@dim.uchile.cl Outlook Objectives Emission Inventory Observations What do we want to improve? How to improve it? To Do’s La Serena November 2004 8 CO monitoring stations Objective 1.30 1.20 1.10 1.00 * Flujo variable normalizado 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 39x39 grid of 2x2km2 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 Hora CO Emission inventory by hours, street bows -> grids of any size La Serena November 2004 Emission Inventory MODEM is a model for the calculation of vehicle emissions (CO, PM, HC, NOx, NO2, NH3, CH4, CC). Bottom-up methodology to estimate emissions produced by on-road mobile sources in urban areas Temporal Variation: Emissions are considered the same from Monday to Friday. Weeks and months are invariable. 1.30 1.20 1.10 1.00 Flujo variable normalizado 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 0 1 2 3 4 5 6 7 8 9 10 11 12 Hora La Serena November 2004 13 14 15 16 17 18 19 20 21 22 23 Parque O’Higgins Diurnal Variation Santiago CO Observations Interannual Variation Hourly air quality data are available online, starting on 1997 These data include: CO, PM10, PM2.5, NO2, SO2, O3 at 8 stations The stations are run by health authorities. The measurements and the data are subject to independent assessments on a regular basis. La Serena November 2004 www.sesma.cl MATCH + 0.1°x0.1° Validating the Scenario La Serena November 2004 What do we want to Improve? Magnitude by Zones Sector 1 Providencia Vitacura Las Condes Lo Barnechea Sector 2 Ñuñoa La Reina Macul Peñalolén Sector 3 Santiago Estación Central Sector 4 Huechuraba Recoleta Independencia Conchalí Sector 5 Renca Quinta Normal Cerro Navia Lo Prado Pudahuel Quilicura Sector 6 Maipú Cerrillos Lo Espejo Pedro Aguirre Cerda La Serena November 2004 Sector 7 San Miguel San Joaquín La Cisterna La Granja Sector 8 San Ramón La Pintana El Bosque San Bernardo Sector 9 La Florida Puente Alto What do we want to Improve? Determine if there is Weekly or Monthly variation Analize if the Diurnal estimated variation corresponds La Serena November 2004 Inverse Modeling How to Improve the Inventory? BLUE (Best Linear Unbiased Estimator) Computationally inexpensive least square method. Minimizes distance between observations and model results, and errors. MATCH Adjoint Adjoint Dispersion Model from SMHI Goes back in time through the derivate. Difficulty: Sources are co-located with the measurement stations La Serena November 2004 Inverse Modeling BLUE Validation Parameters: Diurnal Variation Real Emissions: Fictitious scenario that generated the observations Errors: 20% observations, 50% parameters La Serena November 2004 Inverse Modeling MATCH Adjoint Validation Parameters: Temporal and Geographical variation Real Emissions: Fictitious constant scenario that generated the observations Errors, Initial Guess: Non applicable La Serena November 2004 To Do Forward Runs: Improve representation of meteorological fields (dynamical interpolation and by data assimilation of surface wind data). Earlier runs for getting stable I.C. BLUE: Useful light weighted technique. MATCH Adjoint: further explorations with more iterations and usage of initial guess. La Serena November 2004 Emission Inventory MODEM is a model for the calculation of vehicle emissions (CO, PM, HC, NOx, N2O, NH3, CH4, CC). Bottom-up methodology to estimate emissions produced by on-road mobile sources in urban areas CO EMISSIO NS 100% 80% 60% 20% O TE CA R M U C A G U P CE O N La Serena November 2004 C V AL P 0% M Light-w CAT-P 40% R Light-w NO CAT Boundaries Parallel MATCH La Serena November 2004 Topography and Dispersion Santiago is a mega-city of 6 million inhabitants, located within a basin surrounded by the high mountain chains, which reaches maximum values of 4.500 m.a.s.l. Stable conditions prevail all year around. This is further enhanced by coastal lows, which are associated with severe pollution episodes. La Serena November 2004 Geography and Termic Inversion La Serena November 2004