Chapter 25 25.1 Marie Curie was a Polish scientist whose research led to many discoveries about radiation and radioactive elements. In 1934 she died from leukemia caused by her long-term exposure to radiation. You will learn about the various types of radiation and their effects. 25.1 Marie Curie (1867-1934) and Pierre Curie (1859-1906) were able to show that rays emitted by uranium atoms caused fogging in photographic plates. Marie Curie named the process by which materials give off such rays radioactivity. The penetrating rays and particles emitted by a radioactive source are called radiation. 25.1 Nuclear reactions differ from chemical reactions in a number of important ways. In chemical reactions, atoms tend to attain stable electron configurations by losing or sharing electrons. In nuclear reactions, the nuclei of unstable isotopes, called radioisotopes, gain stability by undergoing changes. In the periodic table, radioactive elements have mass numbers in parentheses. Reference table N 25.1 ◦ An unstable nucleus releases energy by emitting radiation during the process of radioactive decay. 25.1 Types of Radiation ◦ What are the three main types of nuclear radiation? 25.1 The three main types of nuclear radiation are alpha radiation, beta radiation, and gamma radiation. Reference table O 25.1 ◦ Alpha Radiation Alpha radiation consists of helium nuclei that have been emitted from a radioactive source. These emitted particles, called alpha particles, contain two protons and two neutrons and have a double positive charge. Note: In a nuclear decay equation, mass and charge are conserved! 25.1 25.1 ◦ Beta Radiation An electron resulting from the breaking apart of a neutron in an atom is called a beta particle. 25.1 Carbon-14 emits a beta particle as it undergoes radioactive decay to form nitrogen-14. 25.1 25.1 ◦ Gamma Radiation A high-energy photon emitted by a radioisotope is called a gamma ray. The high-energy photons are electromagnetic radiation. 25.1 Alpha particles are the least penetrating. Gamma rays are the most penetrating. 25.1 25.2 Radon-222 is a radioactive isotope that is present naturally in the soil in some areas. It has a constant rate of decay. You will learn about decay rates of radioactive substances. Radioactive substances decay at a constant rate regardless of factors such as temperature and concentration. Radioactive decay is a random event. Decay continues until a stable isotope is formed. ◦ Some radioisotopes have a long decay series. 25.2 Stable Isotope The time it takes for half the atoms in a sample to decay is called the half-life. Each isotope has its own unique half-life. The shorter the half-life, the less stable it is. Reference table N If a 100 g sample has a half-life of 5 days: ◦ ◦ ◦ ◦ ◦ After 5 days ½ (50g) will remain undecayed After 10 days ¼ (25g) will remain undecayed After 15 days 1/8 (12.5g) will remain undecayed After 20 days 1/16 (6.25g) will remain undecayed And so on… 25.2 The ratio of Carbon-14 to stable carbon in the remains of an organism changes in a predictable way that enables the archaeologist to obtain an estimate of its age. Radioactive decay is measured with a Geiger counter. ◦ A Geiger counter records individual decay events. Graphing decay allows determination of the half-life. 25.2 Transuranium elements are synthesized in nuclear reactors and nuclear accelerators. The conversion of an atom of one element to an atom of another element is called transmutation. What are two ways that transmutation can occur? Transmutation can occur naturally by radioactive decay. ◦ a single nucleus undergoes decay Transmutation can also occur artificially when particles bombard the nucleus of an atom. ◦ at least two reactants produce the target material A nucleus is bombarded with high-energy particles to bring about a change. Two types: ◦ Bombarding with charged particles: protons or alpha particles. Particle accelerators use magnetic or electrostatic fields to accelerate particles towards the target. Cern video ◦ Bombarding with neutrons. Neutrons are obtained as by-products of nuclear reactors. The first artificial transmutation reaction involved bombarding nitrogen gas with alpha particles. The elements in the periodic table with atomic numbers above 92, the atomic number of uranium, are called the transuranium elements. ◦ All transuranium elements undergo transmutation. ◦ None of the transuranium elements occur in nature, and all of them are radioactive. 25.3 The sun is not actually burning. If the energy given off by the sun were the product of a combustion reaction, the sun would have burned out approximately 2000 years after it was formed, long before today. You will learn how energy is produced in the sun. 25.3 Nuclear Fission ◦ What happens in a nuclear chain reaction? 25.3 When the nuclei of certain isotopes are bombarded with neutrons, they undergo fission, the splitting of a nucleus into smaller fragments. 25.3 ◦ In a chain reaction, some of the neutrons produced react with other fissionable atoms, producing more neutrons which react with still more fissionable atoms. 25.3 Nuclear Fission 25.3 A Nuclear Power Plant 25.3 Nuclear Waste ◦ Why are spent fuel rods from a nuclear reaction stored in water? 25.3 Water cools the spent rods, and also acts as a radiation shield to reduce the radiation levels. 25.3 Nuclear Fusion ◦ How do fission reactions and fusion reactions differ? 25.3 Fusion occurs when nuclei combine to produce a nucleus of greater mass. In solar fusion, hydrogen nuclei (protons) fuse to make helium nuclei and two positrons. 25.3 ◦ Fusion reactions, in which small nuclei combine, release much more energy than fission reactions, in which large nuclei split. 25.3 The use of controlled fusion as an energy source on Earth is appealing. The potential fuels are inexpensive and readily available. The problems with fusion lie in achieving the high temperatures necessary to start the reaction and in containing the reaction once it has started. 25.4 In a smoke detector, radiation from the Americum nuclei ionizes the nitrogen and oxygen in smoke-free air, allowing a current to flow. When smoke particles get in the way, a drop in current is detected by an electronic circuit, causing it to sound an alarm. You will learn about some of the other practical uses of radiation. C-14 is used to date fossils. U-238 is used to date rocks. Radioisotopes are used to trace chemical pathways in biological systems. Radioisotopes are used to determine minute thicknesses such as plastic wrap and aluminum foil. Gamma radiation is used to irradiate foods to kill bacteria and make the foods last longer. Radioisotopes with short half-lives that are quickly eliminated from the body are used as tracers in medical diagnoses and treatments. ◦ I-131 is used to detect and treat thyroid disorders. ◦ Co-60 is used in cancer treatments. ◦ Tc-99 is used to detect tumors. 25.4 This scanned image of a thyroid gland shows where radioactive iodine-131 has been absorbed. In medical treatments radiation can destroy normal cells as well as cancerous cells. Radiation leaking from a nuclear power plant can cause mutations that could be inherited. Spent fuel rods are a disposal concern. They are still radioactive and potentially dangerous.