Die Casting Basics Die is closed. Metal is drawn in to tool (plunger). Metal solidifies under pressure. Tool injects metal into cavity. Die is opened. Casting removed. Cavity continues to fill. (fractions of a second) Machine recovers to initial orientation (cycle starts over) Properties: Pb-Sb vs. Zn-Al L35 Pb-Sb Alloy Zamak 3 Zn-Al Alloy 11.04 6.6 3.36 1.17 252-299 381 - 387 133.1 418.7 Thermal expansion ( um/m per ºC at 20-100 ºC) 27.8 27.4 Thermal conductivity ( cal/cm2/cm/ ºC/sec at 70-140ºC ) .073 .27 Viscosity (poise) .032 .01 Density ( g/cm^3) at 21ºC Solidification shrinkage ( % ) Freezing range ( ºC ) Specific heat capacity ( J/kg/ºC ) at 20 - 100 ºC Stage III: Temperature Monitoring Overview Nozzle temperature Die temperature Nozzle freezing Thermal expansions Holding pot temperature Temperature gradients Excess superheat Results: Injection Pressure Monitor weight as a function of pressure Decreasing Pressure: Pressure Dependency Analysis Reduces flashing Decreases machine errors Weight variation for each setting < 1% *Tolerance (41.24 – 43.80g) Molten metal leaking through the gap is called ‘flashing’. Assume the upper and lower mold pieces have opposing faces which are perfectly smooth, but 3 with a gap of thickness 10 5 m.. Consider if a Zn melt is pressurized to 3 10 Pa while 5 atmospheric pressure is 1 10 Pa. The viscosity of the Zn is 0.003 Pa s. Determine the steady state volume flow rate through the mold gap if the circumference of the cylindrical mold is 6 m and the distance from the inside of the mold to the outside of the mold is 0.2 m. Assume laminar flow. Hint: think about flow between parallel plates. VolumeFlowRate 2 P 3 W 3 L Upper Mold Atmospheric Pressure Lower Mold Mold gap Pressurized Molten Metal Solution : The volume flow rate is given by the average velocity multiplied by the cross section of flow, which is the same as the velocity profile integrated over the gap thickness multiplied by the width of the gap, W VolumeFlowRate 2 P 3 W 3 L where is the half thickness of the gap and W is the width (circumference in this case) 3 5 VolumeFlowRate 2 P 3 W 3 L 0.5 10 m P 2 10 Pa 0.003 Pa s W 6 m 3 VolumeFlowRate 0.167 m s L 0.2 m Upper Mold Atmospheric Pressure Pressurized Molten Metal L(t1) L(t2) L(t3) L(t4) Lower Mold Mold gap The above problem is concerned with steady state flow of molten metal through the mold gap. Of greater interest is the time required for the molten alloy to reach the outside of the mold after it is first injected into the mold. We can estimate that time by letting L be the distance between the melt and the tip of the flow through the mold gap and assuming that the rate of change of the of L is the average rate of flow between parallel plates. Note that this is an approximate solution to this problem. AverageFlowRate P 2 2 d y dy L( t ) 2 2 L( t) dt 1 After integration with respect to y P d L( t) dt 3 L( t ) 2 Solving the differential equation by integration L L( t( t) ) d L 0 1 2 L 2 2 P t 1 d 3 0 P 3 2 t The approximation that the liquid:air interface velocity is equal to the average velocity of the steady stae profile was introduced by E. W. Washburn, Physical Review, vol. 17, pp. 213-283, 1921. P 1 2 L 2 3 2 t The solutions for L from the Mathcad symbolic solver ('symbolics' on the tool bar, then variable and then solve) are 1 1 1 2 2 6 P t 3 1 1 1 2 2 6 P t 3 Picking the positive one 1 L 1 3 1 6 P t 2 2 t 0 0.001 0.01 1 1 L( t) 1 6 P t 2 2 3 0.4 L( t ) 0.2 m 0 0 0.005 t 0.01 s Looks like it will take about 0.005 seconds for the molten metal to begin flashing through the mold wall gap given the parameters defined above. Further discussion of the planar interface approximation. Flow profile is disturbed at the fluid air interface Fluid Air Average velocity must be equal for incompressible fluid Complications regarding the shape of the moving solid vapor interface. Meniscus Formation Represent the surface tensions of a multi-phase junction as vectors drawn parallel to the respective surfaces The surface energies for the for the solid/liquid, the solid/vapor and the liquid/vapor interfaces are γsl, γsv, γlv γlv γsv θ γsl The contact angle θ is a measure of the magnitude of the solid liquid interface energy compared to the solid vapor and liquid vapor energies. Youngs’ Equation Represent the surface tensions of a multi-phase junction as vectors drawn parallel to the respective surfaces The surface energies for the for the solid/liquid, the solid/vapor and the liquid/vapor interfaces are γsl, γsv, γlv. The vectors representing these surface energies must balance at the three phase triple junction. This equation representing this balance is known as ‘Youngs’ equation” γlv γsv θ γsl sv sl cos( )lv γlv γsv γsl Large γsl, non-wetting θ Large γlv γsv θ γsl Large γsv, wetting θ small θ Interface shapes for ‘wetting’ and non-wetting contact angles Liquid Liquid Vapor Vapor