Properties of Water Chapter 2 Section 2 Objectives Discuss the unique properties of water Differentiate between solutions and suspensions Explain what acidic solutions and basic solutions are The Water Molecule Its properties and functions stem from its chemical structure It is one of the few compounds found in a liquid state over the Earth’s surface It is a neutral molecule Is essential for all biological processes Structure of Water Made of 2 hydrogen atoms covalently bonded to 1 oxygen atom Polarity The electrons are not shared equally between the oxygen atom and the hydrogen atoms This unequal sharing causes partial charges to occur at opposite ends of the molecule A molecule in which the charges are unevenly distributed is called polar The polarity of water molecules also gives it a bent shape Hydrogen Bonding Because of polarity, water molecules are attracted to each other They form hydrogen bonds between the partial positive charge of the hydrogen atoms of one molecule to the partial negative charge of oxygen on another molecule Hydrogen bonds are the force of attractions between hydrogen molecules and other atoms such as oxygen, nitrogen & fluorine These bonds form, break , and reform with great frequency Polarity of water and hydrogen bonding are responsible for the other properties of water Properties of Water Cohesion Adhesion Heat Capacity Solvent nature Cohesion Cohesion is an attraction between molecules of the same substance Water molecules can be involved in as many as 4 hydrogen bonds at the same time, making it extremely cohesive Cohesion causes water molecules to be drawn together, which is why drops of water forms beads on a smooth surface It is also responsible for surface tension which makes water acts as if it has a thin “skin” on its surface Surface tension also enables small creatures such as spiders and water-striders to run on water without breaking the surface Adhesion Adhesion is the attractive force between molecules of different substances For example: water molecules and glass molecules The surface of water becomes curved because the attraction between the water and glass molecules is greater than the cohesion between water molecules Adhesion between water and glass molecules also cause water to rise in a narrow tube against the force of gravity This affect is called capillary action Plants use capillary action to draw water from its roots to its leaves Cohesion and Adhesion in Action Trip to ISS Mini Lab! How many drops of water can you get on a penny before it spills over? Heat Capacity Due to multiple hydrogen bonds between water molecule, it takes a large amount of heat energy to speed those molecules up and create a rise in temperature Water’s heat capacity, the amount of heat energy required to increase temperature, is relatively high This allows: Bodies of water to absorb large amounts of heat with only small changes in temperature Cells to regulate temperature Stabilizing of global temperatures Evaporative cooling Water Mixtures Water is not always pure It is often part of a mixture A mixture is a material composed of two or more elements that are physically combined and not chemically combined For example: Salt & pepper Sugar & sand Air Living things are mixtures involving water Two types of mixtures with water: Solutions Suspensions Solutions A solution is a mixture in which 1 or more substances are uniformly distributed in another substance They can be mixtures of liquids, solids, or gases For example: Blood Plasma They are made up of two components: the solute & the solvent Water’s polar nature allows it to dissolve polar substances Examples: sugar, ionic compounds, some proteins Solute vs. Solvent Is a substance dissolved in the solvent Is the substance that does the dissolving Can be ions, atoms, or molecules that are dispersed Example: water (universal) In a solution of sugar water, sugar is the ___________ and water is the ____________. Solutions Continued Solutions can have varying concentrations which is the amount of solute in a certain amount of solvent Example: 5% saltwater solution is 5g of salt dissolved into 100 mL of water Saturated solution: is one in which no more solute can dissolve Aqueous solution: is one in which water is the only solvent Suspensions Some materials do not dissolve when placed in water, but separate into pieces so small that they do not settle out The movement of the water molecules keeps the small particles suspend Mixtures of water and undissolved material are called suspensions Some of the most important biological fluids are both solutions and suspensions For example: blood Blood as a Solution & Suspension Ionization of Water Occurs when water molecules are pulled apart or dissociate into ions Hydroxide ion When this happens it leaves hydrogen to bond with another water molecule forming the hydronium ion Hydrogen ion pH Chemists devised a measuring system called the pH scale to indicate the concentration of H+ ions in solution The pH scale ranges from 0 to 14 Each step on the pH scale represents a factor of 10 pH Determinations The pH of a solution is determined by the amount of hydrogen ions or hydroxide ions present At a pH of 7, the concentration of the H+ ions and OH- ions is equal so its called neutral Solutions with a pH below 7 are called acidic because they have more H+ ions than OH- ions Solutions with a pH above 7 are called basic because they have more OH- ions than H+ ions Acids & Bases Acids Bases Is any compound that forms H+ ions in solution Is any compound that forms OH- ions in solution Strong acid pH values range from 1 to 3 Strong base pH values range from 11 to 14 Tend to have a sour taste Can be corrosive Tend to have a bitter taste For example Tend to feel slippery HCl H2SO4 For example: NaOH NaHCO3 Buffers The pH of the fluids within most cells in the human body must generally be kept between 6.5 and 7.5 If the pH is higher or lower it affects the chemical reactions within the cells Controlling pH is a matter of homeostasis and is done using buffers Buffers are weak acids or bases that can react with strong acids or bases to prevent sudden changes in pH For example: bicarbonate and phosphate ions