The Periodic Table The most important document in chemistry Learning objectives Define group and period as related to periodic table Describe properties of metal, semimetal and nonmetal Write names and symbols of several common elements Predict type of element from position in periodic table Elements: names and symbols All elements have a name and a symbol (one or two letters) Symbols are used in writing compound formulae and chemical equations It is essential to be familiar with both names and symbols for the important elements Common elements and symbols - obvious Carbon Calcium Chlorine Nitrogen Oxygen Aluminium Phosphorous Common elements and symbols – less obvious Sodium Potassium Iron Mercury Silver Gold Tungsten 1869 Dimitri Mendeleev developed the periodic table Ordered elements according to atomic weights and physical and chemical properties. Only about 60 elements had been identified Predicted existence of as-yetundiscovered elements and their properties. Predictions often proved astonishingly accurate. The modern periodic table There are 92 naturally occurring elements: 2 liquids, 11 gases, 23-25 nonmetals Reduce chemistry of all elements to discussion of group behaviour 1A ALKALI METALS: Reactive. Reactivity increases down group. Physical properties vary gradually. 2A ALKALINE EARTH METALS : Similar to alkalis but less reactive. Lots of common calcium compounds: calcium carbonate (limestone, marble), calcium oxide (lime), calcium sulphate (gypsum, plaster of Paris) Important groups on other side of table 7A HALOGENS: Very reactive, form lots of compounds with most elements. Chlorides in particular are common: NaCl, KCl. Reactivity decreases down group 8A RARE, INERT, NOBLE GASES: Discovered late because of lack of compounds, all gases. Not “rare” since 1 % argon in air; He second most abundant element in universe. Very unreactive. Provide insight into properties of other elements The Periodic Table: two main types of element: metals - are shiny, lustrous; good conductors of heat and electricity. Only one metal is a liquid at room temp. The Periodic Table: nonmetals - insulators (or perhaps semiconductors), poor heat conductors mostly. Solids are brittle. Several are gases, one is a liquid. The Periodic Table: semimetals – borderline cases Some properties are metal-like Other properties are nonmetal-like Semiconductors Atoms and ions Ions are charged particles with more or less electrons than protons Positive ion (cation) has fewer electrons Negative ion (anion) has more electrons Ions and compounds Ions are important in one class of compounds Metals form positive ions Nonmetals form negative ions Periodic table can be used to predict charges Rules to predict ion charge Cation Charge = group number Anion Charge = - (8 - group number) Practice with a few examples