CHANGES IN MATTER: PHYSICAL AND CHEMICAL CHANGES EQ: How are changes in matter related to changes in energy? CHANGES IN MATTER You are at the beach You built a sandcastle! You notice storm clouds gathering in the distance. You are sad : ( You know your sandcastle is about to go bye-bye. You look at your shoulders, You are getting sunburned. The creation of sand art, the gathering clouds and your sunburn are all examples of changes in matter. Chemistry is mostly the study of the changes in matter. We will be studying these changes as we answer the question: How are changes in matter related to changes in energy? PHYSICAL CHANGES In what ways can matter change? A physical change is any change that alters the form or appearance of matter. But does not make any substance in the matter into a difference substance. PHYSICAL CHANGES For example, when making your sandcastle, you changed your formless pile of sand into a work of art. However, despite the change in form, the sand is still sand. PHYSICAL CHANGES--MATTER CAN PHYSICALLY CHANGE IN SEVERAL WAYS Change of State Matter occurs in four states: solids, liquids, gases and plasma. Suppose you leave a puddle of liquid water on your kitchen counter (bad 8th grader!) When you come back, the puddle is gone! What happened? Did the liquid disappear? Did your mother wipe it up for you (bad 8th grader!)? It may have evaporated and become water vapor, a gas. A change in state, from a liquid to a gas is an example of a physical change. The water is still water. Examples: melting, freezing, condensing, evaporating, sublimating Change in Shape or Form Is there a physical change when you make sweet tea the right way? To be sure, you would need to know if the sugar has been changed into a different substance. If you pour the tea into a pan, boil the solution dry, you would find a sugar crust at the bottom. The sugar looks different, but it is still sugar. Other physical changes are: bending, crushing, breaking, chopping, dissolving, distilling CHEMICAL CHANGES Chemical changes happen on a much smaller scale. While some experiments show obvious chemical changes, such as a color change, most chemical changes are not visible. A change in matter that produces one or more new substances is called a chemical change, or a chemical reaction. In some chemical changes, a single substance simply changes to one or more substances. In other chemical changes, two or more substances combine to form different substances. CHEMICAL CHANGES One substance changes to one or more other substances Hydrogen peroxide (H2O2) when poured on to a cut on your skin, it breaks down into water (H2O) and oxygen gas (O2) The chemical change as hydrogen peroxide becomes water cannot be seen since both liquids are clear. However, behind the scenes, billions of chemical bonds are being created and destroyed. In this example, you may see bubbles of oxygen (O2) gas. Those bubbles are evidence of the chemical changes. Two substances combine to form different substances. Iron (Fe) rusts when it is exposed to oxygen gas in the air. You can watch the process happen over a long period of time. The molecules change their structure as the iron is oxidized, eventually becoming iron oxide (Fe2O3) Rusty pipes in abandoned buildings are real world examples of the oxidation process. EVIDENCE OF CHEMICAL CHANGES Chemical Changes involve a change in chemical composition in the substances and something new is formed. These changes are difficult to reverse Some signs (or evidence) of chemical change are: Bubbling Light given off Change in temperature Color change New odor Decomposition ENDOTHERMIC AND EXOTHERMIC CHANGES When matter changes, the most common form of energy released or absorbed is thermal (heat) energy. For example, ice absorbs energy from its surroundings as it melts. The melting of ice is called an endothermic change. ENDOTHERMIC AND EXOTHERMIC CHANGES An endothermic change is a change in which energy is taken in/absorbed. Examples: Melting Evaporation Boiling ENDOTHERMIC AND EXOTHERMIC CHANGES Changes in matter can also occur when energy is given off Exothermic changes are chemical reactions that produce heat Examples: Combustion Steam condensing to liquid water Fire PHYSICAL AND CHEMICAL CHANGES SORT EQ: How are changes in matter related to changes in energy? http://glencoe.mheducation.com/sites/dl/free/00786004 72/160350/00044680.html Physical Change Chemical Change No new substance formed At least one new substance. Temporary No change in the mass of the substances undergoing changes Permanent Mass/ matter in = mass/matter out CHANGES IN MATTER --- LAW OF CONSERVATION OF MASS/MATTER EQ: How are changes in matter related to changes in energy? CONSERVATION OF MASS/MATTER A candle may seem to “go away” when it’s burned or water may seem to “disappear” when it changes into a gas. However, scientists proved otherwise long ago. The Law of Conservation of Mass/Matter states that matter is neither created nor destroyed in any chemical or physical change. The mass of the stuff that you make in a chemical reaction is the same as the mass of the stuff that you start with LAW OF CONSERVATION OF MASS/MATTER For example --- my world’s famous chili: Despite the cutting, chopping, dicing, browning and simmering … The mass of the chili I serve is equal to the mass of the ingredients I put into the chili. As it is with chili, so it is with chemical reactions. BALANCING CHEMICAL EQUATIONS One way to show this rearrangement of molecules is to balance a chemical equation. When you balance an equation, it is easy to see how atoms are not lost during a chemical change, but that they are rearranged BALANCING CHEMICAL EQUATIONS There are four easy steps that you need to follow to make this work. Here they are: 1. Get yourself an unbalanced equation. 2. Draw boxes around all the chemical formulas. Never, ever, change anything inside the boxes. Ever. Really. If you do, you're guaranteed to get the answer wrong. 3. Make an element inventory. How are you going to know if the equation is balanced if you don't actually make a list of how many of each atom you have? You won't. You have to make an inventory of how many atoms of each element you have, and then you have to keep it current throughout the whole problem. 4. Write numbers in front of each of the boxes until the inventory for each element is the same both before and after the reaction. Whenever you change a number, make sure to update the inventory - otherwise, you run the risk of balancing it incorrectly. When all the numbers in the inventory balance, then the equation can balance, and you can relax BALANCING CHEMICAL EQUATIONS You know why you need to balance chemical equations, but you don't yet know how to do it. It turns out that I'm star who knows how to explain things in a way that even the dumbest people know how to follow. And, hey, if the dumbest people can figure it out, so can you! BALANCING CHEMICAL EQUATIONS Step : 1 Get yourself an unbalanced equation Done! BALANCING CHEMICAL EQUATIONS Step 2: Draw boxes around all the chemical formulas. This is the step that people frequently don't do. Do it. It makes the difference! You're drawing those boxes so that you'll be sure not to mess around with the formulas to balance the equation. While they all suffer, you'll be laughing. Here's what the equation looks like: BALANCING CHEMICAL EQUATIONS Step 3: Make an element inventory. In this inventory, your job is to figure out how many atoms of each element you have on the left and right sides of the equation. BALANCING CHEMICAL EQUATIONS Step 4: Write numbers in front of each of the boxes until the inventory for each element is the same both before and after the reaction When we put a number in front of a formula anything in that box is multiplied by that number, because we're saying that we have that many of that kind of molecule. BALANCING CHEMICAL EQUATIONS So, looking at the inventory, what should we do? Well, we can see that on the left side of the inventory, there is one atom of sodium and on the right there are two. The solution: Stick a "2" in front of the sodium hydroxide (NaOH) on the left side of the equation so that the numbers of sodium (Na) atoms are the same on both sides of the equation. When we do this, the new atom inventory should look like the figure to the right BALANCING CHEMICAL EQUATIONS Now what? Looking at the new inventory, we can see that we now have two sodium atoms on both the left and the right sides, but the others still don't match up. What to do? BALANCING CHEMICAL EQUATIONS You can see from the inventory that on the right side of the equation, there are two hydrogen (H) atoms and on the left there are four. Using your amazing powers of mathematics (and hopefully you can see that two multiplied by the number two becomes four. That's what you need to do. How? BALANCING CHEMICAL EQUATIONS Put a "2" in front of the water on the right side of the equation to make the hydrogens (H) balance out. Now that this is done, you should make a new inventory that looks something like the figure on the right Since both sides of the inventory match, the equation is now balanced! All other equations will balance in exactly the same way, though it might take a few more steps in some cases. BALANCING CHEMICAL EQUATIONS Step 1 :Get yourself an unbalanced equation Step 2: Draw boxes around all the chemical formulas. Step 3: Make an element inventory. Step 4: Write numbers in front of each of the boxes until the inventory for each element is the same both before and after the reaction NaCl + BeF2 --> NaF +BeCl2 BALANCING CHEMICAL EQUATIONS NaCl + BeF2 --> NaF +BeCl2 Answer: 2 NaCl + BeF -2-> 2 NaF + BeCl2 BALANCING CHEMICAL EQUATIONS CH4 + O 2-> CO2 + H 2 O Step 1 :Get yourself an unbalanced equation Step 2: Draw boxes around all the chemical formulas. Step 3: Make an element inventory. Step 4: Write numbers in front of each of the boxes until the inventory for each element is the same both before and after the reaction BALANCING CHEMICAL EQUATIONS CH4 + O 2-> CO2 + H 2 O Answer: CH4+ 2 O 2 --> CO2 + 2 H 2 O LAW OF CONSERVATION OF MASS/MATTER Suppose you could collect all the carbon dioxide and water produced when methane burns, and you measured the mass of all this matter. You would find that it equaled the mass of the original methane, plus the mass of the oxygen that was used in the burning. No mass was lost, because in a chemically change, atoms are not lost or gained, just simply rearranged. CHANGES IN MATTER: ENERGY AND MATTER EQ: How are changes in matter related to changes in energy? ENERGY AND MATTER Everyone has cooked something at one time or another, You may have wondered why it takes any time at all to cook the food. Why can't you just have instantly cooked potatoes every time? And, you may have also wondered why you needed to get the food hot in order to cook it. Well, both of these questions can be answered through chemical change concepts. ENERGY AND MATTER Like matter, energy is never created nor destroyed. The Law of Conservation of Energy states that energy is never created nor destroyed, it’s changed into another form. FORMS OF ENERGY How do you know if something has energy? You know if someone is running has energy because it is moving. But how about the light and heat from a burning candle? How do you know it has energy? ENERGY AND MATTER We know that energy is the ability to do work or cause change. In the first unit, we focused on energy and the ability to do work. In this unit, we will focus on energy and its ability to cause change. We use energy to physically and chemically change matter FORMS OF ENERGY The forms of energy that can change matter are: Kinetic Potential Thermal Chemical Electromagnetic Electrical FORMS OF ENERGY Kinetic Energy of matter in motion. Rolling bowling ball Running Molecules moving faster when they are being heated – changing state of matter. Atoms and molecules chemically combining to form new compounds – chemical change Potential Energy an object has due to its position Stored energy Bike at the top of a hill. During a change of state of matter, the energy needed to change goes into increasing the total potential energy stored in the chemical bonds between the molecules. FORMS OF ENERGY --- THERMAL (HEAT) The most common form of energy released or absorbed by matter. Total energy of the all particles in an object Higher heat = higher energy Used to describe the temperature of something. Heat is not the same as temperature! Always flows from the warmer matter to the cooler matter CHANGES IN MATTER – THERMAL/HEAT You need heat to make the uncooked food become cooked food. If you don't add heat, then you won't be able to make your baked potato soft or your hard-boiled egg hard! When you increase the temperature of the food, you increase the speed of the molecules in a food. The greater their speed, the more they collide. These collisions between the molecules can lead to changes in molecular structures by creating new molecules. These new molecules have different characteristic colors, flavors, and textures from the original ones. The formation of new molecules is called a chemical reaction. FORMS OF ENERGY --- CHEMICAL Almost anything you touch, see or taste is composed of chemical compounds. The chemical compounds are made up of molecules and atoms Bonds between the atom and the molecules hold chemical compounds together. Those bonds have a chemical energy. Chemical energy is stored in the matches you light up, the food you eat and even in the cells in your body. When bonds in chemical compound break, some new chemical compounds are able to form. When this happens, chemical energy is able to be released. FORMS OF ENERGY -- CHEMICAL Chemical reactions have a set speed There is very little you can do to speed up a reaction without adding heat to raise the temperature. Since hard-boiling eggs (physical change) occurs in a pot of boiling water, adding heat to the pot will only cause the water to boil faster, but not cook the egg any faster. This is because the boiling temperature of water will not change unless either something is added to the water Adding salt to water will increase the boiling temperature of the water (chemical change) Salt, when present in water, lowers the freezing point (causing snow and ice to melt) and raises the boiling point. FORMS OF ENERGY -- CHEMICAL Cooking brings about chemical changes in food. The texture and taste changes when food is cooked. Baking powder contains sodium hydrogencarbonate. This breaks down when heated, releasing carbon dioxide that helps cake mixtures to rise during baking. FORMS OF ENERGY --- ELECTROMAGNETIC Electromagnetic energy travels in waves. In theses waves, the waves have some electrical properties and some magnetic properties. Some examples for electromagnetic energy would be: Sunlight: photosynthesis -- chemical change A microwave : defrosting -physical change FORMS OF ENERGY --- ELECTRICAL Electrical energy is the energy of electrically charged particles moving from one place to another. When an electric current is passed through the filament of a bulb, the filament starts glowing and the glow stops as soon as the current is cut off – physical change LAB: THE ROLE OF ENERGY IN COOKING EQ: How are changes in matter related to changes in energy? PHYSICAL AND CHEMICAL CHANGES The energy used while cooking brings about both physical and chemical changes in food. Physical changes: may be reversible State of matter (solid to liquid, liquid to gas, liquid to solid) Shape and form Chemical changes: hard to reverse New substances are formed when different ingredients are combined Taste Texture Odor EVIDENCE OF CHANGE As these changes occur, evidence may be shown Physical: may be reversible New state of matter New color New shape or form New temperature Chemical: hard to reverse Bubbling New color – bread turns brown when toasted. Sugars in the bread break down when heated. New temperature New odor New taste New texture LAW OF CONSERVATION OF MASS/MATTER The Law of Conservation of Mass/Matter states that matter is neither created nor destroyed in any chemical or physical change. No mass was lost, because in a chemically change, atoms are not lost or gained, just simply rearranged. The mass of the stuff that you make in a chemical reaction is the same as the mass of the stuff that you start with ENERGY AND MATTER Energy is the ability to do work or cause change. We use energy to physically and chemically change matter The forms of energy that can change matter are: Kinetic - molecules move faster when heated Potential - stored energy in molecules waiting to be changed Thermal – heat that changes state of matter (physical). Heat makes molecules move faster, causing them to bump into each other and created new molecules(chemical) Chemical – molecules combine to create new molecules Electromagnetic – sun provides energy for photosynthesis, resulting in food (chemical), microwaves can warm/cook food Electrical TODAY’S LAB Today we will be making pancakes from scratch so that you may see how matter physically and chemically changes when energy is added We will be doing this cooking show style. I have premeasured the ingredients I will use my griddle under the Ladybug and project the image You will note information on your lab sheet This will be an important document for tomorrow’s assignment THE MATTER Materials: 1 ½ cups all-purpose flour 1 ½ cups milk 3 ½ tsp. baking powder 1 egg 1 tsp. salt 3 T. butter, melted 1 T. white sugar In a large bowl, sift together the flour, baking powder, salt and sugar. Make a well in the center and pour in the milk, egg and melted butter. Mix until smooth Heat a lightly oiled griddle over medium high heat. Pour or scoop the batter onto the griddle. Brown on both sides until cooked through. Serve hot