Environmental Science Unit 7 – Energy (STE 7th ed. Chapter ##) In the long run, humanity has no choice but to rely on renewable energy. No matter how abundant they seem today, eventually coal & uranium will run out. ––Daniel Deudney & Christopher Flavin Where are we going? 1. Energy Resources sources, evaluation 2. Oil what is it? supplies, environmental issues 3. Natural Gas what is it? supplies, environmental issues 4. Coal what is it? supplies, environmental issues 5. Nuclear Energy what happened to nuclear power? 6. Renewable Energy what is it? supplies, environmental issues 1. Energy Resources U.S. has 4.6% of world population uses 24% of the world’s commercial energy Changes in US Energy Use Changes in US Energy Use Experience shows that it takes ~50 years to phase in new energy alternatives Questions • what was the basis of the energy economy until 1800? • what was the basis of the energy economy during 1900? • what was the basis of the energy economy during 1960? • what is the projected basis of the energy economy by the year 2025? • what is the projected basis of the energy economy by the year 2100? How to Evaluate Resources • How much available? – Oil will be depleted in 40-80 years • Net energy yield? • Cost to develop, phase in, & use? • Environmental effects of extraction, transport, & use? – Water, air and soil pollution – Land disruption – Global Warming • Sustainability? – General concensus is to improve energy efficiency Net Energy • Suppose that for every 10 units of oil, we have to use and waste 8 units to find, extract, process and transport the oil to users. There are only 2 of useful energy available. – Net Energy = Useful energy produced / Energy used to produce it – 10/8 = 1.25 – The higher the ratio, the higher the net yield OIL • Currently oil has a high net energy ratio since much of it comes from large accessible deposits in the middle east • when the sources deplete the ratio will decrease Net Energy has a low ratio, large amounts of energy are needed to extract and process uranium ore and to build and operate power plants Ratios < 1 = energy loss Questions • what are the noticeable patterns? • how will these current patterns change based on future trends predicted? • what is the primary difference between Solar heating and carbon based fuels? 2. Oil • • fossil fuel, produced by the decomposition of deeply buried organic matter from plants & animals – ‘biogenic theory’ crude oil: complex liquid mixture of hydrocarbons, with small amounts of S, O, N impurities – Only 35-50% can be economically recovered from a deposit. – As prices rise, about 10-25% more can be recovered from expensive secondary extraction techniques – This lowers the net energy yield Oil: Extraction and Processing • • • Extraction: – primary - drill & pump – secondary - inject H2O – tertiary - inject steam or CO2 refine to separate by boiling point: – high: gasoline, aviation fuel – medium: heating oil, diesel – low: grease, wax, asphalt transport by tanker, truck, pipeline Oil: Sources • Organization of Petroleum Exporting Countries (OPEC) - 13 countries have most of the world reserves: – Algeria, Ecuador, Gabon, Indonesia, Iran, Iraq, Kuwait, Libya, Nigeria, Qatar, Saudi Arabia, United Arab Emirates, & Venezuela • other important producers: Alaska, Siberia, & Mexico Oil in US • < 3% of world reserves • uses nearly 30% of world reserves; • 65% for transportation; • increasing dependence on imports Energy: A Definition 1979 Iranian Revolution Oil Prices 1973 Oil embargo 2003 Iraq Invasion 1939-1945 WW2 9/11 1993 Gulf War Oil • • • • • • 1968 – largest oil field in US discovered on Alaska’s North slope (Prudhole Bay) 10-20 x109 barrels Difficult to move oil tankers from Atlantic ocean through NW passage 1977 - Trans-Alaska pipeline to nearest ice-free sea port Production is decreasing Look to Arctic National Wildlife Reserve’s 1002 area (ANWR) Oil: Pros and Cons • Pros – still cheap • Cons – pollution & environmental degradation – GH gases CO2 Emissions Cleaner burning FF CO2 emissions per unit of energy produced for various energy resources. 3. Natural Gas • fossil fuel • mixture of 50–90% methane (CH4), smaller amounts of ethane (C2H6), propane (C3H8), & butane (C4H10), and hydrogen sulfide (H2S) • propane & butane removed as liquefied petroleum gas (LPG); • typically transported by pipelines • much burned or pumped back into ground NG: Sources • Russia & Kazakhstan: almost 40% world's supply • Iran (15%), Qatar (5%), Saudi Arabia (4%), Algeria (4%), United States (3%), Nigeria (3%), Venezuela (3%) • Natural gas is versatile and clean-burning fuel, but it releases the greenhouse gases carbon dioxide (when burned) and methane (from leaks) into the troposphere NG: Pros and Cons • Pros – reserves 65–80 yrs for U.S., 125 years for world at current consumption rates; – burns cleaner, & produces less carbon dioxide than other fossil fuels • Cons – pollution & environmental degradation 4. Coal Coal is a solid fossil fuel that is formed in several stages as the buried remains of land plants that lived 300-400 million years ago Coal: Sources Due to air pollution laws, search for cleaner coal, thicker seams • Coal reserves in the United States, Russia, and China could last hundreds to over a thousand years • The U.S. has 27% of the world’s proven coal reserves, followed by Russia (17%), and China (13%) • In 2005, China and the U.S. accounted for 53% of the global coal consumption Since 1940’s production shifted west, from underground to surface mines Coal • • Coal seams vary in thickness from a few inches to hundreds of feet 60% coal produced by strip mining – ripping tops off mountains Aerial view of a Montana strip mine. Dragline used in strip mine to remove coal. The Washington Post 032008 Coal: Pros and Cons • Pros – most abundant fossil fuel; – high net energy yield; • Cons – dirtiest fuel, highest carbon dioxide – major environmental degradation – major threat to health 5. Nuclear Energy • Nuclear fission is the splitting of a large nucleus into smaller nuclei • Energy is released because the sum of the masses of these fragments is less than the original mass • Heat produced drives a turbine to produce electricity Power from Nuclear Fission Critical Mass • • Self-propagating chain reaction Excess neutrons • With small mass, 1 n are lost 0 • Past 15 kg, reaction is sustained http://www.kscience.co.uk/animations/chain_reaction.swf Power from Nuclear Fission Types of Fission Reactor • Commerical nuclear power is produced using thermal neutrons Fuel rods contain fissile material (natural, enriched, or mixed) Moderator slows down neutrons, increases chances of fission Control rods made from boron absorb 10n Coolant water or gas Steam turbine or generator converts heat into electricity • Different reactors use different coolants, fuel and moderators Small amounts of radioactive gases Uranium fuel Control rods input (reactor Containment shell core) Heat exchanger Steam Turbine Generator Waste heat Hot water output Coolant Cool water input Moderator Shielding Coolant Pressure passage vessel Periodic removal and storage of radioactive wastes and spent fuel assemblies Water Periodic removal and storage of radioactive liquid wastes Electric power Useful energy 25%–30% Waste heat Condenser Water source (river, lake, ocean) Power from Nuclear Fission Water remains liquid due to high pressure Types of Fission Reactor: PWR Expansion of water as T rises reduces number of slow moving n Water = coolant, moderator and n absorber Popular design due to safety record, more economic to run After three or four years in a reactor, spent fuel rods are removed and stored in a deep pool of water contained in a steel-lined concrete container After spent fuel rods are cooled, they are moved to dry-storage containers made of steel or concrete Decommissioning of reactor Fuel assemblies Enrichment of UF6 Conversion of U3O8 to UF6 Reactor Fuel fabrication (conversion of enriched UF6 to UO2 and fabrication of fuel assemblies) Uranium-235 as UF6 Plutonium-239 as PuO2 Spent fuel reprocessing Temporary storage of spent fuel assemblies underwater or in dry casks Low-level radiation with long half-life Open fuel cycle today “Closed” end fuel cycle Geologic disposal of moderate & high-level radioactive wastes What Happened to Nuclear Power? • After more than 50 years of development and enormous government subsidies, nuclear power has not lived up to its promise because: – Multi billion-dollar construction costs. – Higher operation costs and more malfunctions than expected. – Poor management. – Public concerns about safety and stricter government safety regulations • some countries (France, Japan) investing increasingly • U.S. currently ~7% of energy nuclear; • no new U.S. power plants ordered since 1978; 40% of 105 commercial nuclear power expected to be retired by 2015 & all by 2030; • France 78% energy nuclear TMI • March 29, 1979, number 2 reactor near Harrisburg, Pennsylvania lost coolant & core suffered partial meltdown • Majority contained • 50,000 people evacuated & another 50,000 fled area; • unknown amounts of radioactive materials released • partial cleanup & damages cost $1.2 billion so far • released radiation increased cancer rates Movie CNN 2002 Chernobyl • April 26, 1986, reactor explosion (Ukraine) flung radioactive debris into atmosphere • Flawed design • Major world-wide release of radioisotopes due to no secondary containment • 56 immediate + 4000 expected deaths • Encased in concrete Movie CNN 2002 Nuclear: Pros and Cons • Pros – U.S. has major reserves of uranium • Cons – risk of radioactive contaminant leaks – radioactive wastes (short– & long–term) A 1,000 megawatt nuclear plant is refueled once a year, whereas a coal plant requires 80 rail cars a day Nuclear Waste Solutions • Scientists disagree about the best methods for long-term storage of high-level radioactive waste: – Bury it deep underground. – Shoot it into space. – Bury it in the Antarctic ice sheet. – Bury it in the deep-ocean floor that is geologically stable. – Change it into harmless or less harmful isotopes. What’s next? • • General consensus? – To improve energy efficiency Disagreement about the next best option Option 1 – turn to renewable energy resources Option 2 – burn more coal Option 3 – turn to natural gas (cleaner) Option 4 – Nuclear power 6. Renewables 1. Energy efficiency 2. Solar energy 3. Hydropower 4. Wind Power 5. Biomass 6. Solar–hydrogen revolution 7. Geothermal 8. Sustainability Energy Waste • Flow of commercial energy through the U.S. economy • 84% is wasted • 41% due to thermodynamics • 43 % due to efficiency Efficiency Reducing Waste by Improving Efficiency • • • • • • allows nonrenewable fuels to last longer gives time to phase in renewable energy decreases dependence on oil imports reduces environmental damage slows global warming saves money Improving Energy Efficiency • cogeneration • efficient lighting & appliances • increases in vehicle fuel efficiency; use of alternative fuels • better insulation ~86 % wasted Solutions Reducing Energy Waste Prolongs fossil fuel supplies Reduces oil imports Very high net energy Low cost Reduces pollution and environmental degradation Buys time to phase in renewable energy Less need for military protection of Middle East oil resources Creates local jobs Fundamental Sources of Energy FUSION (SOLAR) FISSION Fossil fuels Nuclear energy Wind (man-made) Waves Geothermal Biomass (natural) Hydro Direct solar GRAVITATIONAL PE/KE earthmoon-sun) Tides Renewable Energy Sources (RES) • RES – – – – – – – solar wind waves hydro biomass geothermal tidal Solar derived Capture energy from ongoing natural processes Replaced at a rate equal to or faster than consumption Why Are We Still Wasting So Much Energy? • Low-priced fossil fuels and few government tax breaks or other financial incentives for saving energy promote energy waste Heating Buildings and Water with Solar Energy We can heat buildings by orienting them toward the sun or by pumping a liquid such as water through rooftop collectors Passive or Active Solar Heating Disadvantages Solar: Pros and Cons Advantages Energy is free Net energy is moderate (active) to high (passive) Quick installation No CO2 emissions Need access to sun 60% of time Sun blocked by other structures Need heat storage system Very low air and water pollution High cost (active) Very low land disturbance (built into roof or window) Active system needs maintenance and repair Moderate cost (passive) Active collectors unattractive Using Solar Energy to Generate HighTemperature Heat and Electricity Solar Thermal Systems: (i) Heliostats (power towers) (ii) Concentrators Large arrays of solar collectors in sunny deserts can produce hightemperature heat to spin turbines for electricity, but costs are high Solar Thermal Electric Facilities Figure 12.23: Solar Electric Generating System (SEGS), Kramer Junction, California, provides 165 MW from concentrating collectors shown here. Movie ABC 2006 Producing Electricity with Solar Cells Photovoltaic (PV) cells can provide electricity for a house of building using solar-cell roof shingles. Trade-Offs Solar Cells Advantages Fairly high net energy Disadvantages Need access to sun Work on cloudy days Low efficiency Quick installation Easily expanded or moved Need electricity storage system or backup No CO2 emissions Low environmental impact High land use (solar-cell power plants) could disrupt desert areas Last 20–40 years Low land use (if on roof or built into walls or windows) Reduces dependence on fossil fuels High costs (but should be competitive in 5–15 years) DC current must be converted to AC Producing Electricity from Moving Water Hydropower etc. • hydroelectric dams • tides & waves • ocean thermal energy conversion & solar ponds Trade-Offs Large-Scale Hydropower Advantages Disadvantages Moderate to high net energy High construction costs High efficiency (80%) High environmental impact from flooding land to form a reservoir Large untapped potential Low-cost electricity Long life span High CO2 emissions from biomass decay in shallow tropical reservoirs Floods natural areas behind dam No CO2 emissions during operation in temperate areas Converts land habitat to lake habitat May provide flood control below dam Danger of collapse Provides water for year-round irrigation of cropland Decreases fish harvest below dam Reservoir is useful for fishing and recreation Uproots people Decreases flow of natural fertilizer (silt) to land below dam Wind World’s most abundant energy source Abundant, inexhaustible, widely distributed, cheap, clean, and emits no greenhouse gases Movie CNN 1999 Biomass Plant materials and animal wastes can be burned to provide heat or electricity or converted into gaseous or liquid biofuels Trade-Offs Solid Biomass Advantages Disadvantages Large potential supply in some areas Nonrenewable if harvested unsustainably Moderate costs Moderate to high environmental impact No net CO2 increase if harvested and burned sustainably CO2 emissions if harvested and burned unsustainably Plantation can be located on semiarid land not needed for crops Low photosynthetic efficiency Soil erosion, water pollution, and loss of wildlife habitat Plantation can help restore degraded lands Plantations could compete with cropland Can make use of agricultural, timber, and urban wastes Often burned in inefficient and polluting open fires and stoves Converting Plants and Plant Wastes to Liquid Biofuels: An Overview • • Motor vehicles can run on ethanol, biodiesel, and methanol produced from plants and plant wastes The major advantages of biofuels are: – Crops used for production can be grown almost anywhere – There is no net increase in CO2 emissions. – Widely available and easy to store and transport Trade-Offs Ethanol Fuel Advantages High octane Disadvantages Large fuel tank needed Lower driving range Some reduction in CO2 emissions High net energy (bagasse and switchgrass) Reduced CO emissions Low net energy (corn) Much higher cost Corn supply limited May compete with growing food on cropland Higher NO emissions Can be sold as gasohol Potentially renewable Corrosive Hard to start in cold weather This is actually backwards Geothermal • • Geothermal energy consists of heat stored in soil, underground rocks, and fluids in the earth’s mantle. We can use geothermal energy stored in the earth’s mantle to heat and cool buildings and to produce electricity. Trade-Offs Geothermal Energy Advantages Disadvantages Very high efficiency Scarcity of suitable sites Moderate net energy at accessible sites Depleted if used too rapidly Lower CO2 emissions than fossil fuels Low cost at favorable sites Low land use Low land disturbance Moderate environmental impact CO2 emissions Moderate to high local air pollution Noise and odor (H2S) Cost too high except at the most concentrated and accessible sources Hydrogen • • • • Environmentally Friendly Extraction Storage Fuel Cells Environmentally Friendly Hydrogen Solar/Hydrogen Revolution • Some energy experts view hydrogen gas as the best fuel to replace oil during the last half of the century, but there are several hurdles to overcome: – Hydrogen is chemically locked up in water an organic compounds – It takes energy and money to produce it (net energy is low) – Fuel cells are expensive – Hydrogen may be produced by using fossil fuels Movie ABC 2006 Converting to a Hydrogen Economy • Iceland plans to run its economy mostly on hydrogen (produced via hydropower, geothermal, and wind energy), but doing this in industrialized nations is more difficult. – Must convert economy to energy farming (e.g. solar, wind) from energy hunter-gatherers seeking new fossil fuels – No infrastructure for hydrogen-fueling stations (12,000 needed at $1 million apiece) – High cost of fuel cells Trade-Offs Hydrogen Advantages Can be produced from plentiful water Low environmental impact Renewable if from renewable resources No CO2 emissions if produced from water Good substitute for oil Competitive price if environmental & social costs are included in cost comparisons Easier to store than electricity Safer than gasoline and natural gas Nontoxic High efficiency (45–65%) in fuel cells Disadvantages Not found in nature Energy is needed to produce fuel Negative net energy CO2 emissions if produced from carbon-containing compounds Nonrenewable if generated by fossil fuels or nuclear power High costs (but may eventually come down) Will take 25 to 50 years to phase in Short driving range for current fuel-cell cars No fuel distribution system in place Excessive H2 leaks may deplete ozone in the atmosphere A Sustainable Energy Strategy • What do we mean by sustainable? A Sustainable Energy Strategy • More sustainable energy strategy – improve energy efficiency – rely more on renewable energy – reduce the harmful effects of using fossil fuels and nuclear energy shift from large, centralized macropower systems to smaller, decentralized micropower systems Solutions: A Sustainable Strategy Fuels for the Future? http://news.bbc.co.uk/2/hi/science/nature/7241909.stm