Thermal Capacity Of a particular body is the energy required to raise the temperature of that body by 1°C. Thermal capacity = change in thermal energy temperature change C = ∆Q / ∆T Example 1 A 2 kg cylinder of copper is heated from room temperature (20˚C) to 500ºC. 374kJ of thermal energy were transferred to the copper during the heating process. Calculate the thermal capacity of this piece of copper. Answer: 780J Example 2 A 25kg cylinder of copper is heated from room temerature. The same 374kJ of thermal energy were used during the heating process but this time the copper’s temperature rose from room temperature to only 58.4ºC. Calculate the heat capacity of this piece of copper. Answer: 9740J What is the difference between Ex 1 and Ex2 Specific Heat Adding energy to a material causes the temperature to go up. Taking energy away from a substance causes the temp. to go down! Have you ever noticed that on a hot summer day the pool is cooler than the hot cement? OR maybe that the ocean is cooler than the hot sand? Why? The sun has been beating down on both of them for the same amount of time........... It takes more thermal energy to raise the temperature of water that it does the cement! Specific Heat The amount of energy required to raise the temperature of a material (substance). It takes different amts of energy to make the same temp change in different substances. The specific heat capacity of a particular substance is equal to the energy required to raise the temperature of a 1kg mass of the substance by 1ºC Specific Heat of water The Cp is high because H2O mols. form strong bonds w/each other. It takes a lot of energy to break the bonds so that the the molecules can then start to move around faster (HEAT UP). Example: Specific Heat of Water Cp = 4,184 Joules of energy to raise the temperature of 1kg 1°C. Example 3 A 2kg cylinder of copper is heated from room temperature(20ºC) to 500ºC. 374kJ of thermal energy were transferred to the copper during the heating process. Calculate the specific heat capacity of this piece of copper. Answer: 390J Example 3 A 2kg cylinder of copper is heated from room temperature(20ºC) to 500ºC. 374kJ of thermal energy were transferred to the copper during the heating process. Calculate the specific heat capacity of this piece of copper. Answer: 390J Example 4 A 25kg cylinder of copper is heated from room temerature. The same 374kJ of thermal energy were used during the heating process but this time the copper’s temperature rose from room temperature to only 58.4ºC. Calculate the specific heat capacity of this piece of copper. Answer: 390J Solving for specific heat There are two methods common for measuring the specific heat capacity. Electrical – If an electrical immersion heater is place into a solid or a liquid, then the energy from the heater will be transmitted by conduction into the substance and the substance will get hotter. Mixtures – If a hot object is place next to a cooler one (or placed into it if the cooler one is liquid), then the cooler substance will gain energy and become hotter and the hotter object will lose energy and become cooler until both objects come to the same temperature called thermal equilibrium. Example 5 – electrical A 240V electric heating element is used to heat water. The temperature of the water rose from 20ºC to 50ºC in 4minutes 20 seconds. During the heating process, the current flowing in the heater was measured to be 3.54A. Calculate the mass of the water. Solution First the power rating is Power = Voltage x Current P = V I (I.B. Data booklet page 7) P = 240 x 3.54 = 850W The heater supplies 850J of energy to the water every second (850W= 850J/s). So in 4minutes 20seconds(260s), energy transferred to the water = 850 x 260 = 221x103J. Answer: 1.75kg Example 6 The 850W heater was then placed into a hole in a piece of copper of mass 1.75kg. (A) Calculate the temperature rise in the copper if the heater was left on for 4min 20sec. (B) Calculate the final temperature of the copper if the heater was left on for 10min and the copper was originally at a temperature of 65ºC. Answer: (A) = 324ºC, (B) = 747ºC Example 7 – Mixture A block of substance “X” has a mass of 100g and is heated to 260ºC. The block is then placed into a beaker containing 500g of water at 20ºC. After some time both substances reach their equilibrium temperature of 30ºC. Calculate the specific heat capacity of substance X. Solution: Energy gained by the water = Energy lost by X Qw = Qx mwcw∆Tw = mxcx∆Tx Answer = cx = 913J/kgºC Example 8 How much energy is needed to heat a 1kg aluminum pan containing 2kg of water from 25ºC to 95ºC? Solution: Total Energy = Energy gained by aluminum + Energy gained by water Answer 651kJ Example 9 A 0.5kg block of copper (specific heat capacity 390J/kgºC) at an initial temperature of 420ºC was placed into 1.3kg of water at 40ºC. What will be the final temperature of the mixture when thermal equilibrium is reached? Answer: Tfinal = 53.1ºC Micro Properties of different phases Solids Strong bonds between atoms Lowest internal energy Atoms in fixed positions vibrating/oscillating Liquids Weaker forces. Some bonds are broken More internal energy Atoms can move about and change places Gases Virtually no forces/bonds High internal energy Atoms completely free to move at high speed Macro Properties of different phases Solids Maintain shape Lowest temp Low compression/expansion Liquids Takes the shape of its container Moderate temp Low compression/expansion Gases Fills the container Highest temp High compression/expansion Plasmas – atoms are at extremely high temperatures and are ionized. Usually found in stars. Substance Specific Heat of Beryllium Specific Heat of Cadmium Specific Heat of Copper Specific Heat of Germanium Specific Heat of Gold Specific Heat of Iron Specific Heat of Lead Specific Heat of Silicon Specific Heat of Silver Specific Heat of Brass Specific Heat of Glass Specific Heat of Ice(-5°C) Specific Heat of Marble Specific Heat of Wood Specific Heat of Alcohol(ethyl) Specific Heat of Mercury Specific Heat of Water(15°C) Specific Heat of Steam(100°C) Specific Heat of Aluminium Specific Heat of Tin Specific Heat of Steel Specific Heat of Sand Specific Heat of Ethanol (Alcohol, ethyl 32°F) Specific Heat(J/kg. °C) 1830 230 387 322 129 448 128 703 234 380 837 2090 860 1700 2400 140 4186 2010 900 540 120 830 2.3 K