CHEMICAL BONDING, CHEMICAL FORMULAS AND NOMENCLATURE SPS1. Students will investigate our current understanding of the atom. ab. Compare and contrast ionic and covalent bonds in terms of electron movement. SPS2. Students will explore the nature of matter, its classifications, and its system for naming types of matter. b. Predict formulas for stable binary ionic compounds based on balance of charges. c. Use IUPAC nomenclature for transition between chemical names and chemical formulas of binary ionic compounds (containing representative elements). binary covalent compounds (i.e. carbon dioxide, carbon tetrachloride). SPS4. Students will investigate the arrangement of the Periodic Table. a. Determine the trends of the following: Number of valence electrons, Types of ions formed by representative elements, Location of metals, nonmetals, and metalloids b. Use the Periodic Table to predict the above properties for representative elements. ESSENTIAL QUESTION: WHAT IS AN IONIC COMPOUND AND HOW DOES IT FORM. Look at the apparatus set up on the demonstration desk. What do you think will happen when the prongs are placed into the beaker containing the substances? Substance What I think will happen What actually happens My hypothesis A B Atoms want to be ___________________ To be stable an atom needs to have _____electrons in its outer energy level or it can have a completely filled outer energy level such as the element _______. The electrons in the outer energy level are called ________electron. Elements in the same representative group have the same number of _____________. GROUP 1 ___ GROUP 2_____ GROUP 13_____GROUP 17____ ETC. Opposite _______________attract each other. The force that holds atoms or ions together as a unit is called a ___________________. An ______________bond is the type of bond that holds cations and anions together. This type of bond forms when electrons are transferred from the outer energy level of one atom to the outer energy level of another atom so that each atom becomes __________. A compound formed between anions and cations is called an_____________compound. PROPERTIES OF IONIC COMPOUNDS: LIST THE 5 PROPERTIES BELOW 1. 2. 3. 4. 5. 1 IONIC COMPOUNDS CAN BE REPRESENTED BY _____________________________________. EXAMPLES OF CHEMICAL FORMULAS BINARY COMPOUNDS: COMPOUNDS MADE UP OF ONLY __ KINDS OF ATOMS. SODIUM AND CHLORINEALUMINUM AND CHLORINE – IMPORTANT INFORMATION A CHEMICAL FORMULA GIVES 1. 2. ESSENTIAL QUESTION: What is a covalent bond and how does it form? Bonding and Naming Chemical Compounds Covalent Bonding Covalent compound METAL AND NON-METALS BOND TO FORM ______________COMPOUNDS NON-METALS AND NON-METALS BOND TO FORM _______________COMPOUNDS Ionic or Covalent? Bonding between atoms of different elements is rarely purely ionic or purely covalent. It usually falls somewhere between these two extremes depending on how strongly the atoms the atoms of each element attract electrons. The degree to which bonding between atoms of two elements is ionic or covalent can be estimated by calculating the difference in the elements’ electronegativities Ex: Non-Polar Covalent Bond – Polar – Polar Covalent Bond – ***** Attractions between polar molecules Ex: What is the bond type between hydrogen and oxygen in a water molecule? 2 Water is a polar molecule aka dipole molecule: one end is slightly positive and one end is slightly negative. Draw a diagram of a water molecule. Practice Problems: Bonding between magnesium and oxygen sulfur Chlorine Bonding between nitrogen and Oxygen fluorine sulfur Combination of ions Bond Type Chemical formula Combinations of ions Bond Type Example of a chemical formula Covalent Bonding and Molecular Compounds Many chemical compounds, including most of the chemicals that are in living things and are produced by living things are composed of ____________. Certain atoms bond with each other to form __________that are more stable than the single atom. Molecule – Molecular Compound – Molecular Formula – Structural FormulaEx: 3 Diatomic Molecule – (Diatomic Elements) DIATOMIC ELEMENT FORMULA MONATOMIC IONS Ex: POLYATOMIC IONS EX: Naming Monatomic Ions Monatomic cations are identified simply by the elements name. Ex: Monatomic anions are named by first dropping the ending of the elements name and adding –ide to the root name. Ex: Binary Ionic Compounds Binary Compounds – Steps for writing Binary Ionic Compounds: 1. Write the symbol for the ions side by side. Write the cation first. 2. Cross over the charges by using the absolute value of each ion’s charge as the subscripts for the other ion. 3. Check the subscripts and divide them by their largest common factor to give the smallest possible whole number-ratio of ions. (2 x +3 = +6 and 3 x-2 = -6 which cancel each other out) 4 Naming Binary Ionic Compounds Nomenclature – For Binary Ionic Compounds, the name of the cation is given first, followed by the name of the anion Ex: Practice Problems Write the formulas for the binary ionic compounds formed between the following elements: 1. zinc and iodine 2. zinc and sulfur 3. potassium and iodine 4. magnesium and chlorine Name the binary ionic compounds indicated by the following formulas: 1. AgCl 2. ZnO 3. CaBr2 4. SrF2 5. BaO 6. CaCl2 The Stock System of Nomenclature Some elements, such as iron, form two or more cations with different charges. To distinguish the ions formed by such elements, the Stock system of nomenclature is used. This system uses a Roman numeral to indicate an ions charge. The numeral is enclosed in parentheses and placed immediately after the metal name. Ex: Names of metals that commonly form only one cation do not include a Roman numeral. Ex: Naming a Binary Ionic Compound with the Stock System Nomenclature Practice Problems Write the formula and give the name for the compound formed between the following ions: 1. Cu+2 and Br2. Fe+2 and O-2 3. Pb+2 and Cl4. Hg+2 and S-2 5. Sn+2 and F6. Fe+3 and O-2 Give the names for the following compounds: use Roman Numerals (stock system) 1. CuO 3. SnI4 5 2. CoF3 4. FeS Compounds Containing Polyatomic Ions Oxyanions – Naming Binary Molecular Compounds 1. The less electronegative element is given first. It is given a prefix only if it contributes more than one atom to a molecule of the compound. 2. The second element is named by combining (a) a prefix indicating the number of atoms contributed by the element, (b) the root of the name of the second element, and (c) the ending – ide. With few exceptions, the ending –ide indicates that a compound contains only two elements. 3. The “o” or “a” at the end of a prefix is usually dropped when the word following the prefix begins with another vowel. Ex: monoxide or pentoxide Ex: P4O10 Numerical Prefixes 14710258369Practice Problems: Name the following binary covalent compounds: 1. SO3 3. PBr5 2. ICl3 Write the formulas for the following compounds: 1. carbon tetraiodide 3. dinitrogen trioxide 2. phosphorous trichloride 6