Outline Chapter 5a Matter and Energy 5-1. Temperature 5-2. Heat 5-3. Metabolic Energy 5-4. Density 5-5. Pressure 5-6. Buoyancy 5-7. Gas Laws 5-1. Temperature Temperature = average kinetic energy. Heat= total energy. The Lake and the glass of water both are at 70oF. Which has the most heat? 5-1. Temperature 5-1. Temperature The fahrenheit scale in which water freezes at 32° F and boils at 212° F at sea level. The celsius scale in which water freezes at 0° C and boils at 100° C at sea level. C=(F+40)5/9-40 F=(C+40)9/5-40 127.4oF 53oC = ?oF 35oC 95oF = ?oC Measuring Temperature Difference in expansion of two metals side by side A thermostat makes use of the different rates of thermal expansion in the metals of a bimetallic strip to switch heating and cooling systems on and off. Expansion of a liquid Measuring Temperature Expansion of a liquid Bakersfield College Physical Science PHSC-B11 James Prescott Joule (1818-1889) 5-2. Heat British Brewer Conducted an experiment to conclusively James Prescott The SI unit of heatsettle is the joule as wellover as the calorie. Joule the debate heat as a form of (1818-1889) energy Heat can be transferred in three ways: 1. Conduction, whichthe heat is transferred from one place to Joule developed Joulein developed the law of lawmolecular of conservation conservation another by collisions. of of energy energy when when he he 2. Convection, in As which heat is carried by the motion of a was aa result was 29. 29. As result of his his work, work, the the SI SI volume ofof hot fluid. units units for for work work (J) (J) were named for him named for him is transferred by electromagnetic 3. Radiation,were in which heat waves. 5-2. Heat The heat needed to change the temperature of 1 kg of a substance by 1° C is different for different substances. 5-2. Heat Specific Heat is a measure of how much heat a substance can hold. Water holds more heat per gram than any other substance. Substance Water Human Body Concrete Alcohol (ethyl) Ice Steam Wood Aluminum Glass Iron Copper Gold Specific Heat kJ/kg Co 4.2 3.5 2.9 2.4 2.1 2.0 1.8 0.92 0.84 0.46 0.39 0.13 5-3. Metabolic Energy The complex of biochemical reactions that make food energy available for use by living organisms is called metabolism. A kilocalorie (4.2kj) is the amount of heat needed to change the temperature of 1 kg of water by 1° C; it is equal to one dietary "calorie." Food kcal 1 raw onion 5 1 dill pickle 15 1 gum drop 35 1 poached egg 75 1 banana 120 1 cupcake 130 1 broiled hamburger patty 150 1 glass of milk 165 1 cup bean soup 190 1 cup tuna salad 220 1 ice cream soda 325 ½ broiled chicken 350 1 lamb chop 420 5-3. Metabolic Energy The conversion of metabolic energy into biological work is relatively inefficient; much of the energy is lost as heat. The maximum metabolic rate or power output depends on the animal’s ability to dissipate heat. 5.2 W/kg 1.2 W/kg 0.67 W/kg 5-4. Density M D = ------V Find the mass of water in the bathtub above. M 1000kg D == ------M D V = ----------- (0.234 m3) = 234kg V 1 m3 or 1 g/cm3 5-5. Pressure The SI unit of force is the pascal: 1 pascal = 1 Pa = 1 newton/meter2 Atmospheric pressure at sea level averages 101 kPa (equals approximately 15 lb/in2). Instruments called barometers measure atmospheric pressures. F P = ------A 5-5. Pressure Pressure exerted by 60kg woman’s heel onto the floor is about 40 times the estimated pressure of the feet of a 35-ton apatosaurus on the ground. P = F/A = 588N/5x10-5m2 = 1.2x107N/m2 = 12 MPa 5-5. Pressure Measuring Blood Pressure Pump until blood flow stops. Release until hear gurgling of blood flow (systolic). Release until gurgling stops (diastolic). Normal is 120/80 torr. Fig. 5.16 Hydraulic ram converts pressure in a liquid into an applied force. The pressure is provided by an enginedriven pump. Bernoulli’s Principle The pressure in a moving liquid or gas is less than the pressure in a stationary liquid or gas. This explains how airplanes fly. 5-6. Buoyancy Fb= dxVxg P=ρxgxdepth Archimedes' principle states: Buoyant force on an object in a fluid is equal to the weight of fluid displaced by the object. 5-6. Buoyancy Fb= dxVxg P=ρxgxdepth Weighing by Volume You can estimate mass by measuring the volume of water an object displaces. Compare the mls the object displaces in a graduated cylinder below to the measured mass on a balance. Item Mass Volume Wood Animal 19.343g 297-277=20 ml Golf Ball 45.450g 296-250=46 ml Syringe 2.601g 211-209=2 ml Ping Pong Ball 3.444g 217-215=2 ml (only a portion is submerged) Orange Spigot 15.859g 219-204=15 ml 5-6. Buoyancy Fb= dxVxg P=ρxgxdepth Diet sodas contain no sugar and mostly water. Therefore they displace the same amount of water as in the can and they will barely float. Non-diet sodas contain sugar which gives them a density greater than water and they will sink. Fig. 5.18 Air at high pressure in a the tank of a scuba diver is reduced by a regulator valve to the pressure at the depth of the water. The diver must wear lead weight to overcome his or her buoyancy. The deeper the diver goes, the greater the water pressure, and the faster the air in the tank is used up. Fig. 5.20 Because water expands when it freezes it becomes less dense and floats. 90% of this ice berg off of Greenland is under water. 5-7. Gas Laws Boyle’s Law P1 P2 = Charles’s Law V2 V1 V1 T1 = Ideal Gas Law V2 P1V1 T2 T1 = P2V2 T2 Fig. 5.38 Pressure Cooker. By increasing temperature you can increase the pressure. Fig. 5.33 The snow making machine shoots expanded mixture of ice and air to freeze to snow. Absolute Zero Absolute zero is -273° C and is the theoretical but unreachable lowest possible temperature. Outline Chapter 5b Matter and Energy 5-8. Kinetic Theory of Gases 5-9. Molecular Motion and Temperature 5-10. Liquids and Solids 5-11. Evaporation and Boiling 5-12. Melting 5-13. Heat Engines 5-14. Thermodynamics 5-15. Fate of the Universe 5-16. Entropy 5-8. Kinetic Theory of Gases A. Gas molecules are small compared with the average distance between them; a gas is mostly empty space. 1. Gases are easily compressed. 2. Gases are easily mixed. 3. The mass of a certain volume of gas is much smaller than that of the same volume of a liquid or a solid. B. Gas molecules collide without loss of kinetic energy. C. Gas molecules exert almost no forces on one another, except when they collide. 5-10. Liquids and Solids The intermolecular attractions between the molecules of a liquid are stronger than those in a gas but weaker than those in a solid. Molecules of a solid do not move freely about but vibrate around fixed positions. 5-9. Molecular Motion and Temperature •The absolute temperature of a gas is proportional to the average kinetic energy of its molecules. •Gas molecules, even at 0 K (-273° C), would still possess a small amount of kinetic energy. •Compression of a gas increases its temperature; expansion decreases its temperature. •Gas molecules are in constant motion because their collisions result in no net loss of energy. Increases decreases 5-11. Evaporation and Boiling Boiling is when vapor pressure equals atmospheric pressure. Sublimation is the direct conversion of a substance from the solid to the vapor state, or from the vapor state to the solid state, without it entering the liquid state. 5-11. Evaporation and Boiling FB These canthe only formofwhen the the gas • As heated, bubbles gas begin to Asliquid thebubbles gasis inside bubbles expands, inside has enough to overcome form buoyant force pressure on the bubble grows, the pressure in the liquid atmosphere eventually causing it to and rise to the surface above the liquid Changes of State heat of vaporization heat of fusion Changes of State 5-13. Heat Engines 5-13. Heat Engines http://auto.howstuffworks.com/engine1.htm How a Refrigerator Works 5-14. Thermodynamics •Thermodynamics is the science of heat transformation. •The first law of thermodynamics states: Energy cannot be created or destroyed, but it can be converted from one form to another. •The second law of thermodynamics states: It is impossible to take heat from a source and change all of it to mechanical energy or work; some heat must be wasted. OR The universe is always going toward a state of disorder (entropy is always increasing in the universe). 5-15. Fate of the Universe 5-16. Entropy Entropy is disorder. The universe is increasing its disorder (another version of the 2nd law of thermodynamics). The heat death of the universe will occur when all particles of matter ultimately have the same average kinetic energy and exist in a state of maximum disorder. Heat Engine Efficiency Maximum efficiency of a heat engine depends on the temperatures at which it takes in and ejects heat; the greater the ratio between the two temperatures, the more efficient the engine: Tcold 368oK Efficiency = 1 - ----- = 1 - -------- = 0.56 Thot 843oK Steam Engine and Electric Power Plants Dark Energy In a 1998 study led by Adam Riess, and a group of scientists from the Mount Stromlo Observatory, which is part of the Australian National University, Harvard University and Johns Hopkins University and Space Telescope Science Institute found, by observing supernovas in distant galaxies that the universe is expanding faster and faster. This violates Newton’s second law of motion that says acceleration is due a force. What force????? 42 Dark Energy Basically, dark energy is what they attribute to the accelerated expansion of the universe which means it isn’t dark as to light, but dark as to they know nothing about it. Attempts to explain or measure this energy have largely failed. 43 Dark Matter Dark matter was discovered by observing that the arms of spiral move at the same speed in violation of Kepler’s Law of planetary motion. It was explained by some unknown (dark) matter that distorted known gravitational effects. It was later found that the gravity of super massive black holes at the center of galaxies was not enough to hold the galaxies together. Gravity was not enough to hold the small local clusters of galaxies together as well as the super clusters of galaxies. Long filamental lines of matter, evident of some sort of attractive forces, has also been found between the super clusters of galaxies. Dark Matter has been used to explain all of these 44 New Model of the Cosmos The new model of the Cosmos puts about 4.6% of the universe being made up of atoms and molecules like what we think we know something about, about 23% is made up by dark matter and the rest (72%) is composed of dark energy. They say the Universe was different 13.7 billion years ago????? 45