Entropy and Gibb's Free Energy Worksheet

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Entropy and Gibb’s Free Energy Worksheet

1.

What is the symbol for entropy?________________________________________________

2.

What values for entropy will show randomness or disorder?__________________________

3.

What values for entropy will show order? _________________________________________

4.

Predict whether the following will have a positive entropy or a negative entropy a.

CaCO

3

(s)  CaO(s) + CO

2

(l) b.

2H

2

(g) + O

2

(g)  2H

2

O c.

Fe(s)  Fe(l) d.

4Al(s) + 3O

2

(g)  2Al

2

O

3

(s)

5.

Which usually has the greatest entropy? Solid, liquid, gas

6.

The combined enthalpy-entropy function is called _________________ and is represented by

_________.

7.

Give the formula for the enthalpy-entropy change.

8.

A spontaneous reaction always has a ______ΔG.

9.

A positive ΔS value will represent ordering or disordering?

10.

Given the following reaction at 25 o C and ∆S= 0.003 kJ/K*mo, find the ∆G and determine if the reaction is spontaneous or nonspontaneous.

C(s, graphite) + O

2

(g)  CO

2

+ 393.5 kJ/mol

11.

Calculate the Gibb’s Free Energy change for the following reaction at 25 o C.

Ca(s) + 2H

2

O(l)  Ca(OH)

2

(s) + H

2

(g)

Given: ΔH o = -411.6 KJ/mole ΔS o = .0318 KJ/(moleK)

12.

Calculate the Gibbs free energy for the following reaction at 25 o C . ∆S= 3235.7 J/K*mol

5CO

2

(g) + Si

3

N

4

(s)  3SiO (g) + 2N

2

O + 5CO (g)

Use the following equations and data

CO (g) + SiO

2

(s)  SiO(g) + CO

2

(g) ΔH= +520.9 KJ

8 CO

2

(g) + Si

3

N

4

(s)  3SiO

2

(s) + 2N

2

O(g) + 8CO(g) ΔH= +461.05 KJ

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