Chapter 11 Notes Honors Chemistry Chapter 11: Chemical Reactions Section 1 Notes – Describing Chemical Reactions (Read pages 321-329) Chemical Reactions are ALWAYS occurring! _______________ _______________ in your _______________ help _______________ food. _______________ use _______________ to grow by means of a _______________ process called _______________. _______________ causes _______________ to _______________. What is a chemical reaction? One or more _______________, called _______________ or _______________ change into one or more _______________ substances, called _______________. Reaction Equations Used to _______________ what happens in a _______________ _____________ Written as _____________________________________________________ (Read as _______________ _______________ ________________) Use _______________ signs for _______________ reactants or products Two forms: o _______________ Equations Name of _______________ is expressed o _______________ Equations _______________ _______________ are expressed Consider the following: Iron reacts with air (oxygen) to form rust (Iron (III) oxide). Word Equation: Chemical Equation: Try it! When you light a burner on your stove, methane gas (CH4) bursts into flames when it reacts with oyxgen in the air to produce water and carbon dioxide. Write both a word equation and a chemical equation for this reaction. 1 Chapter 11 Notes Honors Chemistry More about Chemical Equations The _____________ equations that you have written so far are what’s called _____________ _____________ o _____________ Equation - _____________ equation that does _________ show the _____________ amounts of _____________ and _____________ _____________ equations are the _____________ for _____________ _____________ _____________ _____________ (We’ll get there shortly) Symbols in Chemical Equations _____________ States o (s) indicates a _____________ o (l) indicates a _____________ o (g) indicates a _____________ o (aq) indicates an _____________ _____________ Example: O2 (g) Different Arrows in Chemical Reactions is the _____________ arrow, which means _____________ indicates that the reaction is _____________ indicates the use of a _____________, the _____________ for the _____________ will appear _____________ the arrow o Catalyst – a _____________ that _____________ _____________ the reaction, but is _____________ used up in the reaction. It is not a _____________ or _____________ or indicates that _____________ is used in the reaction Practice Problems 1. Write a sentence that describes this chemical reaction. Na(s) + H2O(l) NaOH(aq) + H2(g) 2. Sulfur burns in oxygen to form sulfur dioxide. Write a skeleton equation for this chemical reaction. 2 Chapter 11 Notes Honors Chemistry Balancing Equations Imagine you are asked to write an equation to build a bicycle. Reactants: __________________________________________________________ Product: Bicycle Is it enough to use the following equation: First, express the final product in terms of the reactants: Our new bicycle equation is: Balancing equations means making the number of ____________ = ____________ So is our equation balanced? Use _______________ to balance the equation. o Coefficient: _______________ _______________ number placed in front of a _______________ in an _______________ in order to _____________ Why do we balance equations? Law of _______________ of _______________ o States that _____________ cannot be ______________ or ______________ o What the reaction _______________ with, it must _______________ with Let’s Try Balancing an Equation Balance the following equation: Al + Fe2O3 Al2O3 + Fe Let’s Try Another One Balance the following equation: Zn(OH)2 + H3PO4 Zn3(PO4)2 + H2O 3 Chapter 11 Notes Honors Chemistry Practice Problems Balance the following equations: 1. ___ H2 + ___ O2 ___ H2O 2. ___ N2 + ___ H2 ___ NH3 3. ___ AgNO3 + ___ H2S → ___ Ag2S + ___HNO3 4. Hydrogen + Sulfur Hydrogen Sulfide 5. Iron (III) Chloride + Calcium Hydroxide Iron (III) Hydroxide + Calcium Chloride 6. Calcium Hydroxide + Sulfuric Acid Calcium Sulfate + Water 7. ___ CS2 + ___ Cl2 ___ CCl4 + ___ S2Cl2 Book Work – Page 329 #7-12 Section 2 Notes – Types of Chemical Reactions (Read pages 330-341) Classifying Reactions Five Types 1. ______________________________ 2. ______________________________ 3. ______________________________ 4. ______________________________ 5. ______________________________ 4 Chapter 11 Notes Honors Chemistry Synthesis or Combination Reactions A _______________ change in which _______________ or more ______________ react to form a _______________ _______________ substance Formula: ______________________________ Can occur to form _______________ and _______________ compounds What’s important to remember: _______________ _______________ Example: Synthesis Examples Can be two _______________ combining to form a _______________: o Sodium and chlorine react to form sodium chloride o _____________________________________________________________ Can be two _______________ combining to form a _______________. o Sodium oxide combines with water to form sodium hydroxide. o _____________________________________________________________ Synthesis Practice 1. Complete and balance this equation for a synthesis reaction: ___ Be + ___ O2 ___ BeO 2. Write and balance the equation for the formation of magnesium nitride (Mg3N2) from its elements. Decomposition Reactions A _______________ change in which a single _______________ _______________ down into two or more _______________ _______________. Formula: ___________________________________________________________ _______________ of _______________ Most require _______________ in the form of _______________, _______________, or _______________ What’s important to remember: _______________ _______________ Example: Decomposition Practice 1. Balance the following decomposition reaction: ___ KClO3 ___ KCl + ___ O2 2. Complete and balance this decomposition reaction: ___ HI ___ H2 + ___ I2 5 Chapter 11 Notes Honors Chemistry 3. Write the formula for the binary compound that decomposes to the products H2 and Br2. Single Replacement Reactions A _______________ _______________ in which one _______________ _______________ a second _______________ in a _______________. Essentially, the _______________ just _______________ places. o _______________ replace _______________ o _______________ replace _______________ Formula: ___________________________________________________________ What’s important to remember: one _______________ and one _______________ on each side of the _______________ Example: Activity Series Not all _______________ _______________ reactions will take place as written. _______________ _______________ - a list of _______________ in order of _______________ _______________ Some examples: o Fe + CuO _______________ occur – __________________________________ o Mg + LiCl _______________ occur - __________________________________ o Ca + AgBr _______________ occur - __________________________________ Single Replacement Practice Complete the equations for these single-replacement reactions in aqueous solution. Balance each equation. Write “no reaction” if a reaction does not occur. Use the activity series. a. ___ Fe(3+) + ___ Pb(NO3)2 b. ___ Ca + ___ Li2O c. ___ Zn + ___ H2SO4 Double Replacement Reactions A chemical _______________ involving an _______________ of _______________ _______________ between two _______________. Essentially, two _______________ just _______________ places in two _______________. 6 Chapter 11 Notes Honors Chemistry Generally take place in _______________ solution and often produce a _______________, _______________, or _______________ _______________ Formula: ___________________________________________________________ What’s important to remember: Two _______________ on each side Example: Double Replacement Practice Complete and balance the equations for these double replacement reactions. 1. ___ NaOH + ___ Fe(NO3)3 2. ___ Ba(NO3)2 + ___ H3PO4 3. ___ H2SO4 + ___ Al(OH)3 Combustion Reactions A chemical _______________ in which an _______________ or a _______________ reacts with _______________, often producing _______________ in the form of _______________ or _______________. _______________ involves _______________ as a _______________. The other _______________ is usually a _______________ (compound containing _______________ and _______________). _______________ combustion of a hydrocarbon (_______________ oxygen) yields _______________ _______________ and _______________. _______________ combustion (_______________ oxygen) yields _______________ _______________ Formula: ___________________________________________________________ What’s important to remember: _______________ is a _______________ Example: Combustion Practice Write a balanced equation for the complete combustion of each compound: a. Formic acid (HCOOH) b. Heptane (C7H16) c. Glucose (C6H12O6) Page 338-339 in your textbook is a good summary chart of the reaction types 7 Chapter 11 Notes Honors Chemistry Practice Problems Classify each of the following reactions as one of the chemical reaction types. Complete and balance the equation for each as well. 1. ___ CH4 + ___ O2 2. ___ K + ___ S ___ K2S 3. ___ H2O ___ H2 + ___ O2 4. ___ Zn + ___ PbI2 5. ___ CaBr2 + ___ AgNO3 6. ___ Cu + ___ NaCl Book Work: Page 339 #22, 24, and 26 Section 3 Notes – Reactions in Aqueous Solutions (Read pages 342-344) Reaction in Aqueous Solutions… Just means _____________ that take place in _____________ Solubility of Ionic Compounds Some _____________ compounds are _____________ in _____________, which means they will _____________, whereas others are _____________ in _____________, which means they will _____________ _____________. Solubility Rules Using the chart on your reference sheet, you can _____________ whether or not an _____________ solid will _____________ in an _____________ _____________ Try It! o Decide whether the following ionic compounds are _____________ or _____________: LiOH _____________ MgCl2 _____________ NaNO3 _____________ BaSO4 _____________ 8 Chapter 11 Notes Honors Chemistry Dissociation Remember that most _____________ compounds _____________, or _____________, in _____________ _____________ Technically when you _____________ salt (_____________ _____________ - NaCl) in water, it doesn’t exist as ________, it exists as _____ ions and _____ ions Use this concept to write _____________ _____________ equations o An _____________ that shows _____________ ionic compounds as _____________ _____________ _____________. Remember to check _____________ - _____________ compounds do not _____________ Complete Ionic Equation Example Predict the products for the following single replacement reaction: AgNO3 + NaCl Now check the solubility and show the appropriate dissociations: This is the complete ionic equation for the reaction. 9 Chapter 11 Notes Honors Chemistry Net Ionic Equations Ag+ + NO3- + Na+ + Cl- AgCl + Na+ + NO3 _____________ ionic equations can be _____________ one step further – to a _____________ ionic equation o An _____________ for a reaction in _____________ that shows _________ those _____________ that are _____________ _____________ in the chemical _____________ Do you see any similarities on the reactant and product side of the reaction? o These _____________ are called _____________ _____________ _____________ that appear on _____________ sides of an _____________ and are _____________ directly involved in the _____________. In this reaction, the _____________ ___________ are _________ and _________. _____________ ions in a reaction are _____________ because they don’t take part in the _____________ This makes our _____________ ionic equation: ____________________________ Notice that the _____________ ionic equation is still _____________ in terms of _____________ and _____________ Practice Problems 1. Write the balanced net ionic equation for this reaction: Ca2+ + OH- + H+ + PO43- Ca2+ + PO43- + H2O 2. Write the complete ionic equation and net ionic equation for the reaction of aqueous calcium hydroxide with phosphoric acid. The products are calcium phosphate and water. Book Work - Page 344 #30-35 10