Ch. 3 Scientific Measurement Measurement Quantitative information Need a number and a unit (most of time) Represents a quantity For example: 2 meters 2 is number Meters is unit Length is quantity Units compare what is being measured to a defined measurement standard SI Measurement Le Systeme International d’Unites : SI System of measurement agreed on all over the world in 1960 Contains 7 base units We still use some non-SI units Important SI Base Units Quantity Length Symbol l Unit Abbreviation meter m Mass m kilogram kg Time t second s Temperature T Kelvin K Amount n mole mol Prefixes Prefixes are added to the base unit names to represent quantities smaller or larger M mega 106 1,000,000 larger k kilo 103 1,000 larger c centi 10-2 1/100 smaller m milli 10-3 1/1000 smaller μ micro 10-6 1/1,000,000 smaller Length SI unit: m use cm a lot too km is used instead of miles for highway distances and car speeds in most countries Mass Measure of the quantity of matter SI unit: kg use g a lot too mass vs. weight weight is the measure of gravitational pull on matter mass does not depend on gravity on a new planet, mass would be same but weight could change Temperature Conversions Fahrenheit to Celsius 9 F C 32 5 5 C F 32 9 Celsius to Kelvin conversions +273.15 → C K ← -273.15 Temperature Conversions Example What is 32°F in Kelvin? freezing point of water! 5 C (32 32) 0 9 K 0 273.15 273.15 Example What is 298 K in Fahrenheit? C 298 273 25 C o 9 F (25) 32 77 F 5 Derived SI Units come from combining base units combine using multiplication or division Example: Area: A = length x width =mxm = m2 Volume amount of space occupied by object SI: m3 = m x m x m use cm3 in lab a lot non-SI: 1 liter = 1dm3= 1000cm3 1 liter = 1000 mL 1cm 3= 1mL Density ratio of mass to volume kg SI: m 3 mass Density volume Other units: g/ cm3 or g/ mL characteristic property of substance (doesn’t change with amount ) because as volume increases, mass also increases density usually decreases as T increases exception: ice is less dense than liquid water so it floats Example A sample of aluminum metal has a mass of 8.4 g. The volume is 3.1 cm3. Find the density. Known Unknown m = 8.4 g D=? V = 3.1 cm3 m 8.4 g g D 2.7 3 3 V 3.1cm cm Dimensional Analysis Conversion Factors ratio that comes from a statement of equality between 2 different units every conversion factor is equal to 1 Example: statement of equality conversion factor 4quarters 1dollar 1dollar 1 4quarters Conversion Factors can be multiplied by other numbers without changing the value of the number since you are just multiplying by 1 4quarters 3dollars 12quarters 1dollar Example 1 Convert 5.2 cm to mm 5.2 cm= 5.2 x 10 1mm = 52 mm Known: 100 cm = 1 m 1000 mm = 1 m Must use m as an intermediate 1m 1000mm 5.2cm 52mm 100cm 1m Example 2 Convert 0.020 kg to mg 0.020 kg = 0.020 x 10 6 mg= 20,000 mg Known: 1 kg = 1000 g 1000 mg = 1 g Must use g as an intermediate 1000 g 1000mg 0.020kg 20,000mg 1kg 1g Example 3 Convert 500,000 μg to kg 500,000 μg = 500,000 x 10 -9 kg= 0.0005 kg Known: 1,000,000 μg = 1 g 1 kg = 1000 g Must use g as an intermediate 1g 1kg 500,000g 0.0005kg 1,000,000g 1000 g Advanced Conversions One difficult type of conversion deals with squared or cubed units Example Convert 3 dm 3 to cm3 1dm =10 cm 3 dm 3 = 3 x 10 cm x 10 cm x 10 cm= 3000 cm3 Example Convert: 2000 cm3 to m3 Known: 100 cm = 1 m cm3 = cm x cm x cm m3 = m x m x m 1m 1m 1m 3 2000cm cm cm 0.002m 100cm 100cm 100cm 3 OR 1m 3 2000cm 0 . 002 m 100cm 3 Advanced Conversions Another difficult type of conversion deals units that are fractions themselves Be sure convert one unit at a time; don’t try to do both at once Work on the unit on top first; then work on the unit on the bottom Example Convert 350 g/ mL to kg/L Top first 350 g to kg 350 g= 350 x 10 -3 kg= .35 kg Bottom part after 1mL to L 1mL= 1x 10 -3 L= 0.001 L Result: 350 g/ mL = .35 kg/ 0.001L= 350kg/ L Combination Example Convert 7634 mg/m3 to Mg/L Top 7634 mg= 7634 x 10 -9 Mg= 0.000007634 Mg Bottom 1m= 10 dm 1 m3= 10 dm x 10 dm x10 dm= 1000 dm 3 = 1000 L Result: 7634 mg/m3 = 0.000007634 Mg/ 1000 L= 0.000000007634 Mg/L = 7.634 x 10 -9 Mg/L Accuracy vs. Precision Accuracy- closeness of measurement to correct or accepted value Precision- closeness of a set of measurements Accuracy vs. Precision Percent Error vs. Percent Difference Percent Error: Measures the accuracy of an experiment Can have + or – value accepted experimeta l 100% accepted Percent Error vs. Percent Difference Percent Difference: Used when one isn’t “right” Compare two values Measures precision value 1 value 2 average of value 1 and 2 100% Example Measured density from lab experiment is 1.40 g/mL. The correct density is 1.36 g/mL. Find the percent error. 1.36 - 1.40 % error 100 2.94% 1.36 Example Two students measured the density of a substance. Sally got 1.40 g/mL and Bob got 1.36 g/mL. Find the percent difference. 1.40 - 1.36 % difference 100 2.90% 1.40 1.36 2