7.5 & 7.6 Chemical Analysis Chemical Analysis ________analysis: identifies whether a certain substance is present. ________analysis: measures the amount of a certain substance present. Qualitative Chemical Analysis ________Analysis The colour of solutions can indicate the type of ion it contains. Group 1, 2, 17 are ________ Some metal ions produce a ________flame when burned. “Light” collected by a _________________. Qualitative Chemical Analysis Analysis based on ________ Use known solubility values to create a ________that will indicate whether a particular substance is present. When an unknown solution is burned, it gives off a ___ flame, indicating the presence of aqueous _______, calcium and/or strontium. How could you determine which of these ion the solution contains? Qualitative Chemical Analysis When an unknown solution is burned, it gives off a red flame, indicating the presence of aqueous lithium, calcium and/or strontium. How could you determine which of these ion the solution contains? Step 1: Test for Sr2+ – Use Rule 8 Sr2+? No Unknown Solution Unknown Solution (w/o) Sr2+ CrO42- Yes Qualitative Chemical Analysis When an unknown solution is burned, it gives off a red flame, indicating the presence of aqueous lithium, calcium and/or strontium. How could you determine which of these ion the solution contains? Step 2: Test for Ca2+ – Use Rule 5 Ca2+? No Unknown Solution Unknown Solution (w/o) Sr2+ or Ca2+ SO42- Yes Qualitative Chemical Analysis When an unknown solution is burned, it gives off a red flame, indicating the presence of aqueous lithium, calcium and/or strontium. How could you determine which of these ion the solution contains? Step3: Test for Li+ – Use Flame Test Li+? No Unknown Solution Flame Yes Quantitative Chemical Analysis ________Stoichiometry: a method of calculating the ___________of substances in solution by measuring their ________and the results of ________reactions Quantitative Chemical Analysis What mass of precipitate will be produced from the reaction of 0.755L of 15%W/V sodium chloride solution and 1.35L of 0.245mol/L silver nitrate solution? NaCl(aq) + AgNO3(aq) mAgCl = ? cNaCl = 15% W/V = 15g/100mL vNaCl = 0.755L CAgNO3 = 0.245mol/L vAgNO3 =_________ NaNO3(aq) + AgCl(s) Steps: 1. Write a ________equation (provided) 2. ________given values to amount in moles 3. Determine _________________________ 4. ________given amount (of LR) in moles to required amount in moles using _______ ______ from equation 5. Convert amount in ______to required value (mass in this case) Quantitative Chemical Analysis NaCl(aq) + AgNO3(aq) Quantitative Chemical Analysis NaCl(aq) + AgNO3(aq) Therefore, Quantitative Chemical Analysis NaCl(aq) + AgNO3(aq) We use the number of moles of AgNO3 to calculate the mass of precipitate formed. Therefore, Qualitative Chemical Analysis How could you determine if a solution contained aqueous lead(III) and/or strontium ions? Pb2+/Sr2+(aq)? Rule 4 Rule 5 Pb2+? Sr2+? No Yes NaCl(aq) Na2SO4(aq) Yes No Homework For Monday Take-up Pg 309# 6-8 Lab Manual – Concentration Practice For Tuesday Take-up Read 7.5 Make note of the Table 1 (pg 341) & Table 3 (pg 342) Read 7.6, Do p.353 # 3 p.355 # 1