AOSC 620 Cloud Nucleation Russell Dickerson 2014 Rogers and Yau, Chapt. 6 Copyright © 2010 R. R. Dickerson & Z.Q. Li 1 Copyright © 2010 R. R. Dickerson & Z.Q. Li 2 Questions on the Effects of Aerosols on Clouds and Precipitation ● Why do many people think aerosols inhibit deep convective cloud formation? Copyright © 2010 R. R. Dickerson & Z.Q. Li 3 Opposing Effects of Aerosols on Clouds and Precipitation ● How do radiative and micro-physical effects of aerosols compete? How does suppression of precp change buoyancy? How does freezing change buoyancy? Copyright © 2010 R. R. Dickerson & Z.Q. Li 4 Opposing Effects of Aerosols on Clouds and Precipitation ● How do radiative and micro-physical effects of aerosols compete? How does suppression of precp change buoyancy? negative impact. How does freezing change buoyancy? a) if normal precp then freezing enhances buoyancy. b) If suppressed precp (too many ccn) then freezing generates even more buoyancy. Copyright © 2010 R. R. Dickerson & Z.Q. Li 5 Liquid Water Cloud VDR Yorks et al., 2011 Opposing Effects of aerosols on Clouds and Precipitation (Rosenfeld et al., Science 2008) Radiative Effects: ● Aerosols aloft shield the Earth’s surface from radiation and stabilize the atmosphere wrt convection and the moisture is advected away. (Park et al., JGR, 2001; Ramanathan et al., Science, 2001) ● Increased numbers of CCN slow the conversion of droplets into raindrops and inhibit precipitation, but ingestion of large particles such as sea salt appears to enhance precip. (Radke et al., Science, 1989; Rosenfeld et al., Science, 2002) ● Total water vapor is conserved so suppression of precip here means more rain there. Copyright © 2010 R. R. Dickerson & Z.Q. Li 7 The Rain according to Rosenfeld (microphysical effects) ● The extra CCN in hazy air make for more, smaller droplets in the early stages of a convective cloud. ● The smaller droplets travel higher and more reach colder levels where they are more likely to release latent heat of freezing and increase buoyancy – haze means more instability for the same amount of rain. ● Even though aerosols slow the conversion of cloud droplets into rain drops, convection is eventually invigorated. ● With cold-based clouds (< 0 oC) most of the water is frozen already and there is no enhancement of precip. Copyright © 2010 R. R. Dickerson & Z.Q. Li 8 Fig. 2. Evolution of deep convective clouds developing in the pristine (top) and polluted (bottom) atmosphere Published by AAAS D. Rosenfeld et al., Science 321, 1309 -1313 (2008) Wet (Pseudo-Adiabatic) Parcel Theory (no mixing). ● If all the water in excess of the saturation vapor pressure immediately condenses and precipitates out, then buoyancy is zero all the way up; this is the reference for CAPE calculations. ● If all the water is held in the cloud, then buoyancy becomes more negative with altitude. ● If all the water in excess of the saturation vapor pressure immediately condenses and freezes at T < – 4oC then buoyancy is enhanced. ● If precip is suppressed until the parcel reaches T = – 4oC then buoyancy is enhanced further. The following figure shows an example with the LCL at 960 hPa and 22oC. Fig. 3. The buoyancy of an unmixed adiabatically raising air parcel Energy released in J kg-1. no precp. All precp frozen suppressed precp. ←Cloud base Published by AAAS Who wins – radiation or microphysics? Particles in the accumulation mode with a diameter around 500 nm are most effective at increasing AOT, but CCN can be almost any size – it is the number that matters. Does CCN correlate with AOT? Copyright © 2010 R. R. Dickerson & Z.Q. Li 12 Fig. 1. Relations between observed aerosol optical thickness at 500 nm and CCN concentrations at supersaturation of 0.4% from studies where these variables have been measured simultaneously, or where data from nearby sites at comparable times were available Published by AAAS D. Rosenfeld et al., Science 321, 1309 -1313 (2008) Who wins – radiation or microphysics? ● From this empirical relationship we can estimate the number of CCN as a function of AOT. ● If the count of CCN is 104 cm-3 then AOT ~ 1.0 and radiation reaching the Earth’s surface is reduced by an e-folding. ● CAPE reaches a maximum at CCN ~ 1200 cm-3 (AOT ~ 0.25) ; adding more aerosols will inhibit convection. Bell (GSFC) et al., (JGR, 2008; “Why do tornados and hailstorms rest on weekends?” 2011) showed a weekday/weekend effect. Fig. 4. Illustration of the relations between the aerosol microphysical and radiative effects D. Rosenfeld et al., Science 321, 1309 -1313 (2008) Published by AAAS Who wins – radiation or microphysics? ● From this empirical relationship we can estimate the number of CCN as a function of AOT. ● If the count of CCN is 104 cm-3 then AOT ~ 1.0 and radiation reaching the Earth’s surface is reduced by an e-folding. ● CAPE reaches a maximum at CCN ~ 1200 cm-3 (AOT ~ 0.25) ; adding more aerosols will inhibit convection. Bell (GSFC) et al., (JGR, 2008) showed a weekday/weekend effect. From Rosenfeld and Bell, 2011 Let’s get quantitative; Rogers & Yau, Chapt 6. Copyright © 2010 R. R. Dickerson & Z.Q. Li 19 Phase Change & Nucleation Process (inhibited by surface tension) Condensation Vapor Liquid Evaporation Deposition Vapor Solid Sublimation Freezing Liquid Solid Melting Copyright © 2010 R. R. Dickerson & Z.Q. Li 20 Condensation • In theory, a cloud droplet may not be formed until pure water vapor is over saturated by a few hundreds per cent. • In nature, super-saturation rate rarely exceeds a few tenths per cent. • The reason lies in the presence of plentiful of water cloud nuclei. Copyright © 2010 R. R. Dickerson & Z.Q. Li 21 Deposition • In theory, a cloud droplet may be frozen at a temperature at 0oC. • In nature, super-cooled water droplets of temperature well below the freezing point are often observed. • The reason lies in the lack of ice water cloud nuclei. Copyright © 2010 R. R. Dickerson & Z.Q. Li 22 The coverage of this lecture • • • Derivation of equilibrium water vapor pressure for a small droplet of pure water vs pure bulk water; -Homogenous nucleation Derivation of equilibrium water vapor pressure for a small droplet of solution water vs pure water. -Heterogeneous nucleation Aerosol and CCN Copyright © 2010 R. R. Dickerson & Z.Q. Li 23 Questions to be addressed: 1. How is an embryonic cloud droplet formed and maintained? 2. Why do cloud droplets have a rather narrow range in size? 3. How can a cloud exist for certain period of time? Copyright © 2010 R. R. Dickerson & Z.Q. Li 24 Homogeneous Nucleation For a droplet to form by condensation from the vapor, the surface tension, s, must be overcome by a strong gradient of vapor pressure. The Clausius-Claperon equation describes the equilibrium condition for bulk water and its vapor, which does not apply to small droplet. * Surface tension = work required to increase surface area by one unit. * Store potential energy. * Volume of liquid tends to assume minimum area-to-volume. * Small masses Spherical droplets. Copyright © 2010 R. R. Dickerson & Z.Q. Li 25 Take a small particle of radius, r, and divide in half: Surface tension (s )acting across the plane holds the edges of the sphere together. Surface tension force per unit length (N/m) is a fundamental property of all liquids and is relatively high for water. Force tending to hold the edges together = 2ps r Copyright © 2010 R. R. Dickerson & Z.Q. Li 26 For holding together F1 = 2p s r For forcing apart F 2 = p r 2 pi In equilibrium, F1 = F2 2s Now pi = r Copyright © 2010 R. R. Dickerson & Z.Q. Li 27 Surface tension causes internal pressure 2s pi = r s = surface tension ( W/A = J m -2 = Nm -1 ) r = radius of droplet (cm) for H 2 O, s = 0.075 Nm -1 if r = 1m m in radius (10 -4 cm) p i = 1.5´10+6 dynes/cm 2 = 1.5 Atmospheres The surface tensions for a solute is lower than that of pure water by up to one-third, which was attributed to dissolved organics or ions. Copyright © 2014 R. R. Dickerson & Z.Q. Li 28 Derivation of the Kelvin (1870) Equation - Curvature effect on saturation •Surface energy associated with curved surface has impact on equilibrium vapor pressure and rate of evaporation. •Let equilibrium vapor pressure over a flat surface be es. •And over a curved surface be esr. •Consider droplet in equilibrium with environment, temperature = T and vapor pressure = ec Copyright © 2010 R. R. Dickerson & Z.Q. Li 29 Specific Gibbs function gives g = u + pa - Tj note that g remains constant in an isothermal, isobaric change of phase. For the environment g3 = u 3 + e ca 3 - Tj 3 For the droplet g 2 = u 2 + (e c + pi )a 2 - Tj 2 Where ec + pi is the total pressure inside the droplet Copyright © 2010 R. R. Dickerson & Z.Q. Li 30 Note pi 2s r 2s g 2 U 2 (ec ) 2 T2 r Now in equilibriu m g 2 g3 2s i.e. u 2 (ec ) 2 T2 u3 ec 3 T3 r Now conside an isothermal change in phase But for a droplet of radius r dr g g 2 dg 2 g3 dg3 Copyright © 2010 R. R. Dickerson & Z.Q. Li 31 Remember dq = du + pdv 2s dg2 = du2 + da 2 (ec + ) r 2s + a 2 (dec - 2 dr ) - Tdj 2 r + j 2 dT 2s )da 2 = Tdj 2 r and dT = 0 (isothemal) But du2 + (ec + Substituting Tdj 2 into above 2s dg2 = a 2 (dec - 2 dr) r Copyright © 2010 R. R. Dickerson & Z.Q. Li 32 Similar analysis for g 3 gives dg 3 α3dec Here 2s 2(dec 2 dr) 3dec r 2s or ( 3 2 )dec 2 2 dr r 1 But 2 2s dr ( 3 2 )dec r 2 Copyright © 2010 R. R. Dickerson & Z.Q. Li 33 In general, specific volume of vapor 3is much greater th an droplet, 2 Hence formula becomes 2σ dr α3dec 2 r and as RV T α3 ec dec 2s dr 2 ec RvT r Copyright © 2010 R. R. Dickerson & Z.Q. Li 34 Now integrate equation from a flat plate (r , ec es(T)) To a droplet of radius r (ec esr ) esr r dec 2σ dr e ec RV Tρω r 2 s 2σ esr ln es(T) RV Tρω r 2σ es ( r ) es (T) exp ( ) RV Tρω r Kelvin’s Equation, R&Y Eq 6.1 Copyright © 2010 R. R. Dickerson & Z.Q. Li 35 The relative humidity and supersaturation (both with respect to a plane surface of pure water) for pure water droplets. Copyright © 2010 R. R. Dickerson & Z.Q. Li 36 An embryonic cloud droplet (molecular cluster) can be formed by collision of water vapor molecules. Once it exists, it may grow or decay depending on ambient water vapor pressure. S = e/es(∞). e>esr, the droplet tends to grow, e<esr, the droplet tends to decay. So, the droplet must be big enough for it to endure. We will show that the critical radius (S is supersaturation) is: 2s rc Rv wT ln S Copyright © 2010 R. R. Dickerson & Z.Q. Li 37 Kelvin Curve Köhler curve S* - critical saturation ratio r* - critical radius Haze ← → Activated nucleus Copyright © 2010 R. R. Dickerson & Z.Q. Li 38 Fair Weather Cumulus Fair weather cumulus 1 pm EST July 7, 2007, a smoggy day 1.0 0.5 0.0 Copyright © 2010 R. R. Dickerson & Z.Q. Li 41 If the droplet does not evaporate then the vapor pressure of the surroundin g environmen t must be supersatur ated (relative humidity much greater th an 100%) Not many clouds would form. Why then do we see clouds? Copyright © 2010 R. R. Dickerson & Z.Q. Li 42 Köhler Equation - Heterogene ous Nucleation Most efficient nuclei are hygroscopi c particles – souble in water. Let us look at growth of a droplet. Consider a droplet consisting of water and some dissolved substance. ehr as the equilibriu m vapor pressure over a spherical droplet of this solution. esr as the equilibriu m vapor pressure over a spherical droplet of pure water. es equilibriu m vapor pressure over pure plane water surface. Copyright © 2010 R. R. Dickerson & Z.Q. Li 43 we can write ehr eh ehr es es eh Where eh equilibriu m vapor pressure for a plane surface of solution. Now we have shown that 2σ esr e ρ RV Tr es Likewise, for a solution droplet 2σ ehr e ρRV Tr eh σ surface tension of solution droplet ρ density Copyright © 2010 R. R. Dickerson & Z.Q. Li 44 We now have to find an equation for eh es •Proportion of surface area occupied by water molecules n will be reduced in the approximate ratio n + n¢ where n¢ = # of water molecules. n = # of solute molecules (ions). •Assumes (a) Molecules retain their identity. (b) Cross-sectional area of both molecules are the same. (c) Molecules are uniformly spread over surface. Copyright © 2010 R. R. Dickerson & Z.Q. Li 45 • Qualitativ ely we would expect number of water molecules escaping surface to go down – lower equilibriu m vapor pressure. • eh es Raoult’ s law : eh n n 1 * • M (1 ) es n n n M* Mole fraction of water in the solution Copyright © 2010 R. R. Dickerson & Z.Q. Li 46 we now have ehr eh ehr n 1 (1 ) e es es eh n M* e 2s RV Tr 2s RV Tr What if molecules of solute dissociate into ions • n must be replaced by in Copyright © 2010 R. R. Dickerson & Z.Q. Li 47 i # of dissociati ng ions per molecule in 1 * • M (1 ) n • Note N M n o s ms n No M w mw M mass m molecules mass N o Avogadr os number Copyright © 2010 R. R. Dickerson & Z.Q. Li 48 Hence M s mw in i ( ) n M w ms 4 3 But M w r M s 3 iM s mw 1 in (1 ) (1 ) 3 n r 3 M s ms 4 ehr iM s mw 1 (1 ) e 3 es r 3 M s ms 4 In a dilute solution M s M w w s s Copyright © 2010 R. R. Dickerson & Z.Q. Li 2s w RV Tr 49 Hence in 1 in M (1 ) 1 n n 3iM s mw 1 ( ) 3 4 r ms * b 1 3 r 2s and Where ehr b w RV Tr (1 3 )e es r 2s a w RV T 3.3 10 5 o ( k cm) T 3iM s mw Ms b ( ) 4.3i cm 3 mole 1 4w ms ms Copyright © 2010 R. R. Dickerson & Z.Q. Li 50 a ehr b (1 3 ) e r es r For T 300 o K a 1 10 7 cm r 0.1 10 5 0.1m a r 1 10 2 a r a e 1 r Then ehr b a (1 3 )(1 ) es r r b a ab 1 3 4 r r r Copyright © 2010 R. R. Dickerson & Z.Q. Li 51 Kelvin Curve Köhler Curve Copyright © 2010 R. R. Dickerson & Z.Q. Li 52 ehr a b 1 3 es r r See Equation 6.6 Supersatur ation ehr Define S S 1 1 es * a b 3 r r r has a critical value given as 1 * 3 b ds r * ( ) 2 where 0 a dr Copyright © 2010 R. R. Dickerson & Z.Q. Li 53 Next lecture will show where these trends come from. Copyright © 2010 R. R. Dickerson & Z.Q. Li 55 Copyright © 2010 R. R. Dickerson & Z.Q. Li 56