Chemical Formulas and Equations Getting started with some definitions… ATOM - is the smallest whole part of an element ELEMENT - matter made of only one kind of atom MOLECULE - two or more elements that have chemically combined Each new element is identified by a capital letter Example: H2SO4 There are three ELEMENTS in sulfuric acid Hydrogen Sulfur Oxygen CHEMICAL FORMULA - contains chemical symbols and subscripts to show the number and types of atoms in a compound SUBSCRIPT – after a chemical symbol and shows the number of each ATOM in a chemical formula • Example: C12H22O11 • • • • 12 atoms of Carbon 22 atoms of Hydrogen 11 atoms of Oxygen If there is no subscript, it is understood to be 1 • Example: NaCl • • 1 atom of Sodium 1 atom of Chlorine You Practice! NaHCO3 K2Cr2O7 Na = 1 H=1 C=1 O=3 K=2 Cr = 2 O=7 What about Formulas with Parentheses??? EX: Pb(NO3)2 • The “2” after the parenthesis indicates there are two of what’s in the parentheses • You could think of it this way: (NO3) and (NO3) You MULTIPLY everything INSIDE the parentheses by the subscript at the end: Pb = 1 N = 2 (1 N x 2) O = 6 (3 O x 2) You Practice!! (NH4)3PO4 Mg(OH)2 N=3 H = 12 P=1 O=4 Mg = 1 O=2 (2 x 1 O) H=2 (2 x 1 H) (3 x 1 N) (3 x 4 H) (1 x 1 P) (1 x 4 O) COEFFICIENT - in front of the chemical formula and shows the number of MOLECULES 2 H2(SO4) • This means there are 2 molecules of H2(SO4) • You could think of it this way – H2(SO4) and H2(SO4) • MULTIPLY coefficients by ALL of the subscripts in the chemical formula: 2H2SO4 H = 4 (2 x 2 H) S = 2 (2 x 1 S) O = 8 (2 x 4 O) You Practice!! 2 H2O H=4 O=2 3 Ca3(PO4)2 (2 x 2 H) (2 x 1 O) Ca = 9 (3 x 3 Ca) P = 6 (3 x 1 P x 2) O = 24 (3 x 4 O x 2) Got It???? Homework Time… Counting Atoms WS Chemical Equations A CHEMICAL EQUATION shows what happens in a chemical reaction 2 K + Cl2 2 KCl Reactants Products “yields” • The + separates molecules on the same side Law of Conservation of Mass • States that mass cannot be created or destroyed • • In other words, the mass of the reactants is equal to the mass of the products Proved by French chemist Antoine Lavoisier (1742-1794) • known as the “Father of Modern Chemistry” Lavoisier, 1788 So what does that have to do with anything?? Well, consider the following equation: • H 2 + O2 H2O Reactants: H=2 O=2 Products: H=2 O=1 This cannot happen….an oxygen atom cannot be destroyed!!! So what do we do? The chemical equation must be written according to the law of conservation of mass How it actually happens in nature is like this…. 2 H 2 + O2 2 H 2O Coefficents are added to balance on paper… Reactants: H=4 O=2 Products: H=4 O=2 There MUST be the same number AND types of atoms on both sides of the equation! Are These Equations Balanced? Na + O2 Na = 1 O=2 Mg + 2 HCl Mg = 1 H=2 Cl = 2 Na2O Na = 2 O=1 NOPE MgCl2 + H2 Mg = 1 YEP!! H=2 Cl = 2 You Practice!!! MgO Mg = 1 O= 1 N2 + 3 H2 N= 2 H= 6 Mg + O2 Mg = 1 O= 2 2 NH3 N= 2 H= 6 NOPE YEP!! Zn + 2 HCl ZnCl2 + H2 Zn = 1 H= 2 Cl = 2 Zn = 1 H = 2 Cl = 2 YEP!! More Practice K + Br2 K= 1 Br = 2 KBr K= 1 Br = 1 Fe + O2 Fe = 1 O= 2 2Na + 2H2O Na = 2 O= 2 H= 4 6Fe2O3 NOPE Fe = 12 O = 18 2NaOH + H2 Na = 2 O=2 YEP!! H= 4 NOPE So What About the Unbalanced Equations???... WE MUST BALANCE THEM!! 2 K + Br2 K= 1 2 Br = 2 2 KBr K=1 2 Br = 1 2 Add COEFFICIENTS and recount More Practice 6 Fe + 9 O2 Fe = 1 12 O = 2 18 6Fe2O3 Fe = 12 O = 18 Add COEFFICIENTS and recount One More!!! 4 Na + O2 Na = 1 4 O=2 2 Na2O Na = 2 4 O=1 2 Add COEFFICIENTS and recount Got It??? Your turn… Homework time!! Balanced or Not?