NUCLEAR CHEMISTRY OBJECTIVE: TO EXPLAIN THE PROCESS OF RADIOACTIVE DECAY USING NUCLEAR EQUATIONS AND HALF LIFE Essential Question: How do unstable (radioactive) isotopes become stable? Radioactivity introduction • Radioactivity video – 4 minutes • http://ed.ted.com/lessons/radioactivity-expect-the• • • • unexpected-steve-weatherall Review questions: http://ed.ted.com/lessons/radioactivity-expect-theunexpected-steve-weatherall#review Dig deeper: http://ed.ted.com/lessons/radioactivity-expect-theunexpected-steve-weatherall#digdeeper Review: Radioactive Isotopes A radioactive isotope has an unstable nucleus that undergoes spontaneous changes. - Emits particles - 1. - 2. - Emits energy in the form of __________ waves. - Transmutates into another element Types of Radiation Alpha Decay Beta decay Gamma Decay Particles emitted from a radioactive isotope Type Symbol Next slide Charge Mass Rad.Strength Radiation Strength: Explain in your notes how each of the radioactive emissions are blocked. Which is the most damaging (strongest)? Strong Nuclear Force: Holds the nucleus together Limit to the # neutrons: A nucleus with too many neutrons will be unstable and change Balancing Nuclear Reactions • Keep track of atomic number (Z) and mass number (A): protons & neutrons • Totals of A & Z must be the same before and after the reaction. • Shown by “Before” “ After” Nuclear reactions Total number of atomic numbers and the total mass numbers must be equal on both sides of the equation. Examples: Nuclear Equations 1. 2. 3. 238 U 234 Th + ? 92 90 14 C 0 e + ? 6 -1 239 Pu + 4 He 242 Cm 94 2 96 +? Nuclear Equations Practice Website Nuclear Reactions Emission of Alpha or Beta particles • http://phet.colorado.edu/en/simulation/beta-decay • http://phet.colorado.edu/en/simulation/alpha-decay Radioactive decay No two radioactive isotopes decay at the same rate. Therefore, decay rate can be used to identify the isotope. Decay is measured by half life. Half-life • Measure of Radioactive decay rate. • Measured as the time it takes for ½ of a sample of radioisotope’s nuclei to decay into its products. Half Life Decay of a radioisotope Number of Elapsed time Half-Lives 0 0 Amount remaining 100 g 1 1.5 year 50 g 2 3 years 25 g 3 4.5 years 12.5 g • Examples of the Half Life of Radioactive Elements Tearing Through a Half Life 800 Billion Bismuth-210 Atoms Time (years) Half Life: • http://phet.colorado.edu/en/simulation/radioactive-dating- Number of radioactive isotopes game Number of years Fission and Fusion • http://phet.colorado.edu/en/simulation/nuclear-fission Half life Calculations • How much of a 100g sample of an unstable isotope remains after 25 years if the half life is 5 years? • Determine how many “half life intervals”. • Calculate the amount of original sample remaining after each ½ life 100g • Simplify the calculations Half Life Problems • How much of a 100g sample of an unstable isotope remains after 25 years if the half life is 5 years? 3.1 g Half Life Problems • How much of a 60g sample of an unstable isotope remains after 2 days if the half life is 12 hours? 7.5 g Half Life Problems • How much of a 20 g sample of an unstable isotope remains after 3 sec if the half life is 0.5 seconds? Fission and Fusion • http://phet.colorado.edu/en/simulation/nuclear-fission ORIGINS OF ELEMENT Reading Analysis: Teachers' Domain: The Origin of the Elements Teachers' Domain: The Elements: Forged in Stars Got Calcium • Where are most elements created? • When was H and He created? • What elements are made by small stars? • What additional elements are made by large stars? • What elements are made by supernovae (large exploding stars)?