Kurdistan Regional Government – Iraq Council of Ministers Ministry of Higher Education & Scientific Research University of Salahaddin-Erbil College of Science Chemistry Department Course Description Course Title Class Year Course Credits Course Time Course Duration Instructor E-mail Course information Kinetic chemistry 3rd Year student 2013-2014 2hr. Tue. Group-2(8.30-10.30) & Group-1(11.30-1.30) 30 weak Dr. Shireen I. Hamadamin Shireenhawlery@gmail.com References Title Physical chemistry Authors F. Daniels & R.A. Alberty Publisher John Wiley and Sons, Inc. Year 1966 Edition 3rd Ed. Other References (1) Chemical kinetics, K. j. Ladler, 3rd Edition, Harper Collins Pub.1987. (2) Physical chemistry, Atkins & de paula, 7th ed., Oxford University press, 2007. Assessment Type 1st Exam 2nd Exam Other Final Exam Evaluation Policy Expected Date Wed /2/2014 Wed /4/2014 Homework & Discussion Weight 20% 20% 10% 50% Teaching and learning Methods Lectures: that covers and explains the chemical concepts mentioned above. All lectures will be presented by the aid of Data show and will be supported by doing the following techniques. Solved examples: from the text or from problems set will be given to you. Home works, the student must submit a complete report for solutions of the given problems: Short Report: from the course outline, using the Internet, Journals and any other Text Books in Physical chemistry. (5-Marks) Course Outline Chapter 1 1.1 Kinetic molecular theory of gases: (6)Lectures (1)Lec. Discussion 1.2 Postulates of kinetic theory of gases: 1.3 Ideal gas properties: 1.4 Pressure of an ideal gas: 1.5 The kinetic energy of transition 1.6 Root mean square velocity 1.7 Number of collision with the wall: 1.8 Viscosity 1.8.1 Difference in origin of viscosity of a liquid and a gas: 1.8.2 Kinetic theory of gas viscosity 1.9 Mean free path: 1.10 Boltzman distribution of molecular speed: 1.11 Maxwell speed distribution: 1.12 Velocity distribution in one dimension 1.13 Velocity distribution in three dimensions Chapter 2 2.1 Chemical kinetic (12)Lectures 2.2 Rate of reaction: (1)Lec. Discussion 2.3 Factors affecting on the rate of reaction: 2.4 Order of reaction: 2.5 Molecularity of reaction: 2.6 Pseudo order of reaction and apparent rate constant 2.7 Zero order reaction 2.8 First order reaction 2.9 Second-order reactions 2.10 3rd-order reactions 2.11 n-th-order reactions 2.12 Determination of the order of the reaction 2.13 Effect of temperature: 2.14 Energy of activation 2.15 Pressure effect 2.16 Effect of solvent 2.17 Ionic strength effect Exam1 2.18 Theories of reaction Rates 1-Collision theory: 2-The transition-state theory(activation energy theory) 2.19 Complex reactions 1234- Parallel reactions Reversible reactions Consecutive reactions Chain reactions Chapter3 3.1 Photochemistry: (4)Lectures 3.2 Lows in photochemical reactions: (1)Lec. Discussion 3.3 Thermal and photochemical reactions: 3.4 Primary and secondary photochemical reactions: 3.5 Quantum yield: 3.6 Energy transfer and photosensitization: 3.7 photochemical reaction kinetics Exam 2 Chapter 4 4.1 Catalytic reactions 4.1.1 Homogeneous catalysis: (4)Lectures 4.1.2 Heterogeneous catalysis: (1)Lec. Discussion 4.2 Langmuir isotherm: 4.3 Enzyme Kinetics 4.4 Michaelis - Menten Kinetics