2.1 Atoms, Ions, and Molecules KEY CONCEPT All living things are based on atoms and their interactions. 2.1 Atoms, Ions, and Molecules Objectives • Identify elements common to all living things • Describe how ions form • Compare ionic and covalent bonding 2.1 Atoms, Ions, and Molecules Vocabulary • • • • • • • Atom Element Compound Ion Ionic bond Covalent bond Molecule • • • • • • Proton Neutron Electron Nucleus Atomic Number Atomic Mass 2.1 Atoms, Ions, and Molecules Living things consist of atoms of different elements. • An atom is the smallest basic unit of matter. • An element is one type of atom. Hydrogen atom (H) H Oxygen atom (O) O 2.1 Atoms, Ions, and Molecules • An atom has a nucleus and electrons. – The nucleus has protons and neutrons. – Electrons are in energy levels outside nucleus. - The outermost energy level determines the activity of the atom Oxygen atom (O) Nucleus: 8 protons (+) 8 neutrons outermost energy level: 6 electrons (-) inner energy level: 2 electrons (-) 2.1 Atoms, Ions, and Molecules Atoms want to be stable • Energy levels want to be full of electrons • Each level can hold a different number of electrons – 1st energy level wants 2e– 2nd energy level wants 8 electrons – 3rd energy level wants either 8 or 18 – Lower energy levels always fill up before higher energy levels If the energy level isn’t full, the atom is not stable and will react with other atoms and form bonds! 2.1 Atoms, Ions, and Molecules • A compound is made of atoms of different elements bonded together. – water (H2O) _ O H + H + 2.1 Atoms, Ions, and Molecules Atoms want to be stable • Different atoms have different numbers of energy levels • The outermost energy level of an atom is called its valence shell • Electrons in the outermost energy level are called valence electrons • It’s the valence electrons that determine – what types of bonds will form – How many bonds will form 2.1 Atoms, Ions, and Molecules • A compound is made of atoms of different elements bonded together. – carbon dioxide (CO2) 2.1 Atoms, Ions, and Molecules Different Compounds are held together by different types of bonds • Covalent Bonds – Compounds held together by covalent bonds are called molecules • Ionic Bonds • Hydrogen Bonds • The type of bond that will form depends on the number of valence electrons Valence Electron Configuration Hydrogen 1H Mass number First shell 2 He 4.00 Atomic number Helium 2He Element symbol Electron distribution diagram Lithium 3Li Beryllium 4Be Boron 5B Carbon 6C Nitrogen 7N Oxygen 8O Fluorine 9F Neon 10Ne Silicon 14Si Phosphorus 15P Sulfur 16S Chlorine 17Cl Argon 18Ar Second shell Sodium Magnesium Aluminum 11Na 12Mg 13Al Third shell 2.1 Atoms, Ions, and Molecules Atoms share pairs of electrons in covalent bonds. • A covalent bond forms when atoms share a pair of electrons. – The number of covalent bonds depends on the number of valence electrons an atom has to share covalent bonds Oxygen atom (O) Carbon atom (C) Carbon dioxide (CO2 ) Oxygen atom (O) 2.1 Atoms, Ions, and Molecules • Covalent bonds are when atoms share electrons • Sometimes its easier for an atom to gain or lose an electron than to share • Atoms that gain electrons – Are called anions – what kind of charge will an anion have? • Atoms that lose electrons – Are called cations – what kind of charge will an cation have? 2.1 Atoms, Ions, and Molecules Ions form when atoms gain or lose electrons. • An ion is an atom that has gained or lost one or more electrons. • Ionic bonds form between oppositely charged ions. Opposites Attract gained electron Na loses an electron to CI Sodium atom (Na) Chlorine atom (CI) ionic bond Sodium ion (Na+) Chloride ion (CI-) 2.1 Atoms, Ions, and Molecules What distinguishes one element from another? • The number of protons in the nucleus 2.1 Atoms, Ions, and Molecules Describe the formation of an ionic compound • One atom gives up an electron, another atom picks up that electron • The atom that loses the electron has a positive charge • The atom that gains the electron has a negative charge • The two oppositely charged ions are attracted to each other and form an ionic bond 2.1 Atoms, Ions, and Molecules What is the difference between an ionic and a covalent bond? • An ionic bond is formed due to the electrical attraction between oppositely charged ions • A covalent bond is formed by a shared pair of electrons 2.1 Atoms, Ions, and Molecules How does a molecule differ from an atom? • A molecule is made up of 2 or more atoms held together by covalent bonds 2.1 Atoms, Ions, and Molecules Explain why a Hydrogen atom can become either an ion or a part of a molecule? • A hydrogen atom has one unpaired electron in its outer energy level • The electron can either be lost to form an ion, or shared to form a covalent bond 2.1 Atoms, Ions, and Molecules A sodium atom has one outer electron, and a carbon atom has 4 outer electrons. How might this difference be related to types of compounds formed by atoms of these 2 elements? • An atom that has a nearly full or nearly empty energy level (such as sodium) tends to form ions • An atom in between (such as carbon) tends to share electrons 2.2 Properties of Water KEY CONCEPT Water’s unique properties allow life to exist on Earth. 2.2 Properties of Water Objectives • Recognize the importance of hydrogen bonding • Explain why many compounds dissolve in water • Compare acids and bases 2.2 Properties of Water Vocabulary • • • • • • • • • • Hydrogen bond Cohesion Adhesion Solution Solvent Solute Acid Base pH Hydrogen ion 2.2 Properties of Water Life depends on hydrogen bonds in water. • Water is the only common substance found naturally in all three common states of matter and it is essential for all life on Earth • What kind of bonds are holding these 2 hydrogen atoms to the oxygen in this compound? 2.2 Properties of Water Life depends on hydrogen bonds in water. • Its true that these are covalent bonds holding the hydrogen atoms to the oxygen and so they are sharing electrons O H H • BUT oxygen does not share the electrons equally with the hydrogen atoms • Electrons spend more time on the oxygen side than the hydrogen side • What kind of charge will oxygen have? 2.2 Properties of Water Life depends on hydrogen bonds in water. • Water is a polar molecule. – Polar molecules have slightly charged regions. _ O H + H + – Nonpolar molecules do not have charged regions. – Hydrogen bonds form between slightly positive hydrogen atoms and slightly negative atoms. 2.2 Properties of Water • Hydrogen bonds are responsible for three important properties of water. – high specific heat – cohesion – adhesion 2.2 Properties of Water Specific Heat Capacity • Specific Heat is the amount of heat per unit mass required to raise the temperature by one degree Celsius • Water has a high specific heat capacity – This means it requires a lot of heat energy to raise the temperature of water – This allows water to moderate Earth's climate by buffering large fluctuations in temperature - Because water can absorb the heat from the air when its hotter, and release the heat when its cooler outside 2.2 Properties of Water Heat of vaporization • The energy required to transform a given quantity of a substance from a liquid into a gas • Water has a high heat of vaporization • Organisms exploit this in a process called evaporative cooling – As water evaporates it absorbs heat from the environment, leaving it cooler 2.2 Properties of Water Capillary Action and Surface Tension are products of adhesion & cohesion Cohesion • Water molecules are attracted to other water molecules • Water sticks to itself Adhesion • Water molecules are attracted to other polar molecules • Water sticks to things • EX: water sticks to the side of you cold soda cup on a hot day 2.2 Properties of Water Capillary Action and Surface Tension are products of adhesion & cohesion Surface Tension • A thin “skin” across the surface of water due to cohesion • https://www.youtube.com/watch?v=45yabrnryXk Capillary Action • water rises into a narrow tube against the force of gravity. • Water adheres to the inside wall of the tube and surface tension tends to straighten the surface causing a surface rise and more water is pulled up through cohesion 2.2 Properties of Water Many compounds dissolve in water. • A solution is formed when one substance dissolves in another. – A solution is a homogeneous mixture. – Solvents dissolve other substances. – Solutes dissolve in a solvent. solution 2.2 Properties of Water • “Like dissolves like.” – Polar solvents dissolve polar solutes. – Hydrophilic: water loving – Nonpolar solvents dissolve nonpolar solutes. – Hydrophobic: water fearing – Polar substances and nonpolar substances generally remain separate. – think oil (nonpolar) & water – vinegar (polar) & water 2.2 Properties of Water Some compounds form acids or bases. • An acid releases a hydrogen ion (H+) when it dissolves in water. – high H+ concentration – pH less than 7 stomach acid pH between 1 and 3 more acidic 2.2 Properties of Water • A base removes hydrogen ions from a solution. – low H+ concentration – pH greater than 7 bile pH between 8 and 9 more basic 2.2 Properties of Water • A neutral solution has a pH of 7. pure water pH 7 2.2 Properties of Water What causes a molecule to be polar? • Unequal sharing of electrons between atoms 2.2 Properties of Water How do polar molecules form hydrogen bonds? • The oppositely charged regions of a polar molecule attract other polar molecules, allowing positively charged hydrogen atoms to bond to a negatively charged atom 2.2 Properties of Water What are some of waters properties • • • • • Its found in all three phases (solid, liquid, gas) on earth High specific heat High heat of vaporization Adhesion Cohesion 2.2 Properties of Water How do organisms depend on waters properties to survive • Ice floats because its less dense allowing organisms to live on the ice or under , and acts as an insulator • Organisms utilize evaporative cooling (via sweating) to maintain proper body temperature • Plants use waters cohesive and adhesive properties to perform capillary action and transpiration • Animals and insects can walk or lay eggs on water due to its surface tension • Climate is regulated due to waters high specific heat • Water is an important solvent in which many chemical reactions take place 2.2 Properties of Water What determines whether a compound will dissolve in water • Compounds that have charges, such as ionic compounds (like table salt) and polar molecules (like sugar) will dissolve in water 2.1 Atoms, Ions, and Molecules Make a chart that compares acids and bases Acids • Donates protons Bases • Accept protons • In solution has a high H+ ion concentration • In solution has a low H+ concentration & a high concentration of OH- ions • pH below 7 • Has a pH above 7 2.1 Atoms, Ions, and Molecules How do polar molecules differ from nonpolar molecules? How does this difference affect their interaction? • Polar molecules have charged regions due to unequal sharing of electrons. • Nonpolar molecules do not have charged regions because electrons are shared more equally • The charge differences between polar and nonpolar molecules tend to keep the molecules separate 2.1 Atoms, Ions, and Molecules Describe an example of cohesion or adhesion that you might observe in your daily life • Cohesions: water beading on the surface of an object • Adhesions: water sticking to the outside of a milkshake cup on a hot day 2.1 Atoms, Ions, and Molecules When sugars are broken down to produce usable energy a large amount of heat is released. Explain how the water inside a cell helps to keep the cells temperature constant. • Water has a high specific heat – Specific heat: a measure of how much something resists temperature changes • Water in a cell can absorb a large amount of energy before its temperature increases 2.3 Carbon-Based Molecules KEY CONCEPT Carbon-based molecules are the foundation of life. 2.3 Carbon-Based Molecules Objectives • Describe the bonding properties of carbon atoms • Compare carbohydrates, proteins, lipids, and nucleic acids 2.3 Carbon-Based Molecules Vocabulary • • • • • • • • • • Monomer Polymer Carbohydrate Monosaccharide Lipid Phospholipid Starch Cellulose Protein Amino acid • • • • • • • • • Peptide bond Nucleic acid Nucleotide Glycogen Chitin Primary structure Secondary structure Tertiary structure Quaternary structure 2.3 Carbon-Based Molecules Carbon atoms have unique bonding properties. • How many electrons does a carbon atom have? • How many of those electrons are valence electrons? • How many more electrons does carbon need to be stable? • How many covalent bonds do you think carbon will make to accomplish this? 2.3 Carbon-Based Molecules Carbon atoms have unique bonding properties. • Carbon forms covalent bonds with up to four other atoms, including other carbon atoms. • Carbon-based molecules have three general types of structures. – straight chain – branched chain – ring 2.3 Carbon-Based Molecules • Many carbon-based molecules are made of many small subunits called monomers bonded together to form polymers. – Monomers are the individual subunits. – Polymers are made of many monomers. 2.3 Carbon-Based Molecules Four main types of carbon-based molecules are found in living things. • Carbohydrates are made of carbon, hydrogen, and oxygen. 2.3 Carbon-Based Molecules Four main types of carbon-based molecules are found in living things. • Carbohydrates include sugars and starches – MonomersMonosaccharides – Glucose – Fructose – Galactose – Polymers Polysaccharides – Starches – Cellulose – Glycogen – Chitin 2.3 Carbon-Based Molecules • Carbohydrates can be broken down to provide energy for cells. • Some carbohydrates are part of cell structure. Polymer (starch) Starch is a polymer of glucose monomers that often has a branched structure. Polymer (cellulose) monomer Cellulose is a polymer of glucose monomers that has a straight, rigid structure 2.3 Carbon-Based Molecules • Lipids are nonpolar molecules that include fats, oils, and cholesterol. – Many contain carbon chains called fatty acids. – Fats and oils contain fatty acids bonded to glycerol. Triglyceride 2.3 Carbon-Based Molecules • Lipids have several different functions. – broken down as a source of energy – make up cell membranes – used to make hormones 2.3 Carbon-Based Molecules • Fats and oils have different types of fatty acids. – saturated fatty acids – unsaturated fatty acids 2.3 Carbon-Based Molecules • Phospholipids make up all cell membranes. – Polar phosphate “head” – Nonpolar fatty acid “tails” Phospholipid 2.3 Carbon-Based Molecules • Proteins are polymers of amino acid monomers. – Twenty different amino acids are used to build proteins in organisms. 2.3 Carbon-Based Molecules • Proteins are polymers of amino acid monomers. – Twenty different amino acids are used to build proteins in organisms. – Amino acids differ in side groups, or R groups. 2.3 Carbon-Based Molecules • Proteins are polymers of amino acid monomers. – Twenty different amino acids are used to build proteins in organisms. – Amino acids differ in side groups, or R groups. – Amino acids are linked by peptide bonds. 2.3 Carbon-Based Molecules • Proteins differ in the number and order of amino acids. – Amino acids interact to give a protein its shape. Hemoglobin hydrogen bond – Incorrect amino acids change a protein’s structure and function. 2.3 Carbon-Based Molecules 2.3 Carbon-Based Molecules • Nucleic acids are polymers of monomers called nucleotides. 2.3 Carbon-Based Molecules • Nucleic acids are polymers of monomers called nucleotides. – Nucleotides are made of a sugar, phosphate group, and a nitrogen base. A phosphate group deoxyribose (sugar) nitrogen-containing molecule, called a base 2.3 Carbon-Based Molecules • Nucleic acids are polymers of monomers called nucleotides. – Nucleotides are made of a sugar, phosphate group, and a nitrogen base. DNA – DNA stores genetic information . – RNA is used to build RNA proteins. 2.3 Carbon-Based Molecules What is the relationship between a polymer and a monomer • A polymer is a large molecule made up of many smaller units called monomers that are linked together 2.3 Carbon-Based Molecules Explain how both nucleic acids and proteins are are polymers. Be sure to describe the monomers that make up the polymers. Proteins Composed of monomers called amino acids There are 20 different amino acids to choose from Nucleic Acids • They’re both polymers because they’re both made of smaller units bonded together Composed of monomers called Nucleotides Each nucleotide consists of a sugar, phosphate group, and nitrogenous base 2.3 Carbon-Based Molecules How are carbohydrates and lipids similar? How are they different Carbohydrates Includes sugars and starches Shorter term energy storage Cellulose in plant cell walls and chitin in fungi cell walls Lipids -Both made of C,H, & O -Broken down as a source of energy -Have some structural functions Includes fats, oils, and waxes Longer term energy storage Phospholipids in the plasma membrane 2.3 Carbon-Based Molecules Explain how the bonding properties of carbon atoms result in the large variety of carbon-based molecules in living things • Carbon atoms are able to form 4 covalent bonds with other atoms including other carbon atoms • Many other types of atoms can bind to carbon, and many different combinations are possible 2.3 Carbon-Based Molecules Why might fatty acids, amino acids, and nucleic acids increase the hydrogen ion (H+) concentration of a solution? Explain your answer. • These molecules are all acids • Acids, by definition, increase the H+ ion concentration of a solution, and there by lower the pH 2.4 Chemical Reactions KEY CONCEPT Life depends on chemical reactions. 2.4 Chemical Reactions Objectives • Describe how bonds break and reform during chemical reactions • Explain why chemical reactions release or absorb energy 2.4 Chemical Reactions Vocabulary • • • • • • • • Chemical reaction Reactant Product Bond energy Equilibrium Activation energy Endothermic Exothermic 2.4 Chemical Reactions Bonds break and form during chemical reactions. • Chemical reactions change substances into different ones by breaking and forming chemical bonds. – Reactants are changed during a chemical reaction. – Products are made by a chemical reaction. 2.4 Chemical Reactions • Bond energy is the amount of energy that breaks a bond. – Energy is added to break bonds. – Energy is released when bonds form. • A reaction is at equilibrium when reactants and products form at the same rate. CO2 + H2O H2CO3 2.4 Chemical Reactions Chemical reactions release or absorb energy. • Activation energy is the amount of energy that needs to be absorbed to start a chemical reaction. 2.4 Chemical Reactions • Exothermic reactions release more energy than they absorb. – Reactants have higher bond energies than products. – Excess energy is released by the reaction. 2.4 Chemical Reactions • Endothermic reactions absorb more energy than they release. – Reactants have lower bond energies than products. – Energy is absorbed by the reaction to make up the difference. 2.4 Chemical Reactions Hydrogen peroxide (H2O2) breaks down into water (H2O) and oxygen (O2). A) Explain why this is a chemical reaction. B) what are the reactants? C) what are the products? • A) it is a chemical reaction because different substances are formed • B) reactant = Hydrogen peroxide (H2O2) • C) products = water (H2O) and oxygen (O2) 2.4 Chemical Reactions How do endothermic and exothermic reactions differ? • Endothermic reactions absorb energy because the products have a higher bond energy than the reactants have • Exothermic reactions release energy because the products have a lower bond energy than the reactants have 2.4 Chemical Reactions The process below is exothermic. What must be true about the bond energies of the reactants and the products? Explain. 6O2 + C6H12O6 6CO2 + 6H2O • The bond energies of the reactants must be higher than those of the products because energy is released. 2.4 Chemical Reactions Why might it not always be possible to determine the reactants and the products in a reaction? Explain your answer in terms of chemical equilibrium. • Depending on the concentrations of the reactants and the products, both reactants and products may be formed at the same time if the reaction is reversible. • At equilibrium, reactants and products are formed at the same rate 2.4 Chemical Reactions A chemical reaction can start when enough activation energy is added to the reactants. Do you think the activation energy for chemical reactions in living things is high or low? Explain your answer. • The activation energy for reactions must be relatively low because temperature can not be greatly increased in living things. 2.5 Enzymes KEY CONCEPT Enzymes are catalysts for chemical reactions in living things. 2.5 Enzymes Objectives • Explain the effect of a catalyst on activation energy • Describe how enzymes regulate chemical reactions 2.5 Enzymes Vocabulary • • • • Catalyst Enzyme Substrate Active site 2.5 Enzymes A catalyst lowers activation energy. • Catalysts are substances that speed up chemical reactions. – decrease activation energy – increase reaction rate 2.5 Enzymes Enzymes allow chemical reactions to occur under tightly controlled conditions. • Enzymes are catalysts in living things. – Enzymes are needed for almost all processes. – Most enzymes are proteins. 2.5 Enzymes • Disruptions in homeostasis can prevent enzymes from functioning. – Enzymes function best in a small range of conditions. – Changes in temperature and pH can break hydrogen bonds. – An enzyme’s function depends on its structure. 2.5 Enzymes • An enzyme’s structure allows only certain reactants to bind to the enzyme. – substrates – active site substrates (reactants) enzyme Substrates bind to an enzyme at certain places called active sites. 2.5 Enzymes • The lock-and-key model helps illustrate how enzymes function. – substrates brought together – bonds in substrates weakened Substrates bind to an enzyme at certain places called active sites. The enzyme brings substrates together and weakens their bonds. The catalyzed reaction forms a product that is released from the enzyme. 2.5 Enzymes How does a catalyst affect the activation energy and rate of a reaction • A catalyst reduces the activation energy required to start a reaction • A catalyst speeds up the rate of chemical reactions 2.5 Enzymes Describe how the interaction between an enzyme and its substrates changes a chemical reaction • An enzyme brings substrates close together and slightly alters (weakens) the bonds within the substrates by changing the shapes of the molecules so that they can react 2.5 Enzymes Some organisms live in very hot or acidic environments. Would their enzymes function in a persons cells? Why or why not? • NO • Those enzymes function optimally under different conditions than those found in a person 2.5 Enzymes Suppose that the amino acids that make up an enzymes active site are changed. How might this change affect the enzyme? • The substrates would likely not bond to the enzyme because the shape of the active site would change. 2.5 Enzymes Organisms need to maintain homeostasis, or stable internal conditions. Why is homeostasis important for the function of enzymes? • If homeostatic conditions, such as temperature, ionic (salt) concentrations, or pH are not maintained, then the hydrogen bonds that keep an enzyme in its correct shape will weaken or break and the enzymes structure will change. Because enzymes function is determined by their structure, changing their shape will affect their function