Chapter 18.1 The Solid-Waste Problem municipal solid waste: total of all materials thrown away from homes and commercial establishments different from nonhazardous industrial waste includes wastes from construction and demolition projects, sewage treatment sludge, wastes generated from industrial processes disposal of municipal solid waste amount of MSW generated in U.S. has grown steadily growing population increasing use of disposable materials and excessive packaging 1960 = 2.7 pounds / person / day 2006 = 4.5 pounds / person / day MSW composition refuse generated by municipalities is a mixture of materials from households and small businesses varies based on generator (commercial / residential) neighborhood (affluent / poor) time of year (spring / summer / fall) restrictions and prohibitions are bypassed with careful packing of trash containers methods of disposal until the 1960s, almost all waste was burned in open dumps burning reduced volume and increased lifespan of dump produced clouds of smoke and served as breeding ground for rats, flies, and other pests open dumps were replaced in 1960s and 70s with incinerators huge furnaces burned waste more completely at high temperatures path of trash U.S. in 2003 55.4% = landfill 30.6% = recycling or composting 14% = combustion percentage of recycled materials is increasing in U.S. countries with greater population densities (i.e. Japan) burn a much higher percentage landfills landfill: waste is put on or in the ground and is covered with soil each day’s fill is covered with at least 6 inches of soil helps control air pollution and pests first landfills did little to consider ecology, water cycle, or potential for hazardous products when waste components react problems of landfills subjected to biological and physical factors in the environment and undergo change over time problems: leachate methane production incomplete decomposition settling leachate leachate: as water percolates through the landfill, various chemicals dissolve and are carried by the solution likely to include residues of decomposing organic matter with iron, mercury, lead, zinc, and other metals from rusting cans and batteries, along with paints, pesticides, cleaning fluids, and other chemicals areas like Florida, where the groundwater is often just below the surface, have experienced extensive water pollution as a result of unlined landfills methane production because it is about 2/3 organic material, MSW is subject to natural decomposition buried wastes do not have access to oxygen, meaning decomposition is anaerobic produces biogas mixture that is about 2/3 methane, with some hydrogen and carbon dioxide mixture is highly flammable may explode under certain conditions some cities have installed gas wells to tap the landfill gas methane is purified and used for fuel incomplete decomposition common plastics in MSW resist decomposition polymers of petroleum-based compounds that cannot be broken down by microbes (biodegradable plastic polymers have now been developed from cornstarch and soybeans) demand for products based on two factors: 1. price of oil 2. demand for environmentally friendly packages biodegradable materials such as newspaper and wood often degrade slowly or not at all in landfills (mostly due to lack of moisture) settling occurs as waste compacts and decomposes issue for landfills that have been converted to playgrounds and golf courses creates shallow depressions Chapter 18.1 (cont.) Siting New Landfills from 1988 to 2002, number of municipal landfills declined from ~8000 to 1767 increase in size of landfills combined with increase in recycling means that landfill capacity is not a problem in the U.S. however, “regional dislocations” occur as old landfills close, it’s increasingly difficult to to find land for new ones outsourcing problem with finding new sites has some undesirable consequences 1. drives up costs of waste disposal 2. leads to inefficient practice of long-distance transport of trash trash is often carried across state or national lines, leading to resentment from citizens of the locations receiving the waste 10 states import more than 1 million tons of MSW per year, while 8 states export more than 1 million tons per year combustion because of its high organic content, waste can be burned process is really waste reduction, not waste disposal after incineration, ash must still be disposed of advantages of combustion can reduce weight of trash by 70% and volume by 90% toxic or hazardous substances are concentrated into two streams of ash fly ash bottom ash captured from the combustion gases by air pollution control equipment contains most of the toxic substances; can be safely put in a landfill from the bottom of the boiler can be used as fill in some construction sites no changes are needed in consumer behavior or trash collection procedures advantages of combustion (cont.) 2/3 of combustion facilities are waste-toenergy (WTE) facilities equipped with modern emission control technologies when burned, unsorted MSW releases about 35% as much energy as coal facilities often do resource recovery, which separates some materials before (and sometimes after) combustion drawbacks of combustion air pollution and offensive odors facilities are expensive to build combustion ash is often loaded with metals and other hazardous substances even if it generates electricity, process wastes both energy and materials unless recycling and recovery are part of operation an operating facility plant receives about 3000 tons of MSW per day PROCESS 1. incoming waste is inspected, and recyclable and bulky materials are removed 2. waste is then shredded into pieces with a width of 6 inches or less 3. magnets remove 2/3 of ferrous metals for recycling 4. waste is blown into boilers an operating facility PROCESS (cont.) 5. water circulated through the walls of the boilers produces steam, which drives turbines for generating electricity 6. after waste is burned, bottom ash is conveyed to processing facility where further sorting of metals occurs (recovers brass, aluminum, gold, copper, and iron) 7. combustion gases are neutralized to remove sulfur dioxide and other gases 8. fly ash and bottom ash residues are put into landfills