General Chemistry Unit 10 2015 - 2016 Naming review Chemical Reaction/Equations Balancing Word Equations Translating to sentences You should be able to: 1. Count atoms in a given chemical formula, based on subscripts and coefficients. 2. Use coefficients to properly balance a chemical equation. 3. Express chemical equations into formula, word, and sentence form. 1 Refresher on Ionic Naming (metal and nonmetal) I II III IV V VI VII VIII IX X Formula to name: 1. Convert metal symbol to a name using the periodic table If it is Sn or Pb or it is a D-Block metal (except Scandium family (+3) , Ag (+1) Zn (+2), Cd (+2)) It will need a roman numeral To get the roman numeral, uncriss cross the subscripts and make them superscripts. PbBr2 Pb Br2 Pb2+ Br(Bromine is 1- from the periodic table) Check the negative charge…is it correct?? If yes, then so is the metal. Convert the number the metal has to a roman numeral and put it after the metal’s name. so in the above example the metal would be Lead (II) Another example: SnSO4 SO4 is a polyatomic (look on the blue sheet) so it looks like Sn is + and SO4 is – since they are in a one to one ratio BUT from the blue sheet we see the charge of SO4 is 2- which means Sn must be 2+ Tin (II) 2. Convert the anion to a name a. If it is a single element, it is named after an element on the periodic table. Make sure the name ends with – IDE (IDE—I’d check the table) b. If it is a polyatomic ion – check the blue sheet. If it matches the one on the blue sheet exactly – it will end in ATE If it has one more oxygen then the one on the sheet….PER…ATE If it has one less oxygen then the sheet ---ITE If it has 2 less oxygens then the sheet… HYPO…ITE 2 More examples: 1. BaCO3 2. Fe2O3 3. CrN 4. Cu3(PO5)2 Name to formula: 1. Convert the metal to its symbol You need its charge (it will be a positive superscript) If it has a roman numeral – that is the charge – it is positive If it doesn’t have a roman numeral you have to get it from the periodic table 2. Convert the nonmetal to its symbol (it will be a negative superscript) If it is a single element from the periodic table – use the oxidation pattern If it is a polyatomic, the charge will be on the blue sheet 3. To get the balanced formula you must criss cross If the subscripts can be simplified…you must do that! Ex: Iron (III) bromate = Fe3+ BrO3- = Fe3+ BrO3- = Fe(BrO3)3 More examples: 1. Titanium (II) oxide 2. Scandium chlorite 3. .Tin (IV) fluoride 4. Silver hypophosphite 3 Ionic Naming Worksheet Chemical name Ions 1 Ag+ (IO)- 2 Sb3+ (PO4)3- 3 Be2+ (ClO4)- 4 Sn4+ I- 5 Zn2+ Br- 6 Au+ (SO5)2- 7 Magnesium Perbromate 8 Copper (I) Sulfite 9 Calcium Carbonate 10 Chromium (II) Sulfide 11 Strontium Phosphite 12 Sodium Phosphide Ionic Formula 4 Refresher on Covalent Naming (2 nonmetals) mono di tri tetra penta hexa hepta octa nona deca Formula to Name: 1. Name the first nonmetal as it appears on the periodic table. Put a prefix counter in front of it to tell how many of them there are (see above). If there is only one…do not use the term mono – just use the element name 2. Name the second nonmetal a. if it is an element from the periodic table it will end in -IDE b. if it is a polyatomic it will end in ate, per ate, ite or hypo ite Put a prefix counter in front of it to tell how many of them there are. If there is only one – you must use the term mono ! Examples: 1. SF6 2. O2Cl5 3. H2O 4. N(SO4)3 Name to Formula: 1. Turn the first element name into a symbol a. If there is a prefix in front of it - convert it into a subscript after the element symbol b. If there is not a prefix, assume there is one of that element 2. Turn the second element into a symbol a. Take the prefix in front of it and convert it into a subscript after the element symbol Examples: 1. Silicon trioxide 2. Phosphorous pentafluoride 3. Dinitrogen hexasulfide 4. Trichlorine heptaiodide 5 Ionic and Covalent compounds Elements Ionic or Covalent Ions Chemical Formula Name of Compound 4 Phosphorus + 10 Oxygens CS2 Calcium + Chlorine Iron (III) + Bromine Na2O Potassium + Sulfur Si3N4 Triantimony pentasulfide Fe2(SO4)3 Strontium Chloride CuOH Nitrogen Dioxide H2O 6 Elements Ionic or Covalent Ions Chemical Formula Name of Compound Tin (IV) + Fluorine Cl2O7 Phosphorus Triodide CCl4 Beryllium + Nitrate Silicon monocarbide RbClO3 Al2O3 1 Carbon + 1 Oxygen 7 What's wrong on the right hand side of the arrow? 1. Trisilicon Pentoxide → 2. FeSO4 → Correct = Iron (II) Sulfide 3. Cr(NO3)3 → 4. P2Cl5 → S3O5 Correct = Chromium Nitrate Correct = Diphosphide Pentoxide Correct = 5. Copper (I) Oxide → CuO2 Correct = 6. Dinitrogen Tetrasulfide → (NO3)2 (SO4) Correct = 7. Barium Phosphate → Be3(PO4)2 Correct = Calcium (II) Bromide Correct = 8. CaBr2 → 9. SO → Sulfur Oxide Correct = Tin Oxide Correct = 10. SnO → 11. Hexanitrogen Dichloride → 12. NiC → N2Cl6 Nickel (II) Carbide 13. Zinc Fluoride → Correct = ZnFl2 14. Cobalt (II) Phosphide → Correct = Correct = Co3(PO4)2 Correct = 8 15. AgOH → Silver hydrate Correct = 9 10 11 Balancing Practice Problems 1. ___Na + ___MgF2 → ___NaF + ___Mg 2. ___Mg + ___HCl → ___MgCl2 + ___H2 3. ___Cl2 + ___KI → ___KCl + ___I2 4. ___NaCl 5. ___Na + ___O2 6. ___Na + ___HCl → ___Na + ___Cl2 → → ___Na2O ___H2 + ___NaCl 12 7. ___K + ___Cl2 → ___KCl Challenges: ___C7H6O2 + ___O2 → ___CO2 + ___H2O → ___CO2 + ___H2O ___C3H8 + ___O2 13 Balance each of the following equations: 1. ___ Zn + ___HCl ___ ZnCl2 + ___ H2 2. ___Sb + ___ O2 ___ Sb4O6 3. ___H3AsO4 ___ As2O5 + ___ H2O 4. ___N2O5 + ___H2O ___HNO3 5. ___Fe2O3 + ___ C ___CO + ___ Fe 6. ___Al4C3 + ___ H2O ___CH4 + ___ Al(OH)3 7. ___Si2H3 + ___ O2 ___ SiO2 + ___ H2O 8. ___Na2O2 + ___ H2O ___NaOH + ___O2 9. ___Ca3(PO4)2 + ___ H2SO4 ___CaSO4 + ___H3PO4 14 10. ___PCl5 + ___ H2O ___H3PO4 + ___ HCl 11. ___NH4NO3 ___ N2O + ___ H2O 12. ___BaCl2 + ___Al2(SO4)3 ___BaSO4 + ___AlCl3 13. ___C6H6 + ___ O2 ___CO2 + ___ H2O 14. ___As + ___NaOH ___Na3AsO3 + ___ H2 15. ___Ca10F2(PO4)6 + ___H2SO4 ___Ca(H2PO4)2 + ___CaSO4 + ___HF 15 One last balancing worksheet 1. ___Na2S + ____CaCl2 ____NaCl + ____CaS 2. ___Mg3N2 + ____H2O ____MgO + ____NH3 3. ___Al + ____O2 ____Al2O3 4. ___Sr(NO3)2 + ____Al2(CO3)3 5. ___C4H10 + ____O2 6. ___P4O10 + ____H2O 7. ___Al + ____Fe3O4 8. ___KClO3 ____SrCO3 + ____Al(NO3)3 ____CO2 + ____H2O ____H3PO4 ____Al2O3 + ____Fe ____KCl + ____KClO4 16 Converting chemical equations to word equations 1. ____Na2SO4 + ____BaCl2 ____BaSO4 + ____NaCl 2. ____ZnS + ____O2 ____ZnO + ____SO2 3. ____NH3 + ____O2 ____NO + ____H2O 4. ____Al + ____Br2 ____AlBr3 5. ____Mg3N2 + ____HCl 6. ____GaCl3 + ____F2 ____MgCl2 + ____NH3 ____GaF3 + ____Cl2 7. ____Na2SO4 + ____Pb(NO3)2 ____NaNO3 + ____PbSO4 17 8. ____FeCl3 + ____Na2CO3 9. ____CaCl2 + ____Na3PO4 10. ____S8 + ____F2 11. ____Zn + ____HCl 12. ____Mg + ____CuI2 ____Fe2(CO3)3 + ____NaCl ____NaCl + ____Ca3(PO4)2 ____SF6 ____ZnCl2 + ____H2 ____MgI2 + ____Cu 18 Converting word equations into chemical equations (I) 1. Magnesium Sulfate + Calcium Chloride 2. Beryllium Sulfide + Oxygen 3. Potassium Bromide + Chlorine Calcium Sulfate + Magnesium Chloride Beryllium Oxide + Sulfur Dioxide Potassium Chloride + Bromine 4. Calcium Phosphate + Dihydrogen Monosulfate Calcium Sulfate + Trihydrogen Monophosphate 5. Aluminum Chloride + Iodine 6. Iron + Dihydrogen Monosulfate Aluminum Iodide + Chlorine Iron (II) Sulfate + Sulfur Dioxide + Dihydrogen Monoxide 7. Phosphorous Pentachloride + Dihydrogen Monoxide Trihydrogen Monophosphate + Hydrogen Chloride 8. Aluminum Sulfide + Dihydrogen Monoxide Aluminum Hydroxide + Dihydrogen Monosulfide 19 Converting word equations into chemical equations (II) 1. Aluminum Bromide + Chlorine 2. Zinc + Lead (II) Nitrate Aluminum Chloride + Bromine Zinc Nitrate + Lead 3. Hydrogen + Carbon Monoxide 4. Sodium + Calcium Fluoride Dihydrogen Monoxide + Carbon Sodium Fluoride + Calciuim 5. Potassium Carbonate + Calcium Chloride 6. Iron (III) Oxide + Carbon Monoxide 7. Aluminum Oxide + Dihydrogen Monoxide 8. 9. Strontium Iodide + Lead(II) Phosphate Magnesium + Nitrogen Calcium Carbonate + Potassium Chloride Iron + Carbon Dioxide Aluminum Hydroxide Strontium Phosphate + Lead (II) Iodide Magnesium Nitride 10. Sodium Hydroxide + Hydrogen Chloride Sodium Chloride + Dihydrogen Monoxide 20 Translate the following sentences into a formula equation. 1. Solid sulfur trioxide and dihydrogen monoxide combine to make sulfuric acid (H2SO4). 2. Aqueous lead (II) nitrate and aqueous sodium iodide react to make solid lead (II) iodide and aqueous sodium nitrate. 3. Aqueous calcium fluoride and sulfuric acid react to form solid calcium sulfate and hydrofluoric acid (HF). 4. Solid calcium carbonate will come apart when heated to produce solid calcium oxide and carbon dioxide. 5. Aqueous aluminum sulfate and aqueous magnesium hydroxide will react to form solid aluminum hydroxide and aqueous magnesium sulfate. 6. Copper metal and aqueous silver nitrate react to form silver metal and aqueous copper (II) nitrate. 21 Write a balanced chemical reaction for each of the reactions described below: 1. Barium metal and aqueous hydrochloric acid (HCl) react to produce solid barium chloride and hydrogen gas. 2. Using heat, aqueous nitric acid (HNO3) reacts with solid magnesium hydroxide to make aqueous magnesium nitrate and liquid dihydrogen monoxide. 3. Solid Aluminum carbide reacts with dihydrogen monoxide in the liquid form at 450.0 oC to yield carbon tetrahydride gas and aluminum hydroxide solid. 4. Lead (II) acetate in the solid form and aqueous hydrosulfuric acid (H2S) react to form solid Lead (II) sulfide and liquid acetic acid. 22 Write out these reactions in word form and sentence form: 1. H2 (g) + Cl2 (g) 2HCl (aq) Word: Sentence: 2. 2Al (s) + Fe2O3 (aq) Al2O3 (aq) + 2Fe (s) Word: Sentence: 3. 8Pb (s) + S8 8PbS (s) Word: Sentence: 550 oC 4. PbSO4 (aq) + FeCl2 (aq) PbCl2 (s) + FeSO4 (aq) Word: Sentence: 23