Molar Mass & The Mole …..With Some Molar Conversions I II III IV What you will need….. Periodic Table Calculator Get them out now!!!! Please What is the Mole? A counting number (like a dozen) Avogadro’s number (NA) 1 mole = 6.022 1023 representative particles (atoms, molecules, formula units, ions, etc) Molar Mass Mass of 1 mole of an element or compound Atomic mass (on the PT) tells the... mass of each atom (amu) grams per mole (g/mol) Molar Mass Avogadro discovered the relationship between number of particles and volume of a gas This was used to find the relationship for particles in a mole Molar Mass Examples carbon 12.01 g/mol aluminum 26.98 g/mol zinc 65.37 g/mol Molar Mass Examples water H2O 2(1.008) + 15.999 = 18.02 g/mol sodium chloride NaCl 22.99 + 35.45 = 58.44 g/mol Molar Mass Examples sodium bicarbonate NaHCO3 22.99 + 1.008 + 12.01 + 3(15.999) = 84.01 g/mol sucrose C12H22O11 12(12.01) + 22(1.008) + 11(15.999) = 342.28 g/mol Molar Conversion Examples How many moles of carbon atoms are in 26 g of carbon? 26 g C 1 mol C 12.01 g C = 2.2 mol C Mole/Particle Conversions 6.022 1023 NA NUMBER MOLES OF 1 Mole (particles/mol) NA atoms/mol NA molecules/mol PARTICLES Particles = atoms, molecules, formula units, ions, etc Representative Particles & Moles Substance Chemical Representative Rep Particles Formula Particle in 1.00 mole Carbon C Atom 6.02 x 1023 Nitrogen gas N2 Molecule 6.02 x 1023 Calcium ion Ca2+ Ion 6.02 x 1023 Magnesium fluoride MgF2 Molecule 6.02 x 1023 Mole/Particle Conversion Examples How many molecules are in 2.50 moles of C12H22O11? 2.50 mol C12H22O11 6.02 1023 molecules C12H22O11 1 mol C12H22O11 = 1.51 1024 molecules C12H22O11 Mole/Particle Conversion Examples you have 2.23 x 1018 atoms of sodium, how many moles is that? If 2.23 1018 1 mole Na atoms Na 6.02 1023 atoms Na 3.70 x 10-6 = moles Na Mole/Particle Conversion Examples How many molecule are 3.75 moles of calcium hydroxide? 6.02 1023 3.75 molecules mol Ca(OH)2 Ca(OH)2 = 2.26 1024 1 mol Ca(OH)2 molecules Ca(OH)2 Molar Conversions 6.02 1023 NA molar mass MASS NUMBER MOLES IN GRAMS (g/mol) OF (particles/mol) PARTICLES Particles = atoms, molecules, formula units, ions, etc NA atoms/mol NA molecules/mol Molar Conversion Examples the mass of 2.1 1024 molecules of NaHCO3. 2.1 1024 84.01 g Molecules 1 mol NaHCO3 NaHCO3 NaHCO3 Find 6.02 1023 1 mol Molecules NaHCO3 NaHCO3 = 290 g NaHCO3 Molar Conversion Examples How many atoms are in 22.5 grams of potassium? 22.5 g K 1 mol K 6.02 1023 atoms K 39.10 g K 1 mol K = 3.46 x 1023 atoms K Gases •Many of the chemicals we deal with are gases. •They are difficult to weigh. •Need to know how many moles of gas we have? •Two things effect the volume of a gas • Temperature and Pressure •Compare at the same temp. and pressure Standard Temperature and Pressure 0ºC and 1 atm pressure abbreviated STP At STP 1 mole of gas occupies 22.4 L Called the molar volume Avogadro’s Hypothesis - at the same temperature and pressure equal volumes of gas have the same number of particles. Molar Volume Avogadro's Theory: Two gases containing equal numbers of molecules occupy equal volumes under similar conditions. Standard Temperature and Pressure: 0 oC and 1 atm Molar Volume at STP = 22.4 L Mole Calculations What is the mass of 3.36 L of ozone gas, O3, at STP? 3.36 L O3 1 mol O3 48 grams of O3 22.4 L O3 1 mol O3 = 7.2 grams of O3 Mole Calculations How many molecules of hydrogen gas, H2, occupy 0.500 L at STP? 0.50 L H2 1 mol H2 6.02 1023 molecules of H2 22.4 L H2 1 mol H2 = 1.34 x 1022 molecules H2 Mole Ratios The ratio of the moles of one molecule to the atoms within that molecule. molecular formulas give atom-to-atom and moleto-mole ratios example: molecular formula C6H12O6 atom-to-atom ratios atom-to-molecule ratios 6 atoms C 12 atoms H 6 atoms C 6 atoms O 12 atoms H 6 atoms O 6 atoms C 1 molecule 12 atoms H 1 molecule 6 atoms O 1 molecule Mole Ratios Example: molecular formula C6H12O6 mole-to-mole ratios (elements) 6 mol C 12 mol H 6 mol C 6 mol O 12 mol H 6 mol O mole-to-mole ratios (compound) 6 mol C 1 mol C6H12O6 12 mol H 1 mol C6H12O6 6 mol O 1 mol C6H12O6 problems that ask you to relate one substance to another require mole-to-mole ratios