Chapter 2 Notes Qualitative/Quantitative Precision/Accuracy Sig Figs Error/Percent Error What do you know? 1. What is a hypothesis? 2. What is the difference between an control and a variable? 3. What is the difference between an independent and dependent variable? Experiments System: Matter that you’ve chosen to observe and the region of space selected for study. Surroundings: the area around the system. Demo Draw a picture of what happened! Write a couple of sentences regarding what we will discuss. What is the System? Surroundings? MeasurementsWhy do you think measurements might be important to the study of chemistry? What kind of measurements are you familiar with? Day 1 of Measurement Activity Splash of Color- Accuracy and Precision Activity- Group Work Everybody is on task and working at all times. Everyone is responsible for handing in a completed assignment! Jobs: 1. Leader- Reads all the instructions (out loud) and keeps everyone on task 2. Scientist 1- Reviews instructions and does the task. 3. Recorder- Keeps careful record of all observations to share with other group members. Debrief the Activities: 1. What is the difference between quantitative and qualitative observation? 2. Which is most helpful to scientists? 3. What is the problem with using qualitative measures? Debrief 4. Was it a chemical or physical change? Types of Measurements Qualitativedescriptions no numbers determined using senses vary depending on observer Quantitative more definite use numbers (with units) only as good as the instrument used Quantitative Measure Quantity- a measure of magnitude, size or amount. Units- “Le Systeme International d’Unites. Adopted in 1960- agreed on world-wide 7 base units SI Base Units Quantity Symbol Name abbreviation Length l Meter m Mass m kilogram kg Time t Second s Temperature T Kelvin K Amount of substance n Mole mol Non-Si Units Used in Chemistry Physical Quantity Unit Name Symbol Volume Pressure L Atm Energy Liter Atmosphere Millimeters of mercury Torr Calorie Joule mmHg Torr Cal J Derived SI Units You already know two of these from Math! Area What formula would you use to determine the area of this rectangle? What would the units be? Volume What formula would you use to determine the volume of this box? What would the units be? Using a Graduated Cylinder Another way of determining volume is using this fabulous tool. 1ml = 1cm3 Always keep track of your Derived SI Units in any calculation! Quantity Unit Abbreviation Derivation Area Meter squared m2 LxW Volume Meter cubed m3 LxWxH Density Kilograms per cubic meter Kg/ m3 Mass/volume Molar Mass Kilograms/mol Kg/mol Mass/amt of substance Density What formula do we use to calculate density. What do we need to measure? Density Density = Mass/Volume Density is a useful way of determining the identity of a substance! Is it a chemical or physical property? Try a practice problem!! A sample of aluminum metal has a mass of 8.4g. The volume of the sample is 3.1 cm3. Calculate the density. What is the difference between accuracy and precision? The Accuracy/Precision Activity looks at How “Good” is the measurement? Accuracy- how close are we to the real value? Precisionhow reproducible are the results? Were your measurements in the activity accurate, precise or both. Why was it important to use the same measuring tools for each trial? How could you have gotten better results? Accurate or Precise?? Let’s look at some data! Accurate? Precise? Shadows’ weight (experimental) 62.7 lbs 62.0 lbs 62.5 lbs Her weight according to the vet (accepted) 67.4 lbs Miles to school (experimental) 3.9 miles 3.8 miles 3.9 miles Mapquest (accepted) 3.98 In Our Dream Life— All our measurements would be BOTH Accurate and Precise! Scientists strive for correct measurements that are reproducible. With No Error! Experimental Measurements are seldom perfect We often compare experimental values to known, widely accepted values and calculate the error. You learned about this during the measurement activity!! Error Experimental value is measured in the lab Accepted value is based on reliable references Error = lAccepted - Experimentall What formula did you use to calculate percent error? Percent error is an indication of how well the lab went… if you have a low percent error, it means that there were few lab errors. Calculate the percent error! Shadows’ weight (experimental) 62.7 lbs 62.0 lbs 62.5 lbs Her weight according to the vet (accepted) 67.4 lbs Miles to school (experimental) 3.9 miles 3.8 miles 3.9 miles Mapquest (accepted) 3.98 Percent Error What are some lab mistakes you could have made that would effect your accuracy and precision? Gen Chem- Homework… percent error WS. Warm Up: How did you do on %Error WS? Front Side 1. 4.62% 2. 24.3% 3. 12% 4. 0.9% 5. 0.3% Back Side 1. 5.6% 2. 2.6% 3. 1.8% 4. 10.% 5. 0.519 mL 6. 5.6% Warm Up- Friday 1. What is the density of a substance with a length of 3.5 cm a width of 2.1cm and a height of 4.5 cm and a mass of 261 g. What is the substance? Known Densities Zinc Iron Copper Gold 7.14 g/cm3 7.89 g/cm3 8.92 g/cm3 19.39 g/cm3 2. The density of aluminum is 2.7g/cm3. What mass of aluminum takes up 1.2 cm3 of space? Warm Up Answers 1. Iron 2. 3.24 g Work on the density WS… we will fix your answers for SF on Monday Measurement Activity- 3 and 4 Same groups as previous class. Change jobs! 1. Leader- Reads all the instructions (out loud) and keeps everyone on task 2. Scientist 1- Reviews instructions and does the task. 3. Recorder- Keeps careful record of all observations to share with other group members. You have 25 minutes to complete these two tasks! Warm Up- Monday/Tuesday How would you determine the volume of an irregular shaped object? General Chem Collect the “Why I need to study Chemistry” assignment. Debrief Activities 1. So, what is a significant figure? 2. Why is it important that we use them? 3. How hard was it to “estimate” the last digit on the ruler? How about the beaker? Sig Figs Significant figures include all the known digits plus a last digit that is estimated. Significant Figures Depends on the instrument being usedThe better the instrument (read more expensive) the more significant figures. Which was a better measuring tool? The beaker, the cylinder or the volumetric flask? Rules for Zeros: 1. All non zero digits 2. Zero’s in between digits 3. Zero’s in front are not sig 4. Zero’s in back are not sig unless it is a known measured value (there is a decimal point). 5. Unlimited sig figs When something is counted Exactly defined quantities (constants) Every calculation in this class, you need to look at the Sig Figs. When you multiply or divide: count the SF and round your answer to the lowest number of SF. The rule is a little different when you add and subtract… Do the addition or subtraction… Look at the numbers and round to the measurement with the least number of decimal places. Rounding If the number after the last sig fig is 5 or greater– round up. If the number after the last sig fig is less than 5– keep it the same! Look at the Sig Fig WS. Do a few of these… yes, you can use your calculator! Get the answer… and round your answer to the correct number of SF. How did you do on %Error WS? Front Side 1. 4.62% 2. 24.3% 3. 12% 4. 0.9% 5. 0.3% Back Side 1. 5.6% 2. 2.6% 3. 1.8% 4. 10.% 5. 0.519 mL 6. 5.6% What about the SF??? How did you do on the Density WS? Check your significant How do I do conversions Using Dimensional Analysis