Lewis S. Mills High School AP Chemistry Information and Summer Assignment 2014-2015 Mrs. Rosenfield rosenfieldk@region10ct.org AP Chemistry is a college-level course with a lot of material that must be learned before the AP examination in May. This requires spending most of your time learning new material or going into topics covered in first-year chemistry in more depth. There will not be time to re-teach a lot of basic concepts. Because this is a second-year chemistry course, all students will be expected to review and understand certain fundamentals from first-year chemistry that are needed as a foundation for more advanced topics. Some of this is pure memorization and some requires an understanding of basic chemical principles. For example you must memorize the symbols of common elements, the formulas and charges of common monatomic and polyatomic ions, and be able to determine correct formulas and names of compounds. You are expected to master the material in the first three chapters of the textbook (Chemistry the Central Science, 10th edition by Brown, LeMay, and Bursten) before the first day of class. Most, if not all, of this was covered in your first chemistry course. My wiki page: https://studentweb.region10ct.org/groups/krosenfield/ Explore and Make an Account at the College Board AP Chemistry site: https://apstudent.collegeboard.org/home Download the College Board Chemistry Course Description at https://apstudent.collegeboard.org/apcourse/ap-chemistry This will give you a good idea of what to expect in the course. The timing of the course is similar to a first year college chemistry course. You should recognize that this will be a challenging and, I hope, exciting and enjoyable experience, but one that will require a lot of work. You need to be committed to spending the amount of time to succeed in this course before beginning the year. The following assignment is to be handed in on the first day of class. It will be graded, and there will be a test on the material the first week of school. You may either handwrite or type the answers to the problems but make sure to show calculations to receive credit for completing the assignment. Feel free to email me at rosenfieldk@region10ct.org if you have any questions about the assignment. There will be a quiz on the first day of class on the material that you are supposed to memorize in Table 1.5 Metric Prefixes, Table 2.3 Names of Some Groups in the Periodic Table, Figure 2.19 Diatomic molecules, Table 2.4 Common Cations, Table 2.5 Common Anions and Table 2.6 Prefixes, and the list of ions attached. Read Chapter 1 o Key terms and concepts to understand: classification of matter (mixtures, substances, elements, compounds) physical properties vs. chemical properties use of units in conversions and dimensional analysis precision and accuracy significant figures in measurements and calculations o Do problems pgs. 31-33 # 3, 4, 7, 18, 22, 24, 28, 30, 32, 42, 56, 61. o MEMORIZE Table 1.5 Metric Prefixes (I don’t want anyone asking me how many milliliters are in a liter, or how many grams are in a kilogram.) Read Chapter 2 o Key terms and concepts to understand atomic structure and properties of electrons, protons and neutrons atomic number, mass number, isotopes, weighted average atomic mass groups, periods, metals, nonmetals, metalloids molecular formula, empirical formula formation of ions, charges on common ions ionic vs. molecular compounds names and formulas of ionic and molecular compounds o Do problems pgs. 70-75 # 1, 4, 18, 20, 24, 30, 36, 42, 48, 52, 54, 56, 73 AND complete the attached worksheet. o MEMORIZE Table 2.3 Names of Some Groups in the Periodic Table, Figure 2.19 Diatomic molecules, Table 2.4 Common Cations, Table 2.5 Common Anions and Table 2.6 Prefixes, and the list of the common ions found on the AP exam that is attached to this handout. These are essential prerequisites to being able to write correct names and formulas of chemical compounds. You will be quizzed on these the FIRST day of class. Read Chapter 3 o Key terms and concepts to understand balanced chemical equations Avogadro’s number and the mole conversions between mass, moles and number of particles empirical and molecular formulas percent composition limiting reactant calculations relating amounts of reactants and products theoretical, actual and percent yield o Do problems pgs. 110-116 # 5, 6, 12, 14, 16, 26, 34, 38, 42, 44, 48, 50, 54, 58, 60, 67, 68, 73, 79, 89. AP Chemistry – Writing Names and Formulas NAME: _______________________________________________ Chemical Formulas: Write the formulas for the following substances 1. Barium sulfate ________________ 1. CuSO4 2. Ammonium chloride ________________ 3. Sodium phosphate Chemical Names: Write the names of the following substances. The starred ones are acids. __________________ 2. PCl3 __________________ ________________ 3. Li3N __________________ 4. Silicon tetrachloride ________________ 4. BaSO3 __________________ 5. Magnesium fluoride ________________ 5. NaF __________________ 6. Sodium oxide __________________6. KClO4 __________________ 7. Sodium peroxide __________________7. NaH __________________ 8. Copper(I) iodate __________________8. (NH4)2Cr2O7 ________________ 9. Mercury(I) sulfide __________________9. HNO2* 10. Potassium carbonate __________________10. Sr3P2 __________________ __________________ 11. Hydrobromic acid __________________11. Mg(OH)2 __________________ 12. Sulfuric acid __________________12. Al2S3 __________________ 13. Lead(II) acetate __________________13. AgBr __________________ 14. Sodium permanganate __________________14. P2O5 __________________ 15. Lithium oxalate __________________15. HC2H3O2* __________________ 16. Potassium cyanide __________________16. Ca(BrO2)2 __________________ 17. Iron(III) hydroxide __________________17. MnO2 __________________ 18. Silicon dioxide __________________18. Li2O2 __________________ 19. Nitrogen trifluoride __________________19. FeI3 __________________ Common ions found on the AP exam Mastering this list of ions names, formulae, and charges, is essential to success in AP Chemistry. You are expected to know all of these ions on the first day of class, when I will give you a quiz on them. You will always be allowed a periodic table, which makes identifying the ions on the left “automatic.” I will have Tips for Learning the Ions on my wiki page for you and I will be placing a link to study cards using Quizlet (unfortunately, I cannot sub- and superscript with Quizlet so you will have to allow for that when learning them). From the Table Cations H+ Li+ Na+ K+ Rb+ Cs+ Be2+ Mg2+ Ca2+ Ba2+ Sr2+ Al3+ Name hydrogen lithium Sodium Potassium Rubidium Cesium Beryllium Magnesium Calcium Barium Strontium Aluminum Anions HFClBrI- Name Hydride Fluoride Chloride Bromide Iodide O2S2Se2N3P3As3- Oxide Sulfide Selenide nitride Phosphide Arsenide Transition/Heavy Metal Cation Fe3+ Fe2+ Cu2+ Cu+ Co3+ Co2+ Sn4+ Sn2+ Pb4+ Pb2+ Hg2+ Ni2+ Name Iron(III) Iron(II) Copper(II) Copper(I) Cobalt(III) Cobalt(II) Tin(IV) Tin(II) Lead(IV) Lead(II) Mercury(II) Nickel(II) Ions to Memorize Cations Name + Ag Silver Zn2+ Zinc Hg22+ Mercury(I) + NH4 Ammonium Anions NO2NO3SO32SO42HSO4OHCNPO43HPO42H2PO4NCSCO32HCO32ClOClO2ClO3ClO4C2H3O2Purple color MnO4Orange color Cr2O72Yellow color CrO42Yellow color Green color Blue color Green color Green color O22C2O42NH2BO33S2O32- Name Nitrite Nitrate Sulfite Sulfate Hydrogen sulfate (bisulfate) Hydroxide Cyanide Phosphate Hydrogen phosphate Dihydrogen phosphate Thiocyanate Carbonate Hydrogen carbonate (bicarbonate) hypochlorite Chlorite Chlorate Perchlorate Acetate Permanganate Dichromate Chromate Peroxide Oxalate Amide Borate Thiosulfate