Chapter 9 Notes I Stoichiometry Stoichiometry Calculations of quantities in chemical reactions This means using balanced equations to calculate quantities of chemicals used in a chemical reaction A chemical equation is like a recipe; it shows you how much of each “ingredient” is used and how much product you will have in the end. N2 + 3H2 a 2NH3 How many molecules of N2 are there? How many molecules of H2 are there? How many molecules of NH3 are there? So one molecule of N2 will react with 3 molecules of H2 to form 2 molecules of NH3. You could also say that one mole of N2 will react with 3 moles of H2 to form 2 moles of NH3. The heart of stoichiometry is using a balanced chemical equation as a conversion factor for dimensional analysis. Zn + HCl a ZnCl2 + H2 For the above reaction, how many moles of zinc chloride can be produced with 0.27 moles of zinc? Zn +2 HCl a ZnCl2 + H2 For the above reaction, how many moles of zinc will react with 1.39 moles of hydrochloric acid? Why are mole/mole problems impractical in a laboratory setting? 4Fe + 3O2 a 2Fe2O3 How many grams of iron (III) oxide can be produced with 17.2g Fe? 4Fe + 3O2 a 2Fe2O3 How many grams of iron will react with 5.25 liters of O2 (@STP)? 4Fe + 3O2 a 2Fe2O3 How many molecules of O2 are needed to produce 3.92g Fe2O3? Density Remember, a conversion from liters to moles is only valid for gases at STP. Converting from/to liters (or mL) for liquids or solids involve using density as a conversion factor. If you have 10.0mL of isopropyl alcohol (C3H7OH) and burn it, how many liters CO2 gas are produced @STP? The reaction is combustion. D = 0.798g/mL 10.0mL (C3H7OH) D = 0.798g/Ml how many liters CO2 Find Mass using D=M/V Write the reaction 2C3H7OH + 9O2 6CO2 + 8H20 7.98g ?L