1 Phases & Behavior of Matter 2 Phases and Behavior of Matter Goals 1. Compare and contrast the atomic/molecular motion of solids, liquids, gases & plasmas. 2. Explain the flow of energy in phase changes through the use of a phase diagram. 3. Relate temperature, pressure, and volume of gases to the behavior of gases. Solid Liquid Gas 3 Review • Everything in the universe is either matter or energy. • Physical Science is the study of matter and energy. • Matter is anything that has mass and takes up space. 4 Clip Kinetic Theory of Matter 1) All matter is composed of small particles (atoms). 2) These particles are in constant motion. 3) These particles are colliding with each other and the walls of their container. 5 Kinetic Energy • Kinetic Energy is the energy of motion. • Temperature is the measurement of the KE in an object. • So, the more KE the higher the temp. • As the particles in an object gain KE, the temperature goes up. 6 Solids • Particles are closely packed together. • Most are geometric. • There are bonds between atoms/mol. • Rigid shapes. • Definite shape. • Definite volume. Clip Amorphous Solids 7 Clip Liquids • Particles in a liquid have more KE than particles in a solid. • Liquid particles have enough KE to overcome the forces that hold them together. • The particles can now move past one another. (flow) • Definite volume • No Definite shape. Viscosity 8 Clip Gases • Gas particles have more KE than liquid particles. • They have enough energy to break all bonds and escape the liquid state. • No definite Shape • No definite Volume. Gases fill their container. 9 Gases are compressible 10.1 o Most common state of matter in the universe o Extremely high temperatures. o Contains positively and negatively charged particles Plasma Clip Artificially produced plasmas Terrestrial plasmas •Those found in plasma displays, including TVs •Lightning •Inside fluorescent lamps (low energy lighting), neon signs •The ionosphere •The electric arc in an arc lamp, an arc welder or plasma torch •Plasma ball (sometimes called a plasma sphere or plasma globe) •The polar aurorae 10.2 o Force produced by high energy collisions strips electrons from atoms. o Sun, lighting bolts, neon and fluorescent tubes, auroras. ReviewClip 10.3 • PHET Phases of matter simulation • STOP HERE>>>>>> • REVIEW 11 Changing State 12 13 Boiling vs. Evaporation Boiling is The vaporization of a liquid at its boiling point. Evaporation is The vaporization of a liquid below its boiling point. This occurs at the surface of the liquid. 14 Sublimation • Some substances go from the solid state directly to the gaseous state. This happens when a substance was below it freezing point and is suddenly moved to a location where it is above its boiling point • EX: CO2 15 •It takes energy to cause phase changes( soild-liq-gas) •Removal of energy (gas-liq-solid) Phase changes do not change the substance 16 • The amount of energy required for a substance to go from a solid to a liquid is called the HEAT OF FUSION. • (EX) it takes 334,000 Joules of energy to melt 1 kg of ice. No temperature change. 0°C 0°C 17 • The amount of energy required to change a liquid to a gas is called the …Heat of Vaporization • EX: It takes 2,260,000 Joules of energy to vaporize 1 kg of water. 100 °C 100 °C 18.1 Clip Energy • The triple point of a substance is the temp. and pressure at which the three phases of that substance coexist • Phase depends not only on temp. 18.2 19 When heat is added to most materials they expand Thermal Expansion • When objects are heated, they expand. • When they are cooled, they contract. • Video Clip Thermal Expansion Typical expansion joints on a steel span bridge. 20 Thermometers • Work because of thermal expansion. • Because mercury expands and contracts uniformly, it was used in thermometers. 21 19 22 23 Force (N) Pressure (Pa)= Area (M2) 24 Gases exert pressure on their container 24• Pressure: The amt of force exerted per unit of area. • Gases exert pressure by colliding with “things.” 1.Other particles of gas 2.Sides of the container 3.Objects within the area of the gas, like you. 26 • Formula For Figuring Out Pressure: • P = F/A • The Pascal (Pa) is the SI unit of pressure Clip 27 Boyle’s and Charles’ law • Both deal with gases. • Boyle’s Law – As the volume decreases, the pressure increases. • Charles’ Law – As the temperature decrease, the volume of a gas decreases. Boyle’s Law • Relationship between volume and pressure. You tube Clip P1V1 = P2V2 28 Boyle’s Law P1V 1 = P 2V 2 If you decrease the volume, the pressure will increase ( no Δt) 29 30 P1 V1 = P2 V2 Boyle’s Law A volume of helium occupies 11.0 L at 98.0 kPa. What is the new volume if the pressure drops to 86.2 kPa? P1 V1 = P2 V2 (98.O kPa) (11.0 L) = (86.2 kPa) (V2) (98.O kPa) (11.0 L) = (V2) (86.2 kPa) (V2)=12.5 L P 1 V1 = P 2 V2 • A sample of helium gas at 25°C is compressed from 200 cm3 to 0.240 cm3. Its pressure is now 3.00 cm Hg. What was the original pressure of the helium? – P1 = 3.60 x 10-3 cm Hg Charles’ Law • Relationship between volume and temperature. In theory there is a temperature in which gases ceases to have volume. This temp. is referred to as absolute zero. Absolute Temp. Scale T (K) = °C + 273.15 K 31 Charles’ Law If you increase the temperature, the volume will increase 32 Charles’ Law • V1/T1 = V2/T2 33 Charles’ Law 34.1 Charles’ Law What would be the resulting volume of a 2.0 L balloon at 25.0˚C that was placed in a container of ice water at 3.0˚C? V 1 = V2 T1 T2 2.0 L 25.0˚C = . V2 3.0˚C V2 = 0.24 L 0.40 L of a gas is collected at 50.0°C. What will be its volume upon cooling to 25.0°C? 0.2 L 34.2 • PHET Phases of matter simulation 34.3 EOCT Practice Question: A B C D 34.4 EOCT Practice Question: A B C D 35 36 Greek Mathematician 37 • Born: 287 BC in Syracuse, Sicily Died: 212 BC in Syracuse, Sicily • “There are things which seem incredible to most men who have not studied mathematics.” • “Eureka, Eureka. I have found [it].” • Despite his mathematical prowess, Archimedes is perhaps best remembered for an incident involving the crown of King Hiero. • As the story goes, the king of Syracuse had given a craftsman a certain amount of gold to be made into an exquisite crown. When the project was completed, a rumor surfaced that the craftsman had substituted a quantity of silver for an equivalent amount of gold, thereby devaluing the crown and defrauding the king. Archimedes was tasked with determining if the crown was pure gold or not. The Roman architect Vitruvious relates the story: • While Archimedes was considering the matter, he happened to go to the baths. When he went down into the bathing pool he observed that the amount of water which flowed outside the pool was equal to the amount of his body that was immersed. Since this fact indicated the method of explaining the case, he did not linger, but moved with delight, he leapt out of the pool, and going home naked, cried aloud that he had found exactly what he was seeking. For as he ran he shouted in Greek: Eureka! Eureka! (eureka translated is "I have found it"). • Although there is speculation as to the authenticity of this story, it remains famous. Probably no other tale in all of science combines the elements of brilliance and bareness quite so effectively. Whether the story is true or not, there is no doubt to the truth of Archimedes understanding of buoyancy. 38 Here is what Archimedes had found. Since an object immersed in a fluid displaces the same volume of fluid as the volume of the object, it was possible to determine the precise volume of the crown by immersing it in water. After determining the volume of water, a piece of pure gold could easily be made to match the volume of the water, and thus the volume of the crown. In theory, if the volume of the crown and the volume of the gold block are the same, they should also have the same mass. The only reason they would not have the same mass is if one of them was not pure gold. When the two objects were placed in a balance they did not have equal mass. Faced with this evidence the craftsman confessed to his crime. 39 • Why is it easier to lift something heavy when it's underwater? • Buoyancy! 40 •Buoyancy is an upward force exerted by a fluid on an object that is submerged in that fluid. Eureka: Buoyancy Archimedes’ Principle • Deals with fluids and buoyancy. • What is a fluid? • Any substance that can flow. • Buoyancy is an upward force exerted by a fluid on on object that is submerged in that fluid. 41 42 Archimedes’ Principle • Archimedes Principle states that the buoyant force on a submerged object is equal to the weight of the fluid that is displaced by the object. •What does that mean? Describes how ships float. The more water you displace, the more upward force. 43 • Pressure: The amt of force exerted per unit of area. 44 Blaise Pascal • Mathematician, physicist, and theologian. • Pascal's work in the fields of the study of hydrodynamics and hydrostatics centered on the principles of hydraulic fluids. 45 Pascal’s Principle • Pressure applied to a fluid is transmitted unchanged throughout the fluid. • Toothpaste • Hydraulic Jacks 46 P1 = P 2 F1A2 =F2A1 P1 = P2 Pascal’s Principle • How much force will the piston apply to lift the monkey? 47 48 49 Daniel Bernoulli • Dutch-born mathematician. • His most important work considered the basic properties of fluid flow, pressure, density and velocity, and gave the Bernoulli principle. 50 • As the velocity of a fluid increases, the pressure exerted by that fluid decreases. • A plane's wing is curved so that the air going the greater distance over the top of the wing moves faster, • Reducing pressure from above,allowing the lift from below to raise the plane up 51 Th e En d Amorphous Solids “without form” • Lack highly ordered arrangement • Melt over a temperature range • Glass & Plastic • Some scientist classify them as “thick liquids” •Crystalline solids are arranged in fixed geometric patterns or lattices. •Amorphous solids are solids with random unoriented molecules Go Back to solids Viscosity • Resistance to flow