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Ch. 12 Liquids and Solids Notes

Liquids

Properties of Liquids and the KMT

1.

Fluid – flows and takes shape of container

2.

Constant motion

3.

Relatively high Density

4.

Incompressible

5.

Diffusible

6.

Surface Tension: force that pulls liquid together, decreasing surface area to the smallest size

7.

Capillary Action: attraction of liquid surface to surface of solid

8.

L –>G (vaporization) Evaporation (molecules escape surface of nonboiling liquid) and Boiling

9.

Volatile v.s. Nonvolatile

Formation of Solids

1.

L  S freezing or solidification

2.

S  L melting same temperature

SOLIDS

Properties of Solids and the KMT

1.

crystalline solid - orderly geometric repeating pattern arrangement a.

Ionic Crystals b.

Covalent Network crystals i.

Quartz, diamond ii.

asbestos c.

Metallic Crystals - Metals d.

Covalent molecular crystals i.

Weak LDF ii.

Dipole – Dipole iii.

H- bonding

2.

amorphous solid: arranged randomly a.

Without shape b.

Plastics and glass

3.

Definite Shape and Volume

4.

Definite Melting Point – super cooled liquids (usually liquid at temperature)

5.

High Density and Incompressibility

Assign 1 st POGIL on Phase Changes and Read and outline Ch. 12 pp.363-371

2 nd do Hot Pot , a review of Calorimetry

Read and outline Ch. 12 pp. 372-380,

Changes of State:

Equilibrium

is a dynamic condition in which 2 opposing changes occur at equal rates in a closed system Equilibrium Equation

L + heat energy  Vapor or

V  L + ______________

Skip Le Chatelier’s Principle for now

Table 12-2

S  L

L  G

S

G

G

L

L  S

G  S

Phase

any part of system that has uniform composition and properties

Equilibrium Vapor Pressure over a Liquid

Heating and Cooling Curves

Boiling

Condensation

Energy and Boiling  Molar Heat of Vaporization

Freezing and Melting  Molar Heat of Fusion

Sublimation and Deposition

Heating and Cooling Curve

Review Phase Change POGIL

Show/discuss Heating Curve:

Heating and Cooling Curves use

Different substances have different values for: Specific heat, Cp, molar heat of fusion or molar heat of vaporization

Water Cp = 4.84 J/g C

Ice:

Hf = 6.009 kJ/mol  mole to grams

Steam:

Hv = 40.79 kJ/mol  mole to grams

Vapor Pressure Curves

Equilibrium Vapor Pressure exists over a Liquid

Initial conditions in a closed container:

Final conditions in a closed container: liquid with vacuum above and  after time  liquid with vapor above

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