Radioactivity and radioisotopes • Half-life • Exponential law of decay Half-life The half-life of a radioactive element means: a) The time taken for half the radioactive atoms in the element to disintegrate Radioactive atoms HALF-TIME Radioactive atoms Decayed atoms b) The time taken by the radiation from the element to drop to half its original level HALF-TIME What does decay rate depend on? In other words, there is a 50% chance that any radioactive atom within the sample will decay during a half-life time T½. Consider the b emitter Fe-59. Its half-life is 46 days. Plot a graph of the fraction of undecayed atoms vs time (days). Click here for radioactive decay simulation Half-life of Fe-59 Fraction of undecayed atoms 1 1/4 1 1 3/4 1/2 1/2 1/4 1/4 1/8 0 0 46 92 Time (days) 138 0 184 What does decay rate depend on? Can you now answer by considering the graph you drew? Explain your answer. The rate of radioactive decay of Fe-59 atoms depends on the number of atoms itself. In fact, our graph is not a straight line, which means that the number of atoms decaying changes with time, i.e. with the number of radioactive nuclides left. The number of radioactive nuclides left after each half-life drops to ½, not of the original amount, but of the amount left. This means that not all Fe-59 has decayed after 2 x 46 days, but only ¼ of the original amount is left. Exponential law of decay Now, Interpolate plot the thegraph logarithm of theoflogarithm the fraction to base remaining 10 of the afterfraction 120 days. of Fe-59 remaining against time. Logarithm of fraction remaining - time Log of fraction remaining 0 46 92 0 -0.301 -0.602 0.785 -0.903 -1.204 Time (days) 138 184 Exponential law of decay Consider the table of data from the example on the previous slides. Time (day) Fraction remaining (F) log(F) 0 1 0 46 1/2 -0.301 92 1/4 -0.602 138 1/8 -0.903 184 1/16 -1.204 Exponential law of decay Can you notice any pattern in the log(F)? Explain your answer. Each reading of F is divided by 2 (1, ½, ¼, …), therefore, the value of log(F) must have log2 subtracted from it to get the next reading. In fact; log(a/b) = log(a) – log(b) log(1/2) = log(1) – log(2) = 0 – 0.301 = -0.301 The same applies to the other fractions. Exponential law of decay Using the table and similar triangles find the fraction remaining after 150 days. 138days 150days 0.903 x x = -0.982 x = log(F150) F150 = antilog(-0.982) = 10-0.982 = 0.10 Exponential law of decay From the previous discussion, we can conclude that the rate of radioactive decay is proportional to the number of radioactive atoms: dN N dt Where N is the number of radioactive atoms still present at time t. Exponential law of decay The previous proportionality gives the following equation: dN lN dt The constant l the decay constant, and it is measured in s-1. A solution to the above equation is: N N 0e lt N0 N x 2 Exponential law of decay In the previous formulae, N0 is the number of radioactive atoms at time t = 0, and x is the number of half-lives elapsed, which could also be not integer.