Hydrocarbons with Functional Groups Alcohols Alcohols At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Functional Groups A group of covalently bonded elements that when bonded to a carbon chain give it a unique quality. Compounds with similar functional groups will have similar qualities and properties. Alcohols •They are organic compounds that are primarily used as disinfectants. •Alcohols have the functional group of –OH. •They have the general formula of R-OH. Euphemisms in Science We all know that some politicians and government spokesmen use certain euphemistic phrases to give an aura of respectability to descriptions of events or actions which would be offensive when expressed in plain English. The following is a list of Euphemisms in Science and their translations into plain English. “It is believed that...” I think! “It is generally believed that...” A couple of other guys think so too! How to Name Alcohols Alcohols are named by adding the suffix -ol. If there is more than one hydroxyl group (-OH), the suffix is expanded to include a prefix that indicates the number of hydroxyl groups present (-diol, -triol, etc.). The position of the hydroxyl group on the parent chain is indicated by placing the number corresponding to the location on the parent chain directly in front of the base name. How to Name Alcohols The hydroxyl group takes precedence over alkyl groups and halogen substituents, as well as double bonds, in the numbering of the parent chain. If there is a choice in numbering after these rules are followed, the parent chain is numbered to give the substituents the lowest number. Examples of Naming Alcohols A Primary Alcohol – (-OH attached to an end carbon that is attached to 1 other carbon) Ethanol – drinking alcohol Examples of Naming Alcohols A Secondary Alcohol – (-OH attached to a middle carbon that has 2 other carbon bonds) 2-propanol Examples of Naming Alcohols A Tertiary Alcohol – (-OH attached to a middle carbon that has 3 other carbon bonds) 1,1-dimethylethanol (no) 2-methyl-2-propanol or 2-methylpropane-1-ol More Examples of Naming Alcohols 1,2,3-propantriol Propane-1,2,3-triol benzenol phenol Familiar Saying Where there are visible vapors from ignited carbonaceous materials, there is conflagration. Where there is smoke, there is fire! Alcohols Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Exit Quiz: Alcohols Hydrocarbons with Functional Groups Ethers Ethers At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group 15 Helpful Hints On The Lab Report from Mr. T’s Vast Lab Experience!!! Hint #6. If you can't get the answer in the usual manner, start at the answer and derive the question. Ethers •They are organic compounds that are primarily used as anesthetics. •Ethers have the functional group of –O– in the middle of the carbon chain. •They have the general formula of R-O-R’. Examples of Naming Ethers 1. Name the chains as alkyl groups 2. Put them in alphabetical order 3. End with ether. Examples of Naming Ethers 1. Name the chains as an alkyl groups 2. Put them in alphabetical order 3. (ethyl, can’t be propyl, why?) 4. (at 1 and 1 there are methyl groups) 5. End with ether. 6. 1,1-dimethyl ethylmethyl ether Ethers Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Murphy's Laws of Science and Technology To err is human, but to really foul things up requires a computer. Exit Quiz: Ethers Hydrocarbons with Functional Groups Organic Acids Functional Groups A group of covalently bonded elements that when bonded to a carbon chain give it a unique quality. Compounds with similar functional groups will have similar qualities and properties. Organic Acids At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Organic Acids •They are an organic compound that is primarily used as protection for fruits and vegetables. •Organic acids have the functional group of –COOH on the end of the carbon chain. This is called the carboxyl group. •They have the general formula of R-COOH. Examples of Naming Organic Acids 1. Name the R chain and include the C of the carboxyl group 2. End with –oic acid Examples of Naming Organic Acids 1. Name the R chain and include the C of the carboxyl group (methane) 2. End with –oic acid 3. methanoic acid Chemical Compound Quiz Acetylsalicylic acid helps cure aches and pains. What is the common name? Aspirin Organic Acids Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Exit Quiz: Carboxylic Acids Ethanoic acid O || HO-C-C=O | OH What’s the formula? Is it like HC2H3O2? Acetic acid!! ethane-1,2-dioic acid or ethandioic acid Little Known Phobias! Edifice Complex Fear of tall buildings Exit Quiz: Carboxylic Acids 2-methylpropanoic acid Hydrocarbons with Functional Groups Ketones Familiar Saying Similar sire, similar scion. Like father, like son!! Ketones At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Ketones •These are organic compounds that are primarily used as solvents. •Ketones have the functional group of =O somewhere in the middle of the carbon chain. Examples of Naming Ketones 1. Name the hydrocarbon chain. 2. End with –one. 3. Give the number of the carbon to which the ketone group is attached. 4. 2-propanone 5. Common name – acetone. Ketones Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group The Scientific Method begins with Questions about the World Around You. Ever Wonder Why?... teflon sticks to the pan in the first place? Examples of Naming Ketones 1. Name the hydrocarbon chain. 2. End with –one. 3. Give the number of the carbon to which the ketone group is attached. 4. 4-methyl-2-pentanone Hydrocarbons with Functional Groups Aldehydes Aldehydes At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Aldehydes •These are organic compounds that are primarily used as preservatives. •Aldehydes have the functional group of =O on the end of the carbon chain. Examples of Naming Aldehydes 1. Name the hydrocarbon chain. 2. End with –al. 3. methanal 4. Common name – formaldehyde. Examples of Naming Aldehydes 1. Name the hydrocarbon chain. 2. End with –al. 3. benzenal (benzaldehyde) Familiar Saying You cannot estimate the value of the contents of a bound, printed narrative or record from its exterior vesture. You can’t tell a book by its cover! Aldehydes Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Exit Quiz of Drawing Aldehydes: 4-ethylhexanal CH3-CH2-CH-CH2-CH2-CH=O | CH3-CH2 Exit Quiz of Naming Aldehydes: C-C-C-C-C-C=O | C-C-C 2-propylhexanal Happy Birthday Dirge Happy Birthday, Happy Birthday, Gloom and doom and dark despair People dying everywhere. Happy Birthday, Happy Birthday! Hydrocarbons with Functional Groups Esters Esters At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group 7th Grade Science Answers "Artifical insemination is when the farmer does it to the cow instead of the bull." Esters •These are organic compounds that are primarily used as flavorings. •Esters have the functional group of OC=O in the middle of the carbon chain. Examples of Naming Esters 1. The carbon chain with the double bonded O is named last and gets the –oate ending. 2. The other chain is named as a alkyl group. 3. methylethanoate. Examples of Naming Esters 1. The carbon chain with the double bonded O is named last and gets the –oate ending. 2. propanoate 3. The other chain is named as a alkyl group. 4. phenyl 5. phenylpropanoate Esters Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Exit Quiz for Naming Esters: CH3-CH2-CH-CH2-CH2-C-O-CH2-CH2-CH3 | || CH3 O propyl-4-methylhexanoate A.P. TEST IN BIOLOGY Create life. Estimate the differences in subsequent human culture if this form of life had been developed 500 million years ago, with special attention to the probable effect on the English Parliamentary system. Prove your hypothesis. Exit Quiz for Drawing Esters: methyl-4-ethylhexanoate CH3-CH2-CH-CH2-CH2-C-O-CH3 | || CH3-CH2 O Hydrocarbons with Functional Groups Amines Amines At the conclusion of our time together, you should be able to: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Amines •These are organic compounds that are primarily used as part of amino acids for proteins and fertilizer. •Amines have the functional group of -N on the end of the carbon chain as a primary amine •Secondary amines have 2 carbon chains attached to the –N- and ternary amines have 3. •Name each R group as an alkyl group in alphabetical order Examples of Naming Amines butylethylamine Amines Let’s see if you can: Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group Draw this organic compound with this functional group Examples of Naming Amines phenylamine aniline/ aminobenzene ethylmethylphenylamine Exit Quiz for Naming Amines: CH3-CH2-CH-CH2-CH2-NH-CH2-CH2-CH3 | CH3 3-methylpentylpropylamine Examples of Drawing Amines: 2-ethylbutylamine CH3-CH2-CH-CH2-NH2 | CH3-CH2 Familiar Saying Male cadavers are incapable of yielding any testimony. Dead men tell no tales!!