Graduate Lecture Series 29 June – 3 July, 2009 Quantum Physics Underlying Modern Technology Prof Ngee-Pong Chang Lecture 1 Quantum Physics Overview NanoScience A SCANNING microscope image of platinum-lace nanoballs. Liposomes aggregate, providing a foamlike template for a platinum sheet to grow. 5 x 5 mm image 50 nm Z scale Nano-scale Tic-Tac-Toe scratched into polycarbonate Line widths are ~ 40 nm Quantum Dots 10-6 m Max Planck 1858 - 1947 A plaque at Humboldt University, Berlin, commemorating Max Planck as "discoverer of the elementary quantum of action h," who "taught in this building" from 1889 to 1928 Old-fashioned Fireplace Progress of Technology : Log in the Fireplace Replacing the real & messy with the clean & convenient Superlog Blackbody Radiation λmax dependence on T Wien’s Law 1893 1864 - 1928 Rayleigh-Jeans Law 1900 1842 - 1919 1877 - 1046 Birth of Quantum Physics M. Planck, Annalen der Physik, vol 4, 553 (1901) Blackbody Radiation What is quantized ? Ideal Blackbody Standing Waves in a Cavity Polarization vector 2 Polarization states Standing Wave condition Standing Wave Condition or octant Average Energy Boltzmann Probability Distribution Equipartition Theorem Ultraviolet Catastrophe ! Rayleigh-Jeans Law 1900 1842 - 1919 1877 - 1046 Classical Planck Quantization Quantum Planck Blackbody Radiation Formula Birth of Quantum Physics M. Planck, Annalen der Physik, vol 4, 553 (1901) Blackbody Radiation Relation to Wien’s Constant Peak Intensity condition Wien’s Constant Our Universe as a Blackbody Far Infra-Red Absolute Spectrophotometer 1997 Cosmic Background Radiation FIRAS DATA 2.7280 ± 0.0001 K BLACKBODY What is quantized ? Albert Einstein 1879 - 1955 Einstein’s Photon Hypothesis (1905) Energy Momentum Niels Bohr 1885 - 1962 Bohr Model of the Atom 1913 Angular Momentum Quantization Bohr Model of the Atom Angular Momentum Quantization Bohr radius Bohr Model of the Atom Compton wavelength of electron Fine Structure Constant Bohr Radius Hydrogen 1s level rst.gsfc.nasa.gov Einstein’s Photon Hypothesis Energy Momentum 1924 Prince Louis-Victor Pierre Raymond de Brőglie (1892 – 1987) W. Heisenberg 1901 - 1976 Uncertainty Principle A convenient back-of-theenvelope way to keep track of the energy levels of quantum wells, and quantum dots. E. Schrődinger 1887 - 1961 Schrődinger Equation Stationary State Time-Independent Schrődinger Equation Classical Equations of Motion Ehrenfest Theorem Average Expectation Values Paul Ehrenfest 1880 - 1933 Max Born 1882 - 1970 Double Slit Experiment Electron build up over time Ehrenfest with his students Dieke, Goudsmit, Tinbergen, Ehrenfest, Kronig, Fermi. George Uhlenbeck 1900 - 1988 S. Goudsmit 1902 - 1978 Note to Goudsmit by L.H. Thomas Mar 25, 1926 Wolfgang Pauli 1900 - 1958 Pauli & Bohr & a spinning top Dirac Equation Non-relativistic limit Spin-Orbit Coupling Origin of Spin-Orbit Coupling Electron moving in a static E field sees a magnetic field, B : Electron spin precesses around this B field according to the magnetic moment interaction Electron orbiting around nucleus In electron rest frame, nucleus orbiting around electron Enrico Fermi Paul Dirac 1901 - 1954 1902 - 1984 Fermi Sea Fermi-Dirac Distribution Einstein Planck Schrodinger 1927 Dirac Pauli Heisenberg Bohr Solvay Conf A. Piccard, E. Henriot, P. Ehrenfest, Ed. Herzen, Th. De Donder, E. Schrödinger, E. Verschaffelt, W. Pauli, W. Heisenberg, R.H. Fowler, L. Brillouin, P. Debye, M. Knudsen, W.L. Bragg, H.A. Kramers, P.A.M. Dirac, A.H. Compton, L. de Broglie, M. Born, N. Bohr, I. Langmuir, M. Planck, M. Curie, H.A. Lorentz, A. Einstein, P. Langevin, Ch. E. Guye, C.T.R. Wilson, O.W. Richardson Bose – Einstein Statistics 1924 1894 - 1974 1879 - 1955 Kammerlingh Onnes 1853-1926 On the Sudden Rate at Which the Resistance of Mercury Disappears Communications of the Leiden Laboratory, 1911 Meissner Effect 1933 Robert Ochsenfeld Walther Meissner 1882 - 1974 Quantization of Flux