Do Now: TOPIC: ENERGY All physical & chemical changes are accompanied by change in energy The chemistry of energy changes is known as Thermochemistry! Stability and Energy • If energy is high, stability is low • If energy is low, stability is high Energy: Ability to do Work The SI unit for an energy measurement is called the Joule (J) EXAMPLE: 1 Joule = amount of energy required to lift a golf ball 1 meter Other Energy Units: calorie, Calorie, BTU’s 1 calorie = 4.18 Joules 1 Calorie = 1000 calories = 1 kilocalorie NOTE: When your body breaks down food, these reactions give off heat – which is measured in calories (That’s why your food is labelled in calories) Law of Conservation of Energy • Energy is neither created nor destroyed in ordinary chemical or physical change, rather it can be converted from one form to another - potential to kinetic - radiant to electric - electric to heat - chemical to kinetic - chemical to electrical Energy before = Energy after Energy Non-mechanical – too small to see Mechanical – large enough to see Kinetic Potential Chemical (Not a complete list!) Heat Light Electrical Nuclear Kinetic Energy (KE) – energy of motion • KE = ½ x Mass x Velocity2 = ½ mV2 • KE depends on how heavy and how fast Kinetic Molecular Theory: the atoms and molecules making up substances are in constant motion Potential Energy (PE): energy of position; stored energy of matter EXAMPLES stapler Rubberband • When Potential energy is released from matter it becomes kinetic energy Energy in Chemistry = chemical energy heat energy Chemical Energy • energy stored in bonds • Bonds are stable • You need energy to break bonds • Energy is released when bonds are formed EXOTHERMIC If the overall energy in a chemical reaction is negative (meaning energy is released) = the rxn is exothermic energy (heat) is given off = exothermic EXO - energy leaves system (exits) Exothermic Rxn Temperature of environment Environment Temperature of system System Energy ENDOTHERMIC If the overall energy in a chemical reaction is positive (meaning energy is absorbed) = the rxn is endothermic energy (heat) is absorbed = endothermic Endo - Energy enters system (enter) ENDOTHERMIC Temperature of environment Environment System Energy Temperature of system Energy of Universe is conserved Universe EnvironmentEnvironment System Energy Energy can move between the system and the environment Calorimeter: an insulated devise used for measuring the amount of heat absorbed or released during a chemical or physical change “universe” is contained in Styrofoam cup “environment” is water**** “system” is whatever put in water Energy lost = Energy gained Difficult to monitor “system” Easy to monitor “environment” (water) Energy lost/gained by environment = Energy gained/lost by system Calorimetry 10 grams of NaOH is dissolved in 100 g of water & the temperature of the water increases from 22C to 30C • was dissolving process endothermic or exothermic • how do you know? Exothermic – temperature of environment ↑ Heat Energy Heat: energy that is in the process of flowing from warmer object to a cooler object Symbol for heat energy = Q or q The amount of heat required to raise the temp. of 1 gram of water 10C = a calorie The amount of heat transferred depends on 3 things Temperature change Mass of substance Specific Heat of substance Specific Heat • The amount of heat required to raise the temp of any given substance by 10C • Symbol = c • Specific heat = a physical constant • unique for each pure substance Found in Table B Calculating Heat Transferred Simple system: •pure substance in single phase •calculate heat gained or lost using: Q = mCT Q = amount of heat transferred m = mass of substance C = specific heat capacity of the substance. T = temperature change = Tfinal – Tinitial Calorimetry problem from before 10 grams of NaOH is dissolved in 100 g of water & the temperature of the water increases from 22C to 30C • We already said it’s exothermic – now we can actually calculate the amount of heat energy released Energy lost by NaOH (system) = Energy gained by water Environment Energy • What’s happening when NaOH dissolves? Add H2O NaOH close together, not interacting Na+ and OH- ions pulled apart & interacting with H2O Q = mCT Q = energy (joules) M = mass (grams) C = specific heat capacity (Table B) T = temperature change = Tf - Ti Q=? M = Well, temp change was for water, so want mass of water m = 100 g C = specific heat capacity (Table B) = 4.18 J/gK T = temperature of water increased from 22 C to 30 C 30 C -22 C = 8 C = T Q = mCT • Q = (100 g)(4.18 J/gC)(8C) • Q = 3344 Joules