December 4, 2013 In your assigned seat working on the Do Now when the bell rings. IF I CANNOT HEAR THE MUSIC YOU ARE TOO LOUD. Turn in HW #4 (quiz grade). Turn in any late HW, Projects, etc. Pick up a White board, sock, and marker. DO NOW: Complete the warm up you picked up (quarter sheet). This will be collected. The answers are … Element Atomic # Atomic Mass Mg 12 24 P 15 K 19 G Protons Neutrons Electrons 12 A B 12 C 12 D 31 E 15 16 F 15 39 19 H 20 I 19 Tutoring Thursday 12-5 afterschool 2:30-3:30 Homework Vocab column #1 * Post Lab Questions due Friday * *graded Week of 12-2-2013 12-2: Solutions Test 12-3: Equilibrium (HW: #4) 12-4: Equilibrium, Lab, Gas Laws intro (HW: Vocab #1, Lab questions due Friday) 12-5: Gas Laws (HW: Vocab #2, Study) Equilibrium Quiz 12-6: Energy/Thermochem Test Gas Laws (HW: Vocab #3, Solutions Test Corrections) Agenda 12-3 1. 2. 3. 4. 5. 6. Do Now House keeping Equilibrium Wrap Up Equilibrium Practice Ice Cream Lab Intro to Gas Laws Video Objectives • Infer the shift in the equilibrium when a stress is applied to a chemical system ( Le Chatelier’s Principle) Equilibrium Occurs when the rate of the forward reaction is equal to the rate of the backward reaction Equilibrium Constant (Keq) A measure of how far a reaction goes to the right aA bB cC dD c d [C] [D] K eq a b [A] [B] [ ] = concentration Keq > 1 More products than reactants Keq < 1 More reactants than products Once a reaction reaches equilibrium can it ever change?? YES!!! All it takes is a change in either the forward or reverse rates. What changes rxn rate (and therefore changes the equilibrium): Concentration Pressure Temperature Le Chatelier’s Principle If changes are made to a system in equilibrium, the RXN will shift in the direction that will reduce the change Concentration If substance is added, the rxn will shift away from that side; If substance is removed, the rxn will shift towards that side Pressure If pressure is increased, the rxn will shift to the side that will produce fewer molecules (compare moles of gas) Temperature Increased temp will shift the rxn to the side that absorbs heat Equilibrium Practice We all Scream for Ice Cream 1. 2. 3. 4. 5. 6. Get into groups 5 minutes to read through intro 2 pre-lab questions Lab with partners BE SURE TO RECORD ANY DATA If you finish early start working on postlab questions. 7. POST LAB QUESTIONS ARE DUE FRIDAY Intro to Ideal Gas Laws Before : 1 thing you know from kinetics and equilibrium about gases During: 3 bullet points (most important) After: 1 thing you are excited to learn more about from the video http://www.youtube.com/watch?v=BxUS1K7xu30&list =PL8dPuuaLjXtPHzzYuWy6fYEaX9mQQ8oGr Exit Ticket 3rd 4th 1. Ammonia is produced commercially by the Haber reaction: N2(g) + 3 H2(g) ↔ 2 NH3(g) + heat The formation of ammonia is favored by (A) an increase in pressure (B) a decrease in pressure (C)removal of N2(g) (D)removal of H2(g) 2. Given the reaction at equilibrium: 2 SO2(g) + O2(g) ↔ 2 SO3(g) + heat Which change will shift the equilibrium to the right? (A) increasing the temperature (B) increasing the pressure C)decreasing the amount of SO2(g) (D)decreasing the amount of O2(g)