MATERIAL SAFETY DATA SHEET
PhenylMagnesium Bromide
Product Name: PhenylMagnesium Bromide
Identification of the company: Arcelor Chemicals Pvt. Ltd.
Telephone No.: +919819222321
Product Code: ACP - 244
CAS#: 100-58-3
RTECS: Not available
TSCA: Not available
CI#: Not available
Synonym:
(6CI);Bromomagnesiobenzene;Bromophenylmagnesium;
Phenylmagnesiumbromide
Chemical Name: PhenylMagnesium Bromide
Chemical Formula: C6H5MgBr
Composition/Information on Ingredients
Ingredient(S)
PhenylMagnesium Bromide
CAS#
100-58-3
Molecular Weight
181.31
Hazards Identification
Emergency Overview: Highly flammable. Reacts violently with water liberating extremely
flammable gases. May form explosive peroxides. Causes burns.
Factory Add.: Plot No. - 1019, Road No.10, G.I.D.C., Sarigam, Tal.Umbergaon Dist. - Valsad,
Gujrat.
India-396142,
Tel: 91-26022-2781394 / 91-260-2781395 8 Fax: +91-260-2781396
Mumbai Office.: B/134, Oshiwara Industrial Centre, Opp- Oshiwara Bus Depot, Link Road,
Goregaon (West), Mumbai – 400104.
Tel.: 022-28710318 / 022-28710319 8Fax: +91-22-28710319 Ext-27.
Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns.
Ingestion: Causes gastrointestinal tract burns.
First Aid Measures
Eye: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Fire Fighting Measures
General Information: Wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. Exposure to heat may promote
violent decomposition. Will burn if involved in a fire. Water Reactive. Material will react with
water and may release a flammable and/or toxic gas. Extremely flammable liquid and vapor.
May form explosive peroxides.
Extinguishing Media: Use carbon dioxide or dry chemical. DO NOT USE WATER OR FOAM.
Accidental Release Measures
General Information: Use proper personal protective equipment.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in
suitable container. Remove all sources of ignition. Use a spark-proof tool. Do not expose spill to
water.
Handling & Storage
Handling: Facilities storing or utilizing this material should be equipped with an eyewash and a
safety shower facility.
Storage: 1.Do not store in direct sunlight
2.Keep contents under nitrogen
3.Keep in a cool,dry place
4.Keep away from sources of ignition and combustible material
5.Keep container tightly closed
Physical & Chemical Properties
Physical State & Appearance
Liquid
Odor
N/A
Taste
N/A
Molecular Weight
181.31
Molecular Formula
C6H5MgBr
Color
N/A
pH
N/A
Boiling Point
N/A
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Dispersion Properties
Solubility
Flash Point
Storage Temp.
Density
EINECS
Melting Point
N/A
N/A
N/A
N/A
N/A
Reacts with water
-11 °C
N/A
1.134 g/mL at 25 °C
202-867-2
N/A
Stability & Reactivity
Chemical Stability: Decomposes when heated. Air sensitive. Reacts violently with water.
Moisture sensitive. Light sensitive.
Conditions to Avoid: Incompatible materials, excess heat, exposure to moist air or water,
prolonged exposure to air, excess light.
Incompatibilities with Other: Oxidizing agents, acids, bases, alcohols, chlorine,
Hexafluoropropene has an explosive reaction with Grignard Reagents such as
Phenylmagnesium Bromide. (Sax & Lewis)Explosive Peroxides are formed when reacts with
Tetrafluoroethylene and air. ( Sax & Lewis).
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, hydrogen
bromide, bromine fumes, oxides of magnesium.
Polymerization : Will not occur.
Toxicological Information
Toxicity Data[LD50/LC50]: Inhalation, rat: LC50 = 21000 ppm/3H; Oral, rat: LD50 = 1650
mg/kg.
Ecological Information
No information available.
Disposal Considerations
Waste Disposal: Contact a licensed professional waste disposal service to dispose of this
material in a manner consistent with federal, state and local environmental regulations.
Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
Other Regulatory Information
Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Safety glasses.
Other Information
References: Not available.
Other Special Considerations: Not available
The information above is believed to be accurate and represents the best information
currently available to us. However, we make no warranty of merchantability or any other
warranty, express or implied, with respect to such information, and we assumeno liability
resulting from its use. Users should make their own investigations to determine the suitability
of the information for their particular purposes. In no event shall arcelorapi.com be liable for
any claims, losses, or damages of any third party or for lost profits or any special, indirect,
incidental, consequential or exemplary damages, howsoever arising, even if arcelorapi.com
has been advised of the possibility of such damages.
For Arcelor Chemicals Pvt.Ltd.
Plot No. - 1019, Road No.10, G.I.D.C.,
Sarigam, Tal.Umbergaon Dist. - Valsad, Gujrat.
India-396142,
Tel: 91-26022-2781394 / 91-260-2781395
Fax: +91-260-2781396