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List of publications by C Eaborn et. al on compounds containing the trisyl and related
ligands.
1 A. R. Bassindale, C. Eaborn, D. R. M. Walton, and D. J. Young .The electron-releasing effects
of mono-, bis-, and tris-(trimethylsilyl)methyl groups. The importance of hyperconjugation in
the electronic effects of -metalloalkyl groups. J. Organomet. Chem., 1969, 20, 49-56.
2 A. R. Bassindale, A. J. Bowles, M. A. Cook, C. Eaborn, A. Hudson, R. A. Jackson, and A. E.
Jukes .Tris(trimethylsilyl)methyl - a relatively stable saturated organic radical. J. Chem Soc.,
Chem., Chem. Commun., 1970, 559.
3 A. R. Bassindale, C. Eaborn, and D. R. M. Walton. Electronic effects of mono-, bis-, and tris(trimethylsilyl)methyl groups. The 19F nuclear magnetic resonance spectra of m- and p[(Me3Si)xCH(3-x)]C6H4F compounds (x = 0-3). J. Organomet. Chem., 1970, 21, 91-94.
4 M. A. Cook, C. Eaborn, and D. R. M. Walton .Organosilicon compounds. Part XLVII. The
substituent effects and leaving group abilities of mono-, bis-, and tris-(trimethylsilyl)silyl
groups in electrophilic aromatic substitution. J. Organomet. Chem., 1970, 23, 85-90.
5 M. A. Cook, C. Eaborn, and D. R. M. Walton. Substituent effects of mono-, bis-, and
tris(trimethylsilyl)methyl groups: determination of - and +-constants. J. Organomet.
Chem., 1970, 24, 293-299.
6 M. A. Cook, C. Eaborn, and D. R. M. Walton. The mechanism of solvolysis of (2bromoethyl)trimethylsilane. Evidence for the migration of the trimethylsilyl group .J.
Organomet. Chem., 1970, 24, 301-306.
7 M. A. Cook, C. Eaborn, A. E. Jukes, and D. R. M. Walton.
[Tris(trimethylsilyl)methyl]lithium: an alkyllithium compound of unusual stability. J.
Organomet. Chem., 1970, 24, 529-535.
8 C. Eaborn, D. A. R. Happer, S. P. Hopper, and S. D. Safa. Novel rearrangements in reactions
of tris(trimethylsilyl)methylsilicon iodides and hydrides with electrophilic reagents, and the
possibility of cationic intermediates. J. Organomet. Chem., 1979, 170, C9-C12.
9 C. Eaborn and S. P. Hopper. Anchimeric assistance in solvolysis of an organosilicon chloride
and acetate. J. Organomet. Chem., 1979, 170, C51-C52.
10 S. S. Dua, C. Eaborn, D. A. R. Happer, S. P. Hopper, K. D. Safa, and D. R. M. Walton.
Preparation of tris(trimethylsilyl)methyl ("trisyl") derivatives of silicon. J. Organomet.
Chem., 1979, 178, 75-82.
11 C. Eaborn, D. A. R. Happer, P. B. Hitchcock, S. P. Hopper, K. D. Safa, S. S. Washburne, and
D. R. M. Walton. Thermolysis of [tris(trimethylsilyl)methyl](diphenyl)fluorosilane.
Isomerization of a sila-olefin intermediate. J. Organomet. Chem., 1980, 186, 309-323.
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12 C. Eaborn, D. A. R. Happer, S. P. Hopper, and K .D. Safa. The reactions of
[tris(trimethylsilyl)methyl]silicon halides and hydrides with electrophilic reagents. J.
Organomet. Chem., 1980, 188, 179-192.
13 C. Eaborn, N. Retta, and J. D. Smith. Di[tris(trimethylsilyl)methyl]-zinc and -cadmium. J.
Organomet. Chem., 1980, 190, 101-106.
14 C. Eaborn, D. A. R. Happer, and K. D. Safa. Reaction of tris(trimethylsilyl)methylsilicon
halides with methanolic sodium methoxide. Probability of sila-olefin intermediates. J.
Organomet. Chem., 1980, 191, 355-362.
15 C. Eaborn and S. P. Hopper. The reactions of tris(trimethylsilyl)silicon iodides and hydrides
with iodine monochloride. J. Organomet. Chem., 1980, 192, 27-32.
16 S. S. Dua, C. Eaborn, and F. M. S. Mahmoud. A unimolecular solvolysis of an organosilicon
perchlorate. J. Organomet. Chem., 1980, 192, 293-295.
17 C. Eaborn and N. P. Y. Siew. Tris(trimethylsilyl)methyl germanium halides. J. Organomet.
Chem., 1980, 202, 157-162.
18 S. S. Dua and C. Eaborn. Sterically-hindered organosilicon perchlorates. J. Organomet.
Chem., 1981, 204, 21-26.
19 C. Eaborn and K. D. Safa. Pyrolysis of the "trisyl" compounds (Me3Si)3CSiPh2I and
(Me3Si)3CSiPhMeI. J. Organomet. Chem., 1981, 204, 169-179.
20 C. Eaborn and F. M. S. Mahmoud. Rate-determining ionization in methanolysis of an
organosilicon halide. J. Chem. Soc.,, Chem. Commun., 1981, 63-64.
21 C. Eaborn, K. D. Safa, A. Ritter, and W. Binder. Photo-induced reactions of an organosilicon
iodide. J. Chem. Soc.,, Chem. Commun., 1981, 175-176.
22 B. Beagley, R. G. Pritchard, C. Eaborn, and S. S. Washburne. A gas-phase electron
diffraction study of tris(trimethylsilyl)methane. A C-H bond of high p-character. J. Chem.
Soc.,, Chem. Commun., 1981, 710-711.
23 C. Eaborn and F. M. S. Mahmoud. Unimolecular solvolysis of some organosilicon
perchlorates and iodides. J. Chem. Soc., Perkin Trans.2, 1981, 1309-1315.
24 C. Eaborn and F. M. S. Mahmoud. Some properties of the sterically-hindered aminosilane
(Me3Si)3CSiMe2NH2. J. Organomet. Chem., 1981, 220, 139-143.
25 C. Eaborn, P. B. Hitchcock and P. D. Lickiss. The molecular structure of
[dimethyl(phenyl)silyl]tris(trimethylsilyl)methane. J. Organomet. Chem., 1981, 221, 13-17.
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26 C. Eaborn, P. B. Hitchcock and K. D. Safa. An unusual bicyclic tetrasiloxane. J. Organomet.
Chem., 1981, 222, 187-194.
27 S. A. I. Al-Shali, C. Eaborn, and F. M. S. Mahmoud. The SN1 methanolysis of a tertiary
organosilicon iodide, (Me3Si)3CSiMe2I. J. Organomet. Chem., 1982, 232, 215-218.
28 C. Eaborn and K. D. Safa. Some highly sterically hindered organo-silanols and -siloxanes. J.
Organomet. Chem., 1982, 234, 7-14.
29 C. Eaborn, N. Retta, J. D. Smith, and P. B. Hitchcock. The preparation and molecular
structure of the highly sterically hindered tris(trimethylsilyl)methylboron compound
(Me3Si)3CB(Ph)[O(CH2)4C(SiMe3)3]. J. Organomet. Chem., 1982, 235, 265-271.
30 C. Eaborn, K. D. Safa, A. Ritter, and W. Binder. Photoinduced ionic and free-radical
reactions of some organosilicon iodides. J. Chem. Soc., Perkin Trans. 2, 1982, 1397-1401.
31 C. Eaborn. Novel properties of some highly sterically hindered organosilicon compounds. J.
Organomet. Chem., 1982, 239, 93-103.
32 C. Eaborn, P. D. Lickiss, G. Marquina-Chidsey, and E. Y. Thorli.
(Dimethyl)[tris(trimethylsilyl)methyl]silyl cyanate and related species: the first silicon
cyanate. J. Chem. Soc.,, Chem. Commun., 1982, 1326.
33 R. Damrauer, C. Eaborn, D. A. R. Happer and A. I. Mansour. A novel 1,3-migration of a silyl
group from carbon to oxygen in a silanolate ion. J. Chem. Soc., Chem. Commun., 1983, 348.
34 S. A. I. Al-Shali and C. Eaborn. Bimolecular displacements of iodine in reactions of
dimethyl[tris(trimethylsilyl)methyl]silyl iodide with salts. J. Organomet. Chem., 1983, 246,
C34-36.
35 C. Eaborn, N. Retta, and J. D. Smith. Some [tris(trimethylsilyl)-methyl]phosphorus
derivatives. J. Chem. Soc., Dalton Trans., 1983, 905-909.
36 C. Eaborn, N. M. El-Kheli, N. Retta, and J. D. Smith. Some tris(trimethylsilyl)methyl
derivatives of boron, aluminium and gallium. J. Organomet. Chem., 1983, 249, 23-31.
37 Z. Aiube, J. Chojnowski, C. Eaborn, and W. A. Stanczyk. Internal nucleophilic
displacements within silanolate ions. A new mechanism of substitution at silicon. J. Chem.
Soc.,, Chem. Commun., 1983, 493-495.
38 C. Eaborn and D. E. Reed. Anchimeric assistance in methanolysis of some organosilicon
halides, perchlorates, and trifluoromethanesulphates. J. Chem. Soc.,, Chem. Commun., 1983,
495-496.
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39 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. Some derivatives of
tris(dimethylsilyl)methane. A novel bicyclic tris(disiloxane) with a manxane structure. J.
Organomet. Chem., 1983, 252, 281-288.
40 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Crystal structure of the
tetrahydrofuran adduct of tris(trimethylsilyl)methyl-lithium, [Li(thf)4][Li{C(SiMe3)}2], an ate
derivative of lithium. J. Chem. Soc.,, Chem. Commun., 1983, 827-828.
41 A. I. Al-Wassil, C. Eaborn, and A. K. Saxena. Oxidatively assisted nucleophilic substitution
of organosilicon iodides. J. Chem. Soc.,, Chem. Commun., 1983, 974-975.
42 C. Eaborn and A. I. Mansour. Reactions of some sterically-hindered organosilicon hydrides
and iodides with halogens. J. Organomet. Chem., 1983, 254, 273-282.
43 C. Eaborn, Y. Y. El-Kaddar, and P. D. Lickiss. [Tris(trimethylsilyl)methyl]-(dimethyl)silyl
cyanate. The cyanate to isocyanate isomerization, and the high activity of cyanate as a
leaving group in solvolysis. J. Chem. Soc.,, Chem. Commun., 1983, 1450-1451.
44 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. A novel monomeric alkyllithium compound. Crystal structure of [Li{C(SiMe2Ph)3}(tetrahydrofuran)].
J. Chem. Soc., Chem. Commun., 1983, 1390-1391.
45 C. Eaborn, P. D. Lickiss, and N. A. Ramadan. Cleavages of silicon-carbon bonds in
tris(trimethylsilyl)methylsilicon compounds by trifluoroacetic acid. Rearrangements and
anchimeric assistance.J. Chem. Soc., Perkin 2, 1984, 267-270.
46 A. I. Al-Wassil, C. Eaborn, A. Hudson, and R. A. Jackson. An electron spin resonance study
of some silicon-centred free radicals with a tris(trimethylsilyl)methyl substituent. J.
Organomet. Chem. 1983, 258, 271-275.
47 .S. A. I. Al-Shali, C. Eaborn, F. A. Fattah, and S. T. Najim. An SN2 (intermediate) mechanism
for solvolysis of organosilicon iodides. J. Chem. Soc., Chem. Commun., 1984, 318-319.
48 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and crystal structure
of the tetrahydrofuran adduct of lithium bis[tris(trimethylsilyl)methyl]cuprate,
[Li(THF)4][Cu{C(SiMe3)3}2].The first structural characterization of a Gilman reagent. J.
Organomet. Chem. 1984, 263, C23-C25.
49 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. Tetrakis(hydroxymethylsilyl)methane and its
dehydration with rearrangement. Crystal structure of 2,2,4,4,6,6-hexamethyl-5hydroxydimethylsilyl)1,3-dioxa-2,4,6-trisilacyclohexane. J. Organomet. Chem. 1984, 264,
119-126.
50 Z. H. Aiube and C. Eaborn. Improvements in the preparation and use of
[tris(trimethylsilyl)methyl]lithium. J. Organomet. Chem. 1984, 269, 217-218.
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51 C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. The crystal structure of
tris(phenyldimethylsilyl)methane. J. Organomet. Chem. 1984, 269, 235-238.
52 C. Eaborn and A. K. Saxena. Comparisons of the reactivities of the tri-t-butyl- and
tris(trimethylsilyl)methyl-silicon compounds. J. Organomet. Chem. 1984, 271, 33-46.
53 C. Eaborn, M. N. A. El-Kheli, P. B. Hitchcock, and J. D. Smith. Preparation and crystal
structure of [tris(trimethylsilyl)methyl]diphenylborane. J. Organomet. Chem. 1984, 272, 1-9.
54 C. Eaborn, P. B. Hitchcock, P. D. Lickiss, A. Pidcock, and K. D. Safa. Crystal stucture and
variable-temperature hydrogen-1 nuclear magnetic resonance spectrum of
(dimethylnitratosilyl)[methyldiphenylsilyl]bis(trimethylsilyl)methane,
C(SiMe3)2(SiMePh2)(SiMe2ONO2).J. Chem. Soc., Dalton Trans., 1984, 2015-2017.
55 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and crystal structure
of the argentate complex [Li(tetrahydrofuran)4][Ag{C(SiMe3)3}2]. J. Chem. Soc., Chem.
Commun., 1984, 870-871.
5 C. Eaborn and A. K. Saxena. .1,3-methyl migration from germanium to silicon in reactions of
(Me3Si)2(Me3Ge)C(SiMe2Br) with silver salts. J. Chem. Soc., Chem. Commun., 1984, 14821483.
57 C. Eaborn and M. N. Romanelli. The first silicon thiocyanate. J. Chem. Soc., Chem.
Commun., 1984, 1616-1617.
58 .C. Eaborn, M. N. A. El-Kheli, P. B. Hitchcock, and J. D. Smith. The crystal structure of the
alkyltrihydroborate (thf)3Li(µ-H)3BC(SiMe2Ph)3. (thf = tetrahydrofuran). J. Chem. Soc.,
Chem. Commun., 1984, 1673-1674.
59 R. I. Damja, C. Eaborn, and A. K. Saxena. Acyl-oxygen fission in reactions of organosilicon
carboxylates with sodium methoxide in methanol. J. Chem. Soc., Perkin 2, 1985, 597-598.
60 C. Eaborn and A. I. Mansour. Reactions of silicon centres bearing the bulky
tris(phenyldimethylsilyl)methyl ligand. J. Chem. Soc., Perkin 2, 1985, 729-735,
61 C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Novel anionic cages from
'alkylmanganese chloride' and 'alkylcobalt chloride' solutions. Crystal and molecular structure
of [Li(thf)4][{(Me3Si)3C}3Mn3Cl4(thf)] (thf - tetrahydrofuran). J. Chem. Soc., Chem.
Commun., 1985, 534-535.
62 C. Eaborn. .Highly sterically hindered organosilicon compounds, in ‘Organosilicon and
Bioorganosilicon Chemistry’. (ed. H. Sakurai). Ellis Horwood. Chichester. 1985, 123-130.
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63 R. I. Damja and C. Eaborn. Preparation and reactions of some sterically hindered silanols,
including [tris(trimethylsilyl)methyl]silanetriol. J. Organomet. Chem. 1985, 290, 267-275.
64 R. I. Damja, C. Eaborn, and W.-C. Sham. .Reactions of (Me3Si)3CSiMe2R compounds (R =
CH=CH2, CH2CH=CH2, CCPh, Ph, and CH2Ph) with electrophiles. J. Organomet. Chem.
1985, 291, 25-33.
65 Z. H. Aiube, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, and J. A. Zora. .The preparation and
crystal structures of [(Me3Si)3C]PhSi(OH)2 and [(Me3Si)3PhSi(OMe)OH. J. Organomet.
Chem. 1985, 292, 177-188.
66 C. Eaborn and D. E. Reed. Preparation and reactions of difunctional sterically hindered
organosilicon compounds of the type (Me3Si)2C(SiMe2X)(SiMe2Y). J. Chem. Soc., Perkin
Trans. 2, 1985, 1687-1693.
67 C. Eaborn and D. E. Reed. Absence of rearrangement in reactions of the compounds
(Me3Si)3CSiMe(OMe)I, (Me3Si)3CSi(OMe)2I with electrophilic reagents. J. Chem. Soc.,
Perkin Trans. 2, 1985, 1695-1697.
68 J. L. Atwood, S. G. Bott, C. Eaborn, M. N. A. El-Kheli, and J. D. Smith. The crystal and
molecular structure of fluoro(hydroxy){tris-(dimethylphenylsilyl)methyl}borane. J.
Organomet. Chem. 1985, 294, 23-30.
69 C. Eaborn and P. D. Lickiss. Some tetrasilylmethane derivatives. J. Organomet. Chem. 1985,
294, 305-313.
70 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. Preparation and
crystal structure of a two-coordinate manganese compound,
bis[tris(trimethyl)silylmethyl]manganese. J. Chem. Soc., Chem. Commun., 1985, 1380-1381.
71 N. H. Buttrus, R. I. Damja, C. Eaborn, P. B. Hitchcock, and P. D. Lickiss. The crystal
structure of [tris(trimethylsilyl)methyl]silanetriol. A novel and remarkably stable hydrogenbonded cage structure. J. Chem. Soc., Chem. Commun., 1985, 1385-1386.
72 C. Eaborn, P. D. Lickiss, S. T. Najim, and M. N. Romanelli. Unimolecular alcoholysis of
organosilicon halides of the type (Me3Si)2C(SiMe2OMe)(SiR'2X). Anchimeric assistance by
and migration of the OMe group. J. Chem. Soc., Chem. Commun., 1985, 1754-1755.
73 G. A. Ayoko and C. Eaborn. Neighbouring group participation by the vinyl group in reactions
of sterically-hindered organosilicon compounds. J. Chem. Soc., Chem. Commun., 1986, 630631.
74 A. G. Avent, C. Eaborn, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan. An electrondeficient indium hydride. Crystal structure and N.M.R. spectrum of (Me3Si)3CIn(H)(µ-
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H)In(µ-H)(H)C(SiMe3)3 (thf = tetrahydrofuran). J. Chem. Soc., Chem. Commun., 1986, 988989.
75 N. H. Buttrus, C. Eaborn, S. H. Gupta, P. B. Hitchcock, J. D. Smith, and A. C. Sullivan.
Preparation and crystal structure of the novel internally solvated dimeric organolithium
compound [{LiC(SiMe2OMe)3}2]. J. Chem. Soc., Chem. Commun., 1986, 1043-1044.
76 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, J. D. Smith, J. G. Stamper, and A. C. Sullivan.
The crystal structure of [(pmdeta)Li(µ-Cl)Li(pmdeta)][Li{C(SiMe3)3}2] {pmdeta =
Me2N(CH2)2NMe(CH2)2NMe2}. A novel linear chlorine-centred cation. J. Chem. Soc., Chem.
Commun., 1986, 969-970.
77 S. Al-Juaid, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, T. L. Roberts, J. D. Smith, and A. C.
Sullivan. Novel alkylmetal hydroxides. The crystal and molecular structures of bis(µhydroxy)bis{tris(dimethyl-phenylsilyl)methylzinc}, [{Me2PhSi)3CZnOH}2], and µ4oxohexa(µ-hydroxy) tetrakis{tris(trimethylsilyl)methylindium}, [O{Me3Si)3CIn}4(OH)6. J.
Chem. Soc., Chem. Commun., 1986, 908-909.
78 N. H. Buttrus, C. Eaborn, P. B. Hitchcock, P. D. Lickiss, and A. D. Taylor. Hydrogen
bonding in organosilicon hydroxides: crystal structures of dichlorohexylsilanediol and
bis(hydroxydimethylsilyl)bis(trimethylsilyl)methane. J. Organomet. Chem. 1986, 309, 25-33.
79 G. A. Ayoko and C. Eaborn. The effects of the vinyl groups in reactions of the highly
sterically hindered compound [tris(trimethylsilyl)methyl]divinylsilyl chloride. J. Chem. Soc.,
Perkin Trans. 2, 1986, 1289-1293.
80 G. A. Ayoko and C. Eaborn. Silicon-oxygen and acyl-oxygen bond cleavage in reactions of
sterically hindered organosilicon carboxylates. J. Chem. Soc., Perkin Trans. 2, 1986, 13571361.
81 A.G. Avent, C. Eaborn, M.N.A. El-Kheli, M.E., Molla, J.D. Smith, and A.C. Sullivan.
Utilization of the 6Li{1H} nuclear Overhauser effect. The structures of
hydro[tris(trimethylsilyl)methyl]-metallates of boron, aluminium, and indium in solution. J.
Am. Chem. Soc., 1986, 108, 3584-3585.
82 A.I. Al-Wasssil, C. Eaborn, and M.N. Romanelli. Peparation and some reactions of
compounds of the type (Me3Si)2C(SiMe2OMe)(SiMe2X). Anchimeric assistance by the
methoxy group. J. Chem. Soc., Perkin Trans. 2, 1986, 1363-1365
83 C. Eaborn, P.D. Lickiss, S.T. Najim, and M.N. Romanelli. 1,3-Migration of chloride and
azide substituents within organosilicon cations, and anchimeric assistance by the azido group.
J. Organomet. Chem. 1986, 315, C5-C8.
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84 G.A. Ayoko and C. Eaborn. Preparation and some reactions of the compounds HgVsi2,
CdVsi2, and Hg(Vsi)Br [Vsi = (Me3Si)2(CH2=CHMe2Si)C]. J. Chem. Soc., Perkin Trans. 2,
1987, 381-383.
85 G.A. Ayoko and C. Eaborn. Reactions of bis[dimethyl(vinyl)silyl]bis(trimethylsilyl)methane, (Me3Si)2(SiMe2CH=CH2)2. J. Chem. Soc., Perkin Trans. 2, 1987, 657-662.
86 C. Eaborn and M.N. Romanelli. Anchimeric assistance by the methoxy group in solvolysis of
the compounds (Me3Si)2C(SiMe2OMe)-(SiMe2X). J. Chem. Soc., Perkin Trans. 2, 1987, 657662.
87 S.A. Al-Juaid, S.M. Dhaher, C. Eaborn, P.B. Hitchcock, and J.D. Smith. Preparation and
crystal structures of the crowded organotin fluorides (PhMe2Si)3CSnMe2F,
(Me3Si)3CSiMe2F, and (Me3Si)3CSnPh2F. J. Organomet. Chem. 1987, 325, 117-127.
88 C. Eaborn and A.K. Saxena. 1,3-Migration of a methyl group from germanium to silicon in
reactions of (Me3Si)2C(GeMe3)(SiMe2Br) with silver salts. J. Chem. Soc., Perkin Trans. 2,
1987, 779-782.
89 C. Eaborn and A.K. Saxena. The effect of the _-OMe group on the reactivity of the
germanium chloride (Me3Si)2C(SiMe2OMe)(GeMe2Cl). J. Chem. Soc., Perkin Trans. 2,
1987, 775-778.
90 N.H. Buttrus, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, and S.T. Najim. Migration of the
methoxy group in an organosilicon cation. Reactions of (bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane with silver borofluoride and silver
chloride. Crystal structure of (chlorodiphenylsilyl)(methoxydimethylsilyl)-bis(trimethylsilylmethane). J. Chem. Soc., Perkin Trans. 2, 1987, 891-894.
91 G.A. Ayoko and C. Eaborn. Assistance by and migration of the vinyl group in reactions of
the sterically hindered compounds of the type (Me3Si)2C(SiMe2 CH=CH2)(SiR2X). J. Chem.
Soc., Perkin Trans. 2, 1987, 1047-1058.
92 D.B. Azarian, C. Eaborn, and P.D. Lickiss. Effects of the substituents Y in reactions of
compounds of the type (Me3Si)3CSiH(C6H4Y-p)I. Evidence against the SN2(intermediate)
mechanism for methanolysis of (328, Me3Si)3CSiMe2I and (Me3Si)3CSiHPhI. J. Organomet.
Chem. 1987, 328, 256-262.
93 D.B. Azarian, C. Eaborn, and P.D. Lickiss. Reactions of tris(trimethylsilyl)methylsilicon
compounds with organolithium reagents. J. Organomet . Chem., 1987, 330, 1-7.
94 S.M. Dhaher, C. Eaborn, and J.D. Smith. 1,3-Migration of a methyl group from tin to silicon
via a cationic intermediate. J. Chem. Soc., Chem. Commun., 1987, 1337-1388.
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95 C. Eaborn, P.D. Lickiss, S.T. Najim, and W.A. Stanczyk. 1,3-Migrations of a phenyl group
via a silicocation. J. Chem. Soc., Chem. Commun., 1987, 1183-1184.
96 N.H. Butruss, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, and S.T. Najim. 1,3 Silicon to silicon
migration of the methoxy group in solvolysis of
(bromodiphenyl)(methoxydimethylsilyl)bis(trimethylsilyl)-methane. Crystal structure of
(ethoxydimethylsilyl)(methoxydiphenyl-silyl)bis(trimethylsilyl)methane and
(methoxydimethylsilyl)(methoxy-diphenylsilyl)bis(trimethylsilyl)methane. J. Chem. Soc.,
Perkin Trans. 2, 1987, 1753-1757.
97 C. Eaborn, P.D. Lickiss, and A.D. Taylor. Reactions of the sterically hindered organosilicon
diol (Me3Si)2C(SiMe2OH)2 and some of its derivatives. J. Organomet. Chem. 1988, 340,
283-292.
98 J. A. Atwood, S.G. Bott, P.B. Hitchcock, C. Eaborn, R.S. Shariffudin, J.D. Smith, and A.C.
Sullivan. The chemistry of trichloro[tris-(dimethylphenylsilyl)methyl] complexes of gallium,
indium, and thallium. Crystal and molecular structures of [Li(thf)2(µCl)2GaCl{C(SiMe2Ph)3}].thf, [Li(thf)3(µ-Cl)InCl2{C(SiMe3)3}], and [{(Me3Si)3C}In(µCl)2{µ-Fe(CO)4}In{C(SiMe3)3}] (thf = tetrahydrofuran). J. Chem. Soc., Dalton Trans.,1987,
747-755.
99 C. Eaborn, P.D.Lickiss, and A.D. Taylor. The nature of the anchimeric assistance by the
acetoxy group in solvolysis of (Me3Si)2C(SiMe2OCOMe)(SiMe2Cl). J. Organomet. Chem.
1988, 338, C27-C29.
100 N.H. Buttrus, C. Eaborn, M.N.A. El-Kheli, P.B. Hitchcock, J.D. Smith, A.C. Sullivan, and
K. Tavakkoli. Some sterically hindered lithium alkylbromo- and alkylchloro-magnesates.
Crystal and molecular structures of [Li(thf)2(µ-Br)2Mg{C(SiMe3)3}(thf),
[Li(thf)4][{Cd[C(SiMe3)3]}3(µ-Br)(µ-Br)3].0.5C6H12, [{Li(thf)3}(µ-Br)3Br)(µOSiMe3)Cd{C(SiMe3)}3], and [Li(thf)4][Mn[C(SiMe3)3]}3(µ-Cl)4(thf). J. Chem. Soc.,
Dalton Trans., 381-391.
101 N.H. Buttrus, C. Eaborn, M.E. Molla, P.B. Hitchcock, and J.D. Smith. The The synthesis and
crystal structure of µ{di-_6-phenyl(trimethylsilyl)methane}bis(tricarbonyl)chromium. J.
Organomet. Chem.,1988, 344, 313-319.
102 S.S. Al-Juaid, N.H. Buttrus, C. Eaborn, P.B. Hitchcock, J.D. Smith,and K. Tavakkoli. The
preparation and crystal structure of the sterically hindered lithium alkylchlorocadmate
[Li(thf)4][Li(thf)2(µ-Cl)4{CdC(SiMe3)3}2].thf (thf = tetrahydrofuran), the alkylcadmium
halides [{Cd[C(SiMe3]Cl4] and [{Cd[C(SiMe2Ph)3]Br}2], and the hydrate
[{Cd[C(SiMe2Ph)3]Br}(H2O)]2.(thf). J. Chem. Soc., Chem. Commun., 1988, 1389-1391.
103 A. Alvanipour, N.H. Buttrus, C. Eaborn, P.B. Hitchcock, A. I. Mansour, and A.K. Saxena.
Formation of a tetraazole from (PhMe2Si)3CSiMe2I. Crystal structure of
(PhMe2Si)3CSiMe2N-N=C(Me)-N=N. J. Organomet. Chem. 1988, 349, 29-36.
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104 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and P.D. Lickiss, The crystal structure of
tetrakis(hydroxydimethylsilyl)methane. A remarkable three-dimensional network. J.
Organomet. Chem.; 1988, 353, 297-305.
105 S.M. Dhaher, C.Eaborn, and J.D. Smith. Synthesis and properties of some crowded organotin
compounds. J. Organomet. Chem. 1988, 355, 33-44.
106 S.S. Al-Juaid, S.M. Dhaher, C. Eaborn, P.B. Hitchcock, C.A McGeary, and J.D. Smith,
Some [(tris(trimethyl)- and [tris(dimethylphenyl)silyl])methyl derivatives of phosphorus. The
crystal structure of [tris(dimethylphenylsilyl)]methylphosphonous dichloride. J. Organomet.
Chem.,1989, 366, 39-51.
of metasilicate intermediates. J. Chem. Soc., Perkin Trans. 2, 1989, 865-871.
107 S.S. Al-Juaid, N.H. Buttrus, R.I. Damja, Y. Derouiche, C. Eaborn, P.B. Hitchcock, and P.D.
Lickiss. Hydrogen bonding in organosilanetriols. The crystal structures of
tris(trimethylsilyl)silyl- and tris(trimethylsilyl)methylsilanetriol. J. Organomet. Chem. 1989,
371, 287-295.
108 S.S. Al-Juaid, C. Eaborn, M.N.A. El-Kheli, P.B. Hitchcock, P.D. Lickiss, M.E. Molla, J.D.
Smith, and J.A. Zora. Tris(trimethyl)methyl and tris(dimethylphenyl)silyl)methyl derivatives
of boron. Crystal structures of dihydroxy[tris(trimethyllsilyl)methyl]borane and the lithiumboron complex [(MeOH)2Li(µ-OMe)B(OMe)2]. J. Chem. Soc, Dalton Trans.,1989, 447-452.
109 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, C.A. McGeary, and J.D. Smith. The crystal
structure of [tris(trimethylsilyl)methyl]magnesium: an example of two-coordinate magnesium
in the solid state. J. Chem. Soc., Chem. Commun., 1989, 273-274.
110 C. Eaborn, K.L. Jones, and P.D. Lickiss. Anchimeric assistance by -aryl groups in solvolysis
of organosilicon iodides. Some remarkably large remote substituent effects. J. Chem. Soc.,
Chem. Commun.,1989, 595-596.
111 C. Eaborn, K.L. Jones, J.D. Smith, and K. Tavakkoli. The remarkable thermal stability of
benzyl[tris(dimethylphenylsilyl)methyl]mercury. How can a bulky ligand stabilize an
organometallic compound towards unimolecular dissociation? J. Chem. Soc., Chem.
Commun., 1989, 1202-1202.
112 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, P.D. Lickiss, A. Möhrke, and P. Jutzi. Hydrogenbonding in organosilanediols. The crystal structure of
bis(pentamethylcyclopentadienyl)silanediol. J. Organomet. Chem. 1990, 384, 33-40.
113 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, K Kundu, M.E. Molla, and J.D. Smith. Novel
tris(trimethylsilyl)methylboron compounds. Crystal structures of the diborane
{(Me3Si)3C}HB(µ-H)2BH{C(SiMe3)3} and the bis(aminoboryl)amine
{(Me3Si)3C(NH2)B}2NH, J. Organomet. Chem. 1990, 385, 13.
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114 S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and J.D. Smith, and L. Zanotto. Desilylation and
cyclometallation reactions of diphenyl{tris(trimethylsilyl)methyl}phosphine with platinum(II)
compounds. Crystal structure of trans-[PtClPPh2C(SiMe3)2SiMe2CH2{PPh2CH(SiMe3)2]. J.
Organomet. Chem. 1990, 394, 69-75.
115 A.I Al-Mansour, M.A.M.R. Al-Guarashi, C. E.Eaborn, F.A. Fatttah, and P.D. Lickiss. 1,3Migration of triorganosilyl groups from carbon to oxygen in highly crowded organosilanols.
J. Organomet. Chem. 1989, 393, 27-32.
116 C. Eaborn and F.A. Fattah. Miscellaneous reactions of tris(trimethylsilyl)methylsilicon
compounds. J. Organomet. Chem. 1990, 396, 1-8.
117 C. Eaborn, P.D. Hitchcock, P.D. Lickiss, and A.D. Taylor. The synthesis and crystal structure
of the crowded disiloxane [(Me3Si)3Cl2Si]2O. J. Organomet. Chem. 1990, 398, 59-64
118 C. Eaborn, A. Habtemariam, F Aigbirhio, C. Eaborn, and J.D. Smith, J. Chem. Soc., Chem.
Commun, 1990, 1471-1472.
119 F.I Aigbirhio, S.S. Al-Juaid, C. Eaborn, A. Habtamariam, P.B. Hitchcock, and J.D. Smith.
Some unusual organo-zinc and -mercury compounds. The crystal structures of the
compounds [(HOMe2Si)(Me3Si)2C]2Zn, [(MeOMe2Si)(Me3Si)2C]2Zn, and
[(MeOMe2Si)(Me3Si)2C]2Zn, J. Organomet. Chem. 1991, 405, 149-165.
120 C. Eaborn. A contribution to the silicenium ion debate. J. Organomet. Chem., 1991, 405,
141-148.
121 F.I. Aigbirhio, S.S. Al-Juaid, C. Eaborn, P.B. Hitchcock, and P.D.Lickiss. Comparison of the
Reactivities of the Compounds (Me3Si)2C(SiMe2OMe)(SiMe2Cl) and
(MeOMe2Si)3C(SiMe2Cl). Crystal Structure of (MeOMe2Si)3CSiPh2H. J. Chem. Soc., Perkin
Trans. 2, 1991, 1407-1410.
122 S. S Al-Juaid, A. K. A. Al-Nasr, C. Eaborn, and P. B. Hitchcock. Hydrogen bonding
interaction between a hydroxy group and the -electrons of an aryl group. Crystal structure of
[tris(dimethylphenylsilyl)methyl]methylsilanol. J. Chem. Soc., Chem. Commun, 1991, 14821484.
123 C. Eaborn and D.A.R Happer. A novel mode of reaction of a substituted alkyl halide.
Reduction of tris(trimethylsilyl)methyl iodide by methanol. J. Chem. Soc., Chem. Commun,
1991, 1608-1609.
124 Z. H. Aiube and C. Eaborn, Reactions at highly sterically hindered centres. Chemistry of
(Me3Si)3CPhHI, (Me3Si)3CPh(OMe)I, and related species. J. Organomet. Chem. 1991, 421,
159-169.
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125 S. S. Al-Juaid, C. Eaborn, and P.B. Hitchcock. The crystal structure of
(Me3Si)3CSi(OH)2(OCOCF3). J. Organomet. Chem. 1992, 423, 5-12.
126 F.I. Aigbirhio, N.H. Buttrus, C. Eaborn, S.H Gupta, P.B. Hitchcock, J.D. Smith., and A.C.
Sullivan. Synthesis, crystal structure and reactions of the dimeric organolithium compound
[{(MeO)Me2Si]3CLi. J. Chem. Soc., Dalton Trans.,1992, 1015-1018.
127 C Eaborn, K.L. Jones, and P.D. Lickiss. Anchimeric assistance by -aryl groups in reactions
of organosilicon iodides. J. Chem. Soc., Perkin Trans. 2, 1992, 489-495.
128 C. Eaborn, Y.Y. El-Kaddar, and P.D. Lickiss. Preparation and reactions of some
organosilicon cyanates. Inorg. Chim. Acta., 1992, 200, 337-344.
129 S. S Al-Juaid, A. K. A. Al-Nasr, C. Eaborn, and P. B. Hitchcock. Crystallographic Evidence
for Intermolecular Interaction Between Aryl Groups and OH Groups in Silanols. J.
Organomet. Chem., 1992, 429, C9-C13.
130 S.S. Al-Juaid, C. Eaborn, A. Habtamariam, P.B. Hitchcock, and J.D. Smith. Reactions of
sterically hindered organozinc and organocadmium compounds containing functional silicon
centres. Crystal structures of Zn[C(SiMe3)2(SiMe2OCOCF3)]2 and
Cd[C(SiMe3)2(SiMe2OMe)]2. J. Organomet. Chem. 1992, 437, 41-45.
131 Y.Y. El-Kaddar, C. Eaborn, P.D. Lickiss, and D.E. Reed. The methanolysis of the highly
strerically hindered organosilicon compounds (Me3Si)3CSiMe2X with X = OSO2CF3, OCN,
or OClO3. A mechanistic enigma. J. Chem. Soc., Perkin Trans. 2, 1992, 1753-1759.
132 C. Eaborn, P.D. Lickiss, S.T. Najim, and W.A. Stanczyk. Reaction of
(Me3Si)2C(SiMe2Ph)(SiMe2I) with AgBF4. 1,3-Migration of the phenyl group. J. Chem. Soc.,
Perkin Trans. 2, 1993, 59-62.
133 C. Eaborn, P. D. Lickiss, and S. T. Najim. 1,3-Migration of chloride and azide ligands in
reactions of highly sterically hindered organosilicon halides. J. Chem. Soc., Perkin Trans. 2,
1993, 391-394.
134 C. Eaborn, K. L. Jones, P. D. Lickiss and W. A. Stanczyk. Proportion of 1,3-phenyl
migration in the trifluoroethanolysis, methanolysis, and hydrolysis of
(Me3Si)2C(SiMe2Ph)(SiEt2I), J. Chem. Soc., Perkin Trans. 2, 1993, 395-397.
135 S.S. Al-Juaid, M. Al-Rawi, C. Eaborn, P.B. Hitchcock, and J.D. Smith. Preparation and
crystal structures of the crowded triorganotin isothiocyanate (PhMe2Si)3CSnMe2NCS and
nitrate (PhMe2Si)3CSnMe2ONO2. J. Organomet. Chem. 1993, 446, 161-166.
136 C. Eaborn and N M. Romanelli. Anchimeric assistance by the -N3 and -NCS groups in
solvolysis of (Me3Si)2C(SiMe2N3)(SiMe2Br) and (Me3Si)2C(SiMe2NCS)(SiMe2Br). J.
Organomet. Chem. 1993, 451, 45-52.
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137 S.S. Al-Juaid, A.K. Al-Nasr, C. Eaborn and P.B. Hitchcock.The crystal structure of the
oganosilicon p-toluenesulfonate (Me3Si)3SiPh(H)(OSO2C6H4Me-p). J. Organomet. Chem.
1993, 455, 57-60.
138 Y. Y. El-Kaddar, C. Eaborn, and P. D. Lickiss. Reactions of the highly sterically hindered
compounds (Me3Si)3CSiMe2X (X = Cl, Br, I, or ONO2) with NaN3, CsF, KSCN, and KOCN
in MeOH. J. Organomet. Chem. 1993, 460, 7-13.
139 A. G. Avent, C. Eaborn, P. B. Hitchcock, G. A. Lawless, P. D. Lickiss, M. Mallien, J. D.
Smith, A. D. Webb, and B Wrackmeyer. Crystal structure of [Li(tmeda)2][Li{C(SiMe3)2]. A
multinuclear magnetic resonance study of tris(trimethylsilyl)methyl-lithium-tetrahydrofuran
(thf) and -tetramethylenediamine (tmeda). J. Chem. Soc., Dalton Trans.,1993, 3259-3264.
140 C. Eaborn, K. L. Jones, and P. D. Lickiss. Reactions of compounds of the type
(Me3Si)2C(SiMe2C6H4Y)(SiMe2X) with trifluoroacetic acid. J. Organomet. Chem. 1993, 461,
7-13.
141 S. S. Al-Juaid, C. Eaborn, A. Habtemariam, P. B. Hitchcock, J. D. Smith, K. Tavakkoli, and
A. D. Webb. The preparation and crystal structures of the compounds (Ph2MeSi)3CMCl (M =
Zn, Cd, or Hg). J. Organomet. Chem. 1993, 462, 45-55.
142 B. M. Clark, C. Eaborn, and D. A. R. Happer. Light catalysed reduction of
tris(trimethylsilyl)methyl iodide. A radical chain process showing a large kinetic hydrogen
isotope effect. J. Chem. Soc., Perkin Trans. 2, 1994, 341-345.
143 C. Eaborn, K. L. Jones, and P. D. Lickiss. Preparation of the iodides
(Me3Si)2C(SiMe2C6H4Y)(SiMe2I) and some related compounds. J. Organomet. Chem. 1994,
466, 35-42.
144 S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, A. J. Jaggar, and J. D. Smith. The reaction of
(Me3Si)3CBr with Mg in tetrahydrofuran or diethyl ether. Crystal structure of
(Me3Si)3CMg(µ-Br)3Mg(THF)3. J. Organomet. Chem. 1994, 469, 129-133.
145 (a) S. S. Al-Juaid, C. Eaborn, P.B. Hitchcock, K. Izod, M. Mallien and
J.D. Smith. Metallation of tris(trimethylsilyl)- and tris(dimethylphenylsilyl)methane with
methylsodium: the first diakylsodate. Angew. Chem. Int. Ed. Engl., 1994, 33, 1268-1270; (b)
Angew. Chem., 1994, 106, 1336-1338.
146 S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, A. J. Jaggar, and J. D. Smith. Crystal stuctures of
tris(trimethylsilyl)methyl- and tris(dimethylphenylsilyl)methyl)-potassium, Organometallics,
1994, 13, 753-754.
147 A. I. Al-Mansour, S. S. Al-Juaid, C. Eaborn and P. B. Hitchcock. Crystal structure.of the
crowded silanol (Me3Si)3SiPh2OH. J. Organomet. Chem., 1994, 480, 139-143.
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201
S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, K. Kundu, C. A. McGeary and J. D. Smith.
Preparation, crystal structure and reactivity of bis{tris(trimethylsilyl)methyl}magnesium, J.
Organomet. Chem., 1994, 480, 199-203.
202
C. Eaborn, P. D. Lickiss and A. D. Taylor .Anchimeric assistance by the acetoxy group in
solvolysis of the compounds (Me3)2C(SiMe2OCOMe)(SiMe2X), X = Cl, NCS, or N3 .J.
Chem. Soc., Perkin Trans 2, 1994, 1089-1813.
203 C. Eaborn, P. B. Hitchcock, K. Izod and J. D. Smith. A monomeric solvent-free bent
lanthanide dialkyl and a lanthanide analogue of a Grignard reagent. Crystal structures of
Yb{C(SiMe3)3}2 and [Yb{C(SiMe3)3I.OH4]2 .J. Am. Chem. Soc., 1994, 116, 12071-12072.
151 C. Eaborn, I. B. Gorrell, P. B. Hitchcock, J. D. Smith and K. Tavakkoli. Preparation of new
lithium organotrihydroaluminates: crystal structure of {(C4H8O)2Li(µH)2AlH[C(SiMe2Ph)3]}2. Organometallics. 1994, 13, 4143-4144.
152 S. S. Al-Juaid, A. A. K. Al-Nasr, G. A. Ayoko, C. Eaborn and P. B. Hitchcock. The
geometry of SiOCN and SiNCO linkages. The crystal structures of
(Me3Si)2(Ph2MeSi)CSiMe2OCN and (PhMe2Si)3CSiMe2NCO. J. Organomet. Chem., 1995,
488, 155-160.
153 P. T. Brain, M. Mehta, D. W. H. Rankin, H. E. Robertson, C. Eaborn, J. D. Smith and A. D.
Webb. Determination by electron diffraction of the molecular structures of chloro- and
bromo-tris(trimethylsilyl)methane in the gas phase. J. Chem. Soc., Dalton Trans., 1995, 349354.
201
A. I. Almansour and C. Eaborn. Preparation of (iPrMe2Si)3CH and its use as a source of the
bulky ligand (iPrMe2Si)3C. J. Organomet.Chem., 1995, 489, 181-183.
202 A. I. Almansour, J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer .Predominance
of unrearranged products in the reactions of the iodide.(Me3Si)3C(CD3)2I with silver salts, and
its mechanistic implications. J. Chem. Soc., Perkin Trans. 2, 1995, 705-706.
156 P. T. Brain, M. Mehta, D. W. H. Rankin, H. E. Robertson, C. Eaborn, J. D. Smith and A. D.
Webb. Determination by electron diffraction of the molecular structure of
bromotris(methoxydimethylsilyl)methanein the gas phase. J. Chem. Soc., Dalton Trans.,
1995, 975-978.
157 M. A. M. R. Al-Guarashi, G. A. Ayoko, C. Eaborn and P. D. Lickiss.
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Rates of solvolysis of the compounds (Me3)2(Ph2MeSi)CSiMe2X, X = I, OSO2CF3 and
OCN. Mechanistic implications. J. Organomet. Chem., 1995, 499, 57-62.
158 (a) C. Eaborn, P. B. Hitchcock, K. Izod and J. D. Smith, Synthesis and structure of
RbC(SiMe3)3 and CsC(SiMe3)3.3.5C6H6: a one-dimensional ionic and a molecular
festkorper. Angew. Chem. Int. Ed. Engl., 1995, 14, 687-688. (b) Synthesen und Struckturen
von RbC(SiMe3)3 and CsC(SiMe3)3.3.5C6H6: Ein eindimensionaler ionischer und ein
molekular Festkörper, Angew. Chem., 1995, 107, 756-757.
159 M. A. M. R. Al-Gurashi, G, A. Ayoko, C. Eaborn and P. D. Lickiss, Anchimeric assistance
in the reactions of the crowded organosilicon iodide (Me3Si)2(Ph2MeSi)CSiMe2I with
electrophiles. Bull Soc. Chim. Fr., 1995, 132, 517-521.
160 C. Eaborn and J. D. Smith, Synthesis, structure and reactions of organometallic compounds
of Groups 1-3 containing bulky silicon-substituted alkyl groups, J. Organomet. Chem., 1995,
500, 89-99.
161 C. Eaborn, K. Izod, P. B. Hitchcock, S. E. Sözerli and J. D. Smith, The first
monorganolead(II) derivative, [{Pb(µ-Cl)}2] where R = C(SiMe2Ph)3. J. Chem. Soc., Chem.
Commun., 1995, 1829-1830.
162 G. A. Ayoko, C. Eaborn and P. B. Hitchcock, Geometry of the SiOCN Linkage. Crystal
Structure of (Me3Si)2(PhMe2Si)CSiMe2OCN, .Organometallics, 1995, 14, 4960-4961.
163 C. Eaborn, K. Izod, P.B. Hitchcock, and J.D. Smith, Two diorganopotassates: Crystal
stucture of [K(C6H6)][K{C(SiMe3)2(SiMe2Ph)}2. Angew. Chem. Int. Ed. Engl, 1995, 34,
2679-2890.
164 S. S. Al-Juaid, C. Eaborn, P. D. Lickiss, J. D. Smith, K. Tavakkoli, and A. D. Webb,
Preparation, spectroscopic properties, and thermal stabilities of organomercury compounds
containing the bulky ligand (Me3Si)3C or (PhMe2Si)3C. J. Organomet. Chem., 1996, 510,
143-151.
165 A.G. Davies, C. Eaborn, P.D. Lickiss and A.G. Neville, EPR spectra of
tris(trimethylsilyl)methyl(hydroxy)silyl radicals, (Me3Si)3SiROH., and
tris(trimethylsilyl)methylsilanone radical anions (Me3Si)3SiR=O.- (R = H, Me, Et, Bu, Ph, F).
J. Chem. Soc., Perkin Trans. 2, 1996, 163-169.
166 F. Adam, C. Eaborn, P. B. Hitchcock, and J.D. Smith. The novel linear-polymeric
organolithium compound {(Me2NMe2Si)3CLi}n. J. Chem. Soc., Chem. Commun., 1996,
741-742.
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167 C. Eaborn, Z.-R. Lu, P. B. Hitchcock, and J. D. Smith. The novel chelated diorganolithate
ion [CH2SiMe2C(SiMe3)2LiC(SiMe3)2SiMe2CH2]– and the highly crowded chelated
organomercury compound [CH2SiMe2C(SiMe3)2HgC(SiMe3)2SiMe2CH2]. Organometallics.
1996, 15, 1651-1655.
168 A.I. Almansour, G. A. Ayoko and C. Eaborn. The mechanism of the isomerization of
organosilicon cyanates to isocyanates. J. Organomet. Chem., 1996, 514, 277-280.
169 C. Eaborn and J. D. Smith. Compounds of elements of Groups 11-13 containing (Me3Si)3C,
(PhMe2Si)3C, or related ligands. Coord. Chem. Rev., 1996, 154, 125-149.
170 D. A. Antonov, C. Eaborn, J. D Smith, P. B. Hitchcock, E. Molla, V. I. Rozenberg, W. A.
Stancyk, and A. Kowaleska. A bulky tris(trisilylmethyl) ligand incorporating a donor sulfur
atom. Some (Me3Si)2(PhSMe2Si)CSnMe2X compounds. J. Organomet. Chem., 1996, 521,
109-112.
171 C. Eaborn, P.B. Hitchcock, A. Kowalewska, Z.-R. Lu, J.D. Smith and W.A. Stanczyk.
Iodo(methoxydimethylsilyl)bis(trimethylsilylmethane:a reagent for the preparation of novel
organometallic compounds. Crystal structures of Mg{C(SiMe3)2(SiMe2OMe)}2 and
MgI2(OH4)2. J. Organomet. Chem., 1996, 521, 113-120.
172 A.G. Avent, W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock and J.D. Smith.
Organotrialkoxy- and Organotrifluoroaluminates. Crystal structures of
Li[(Me3Si)3CAlX3].OC4H8 (X = OBut, F). Organometallics, 1996, 15, 4343-4345.
173 C. Eaborn, P.B. Hitchcock, K. Izod, Z.-R. Lu and J.D. Smith. Alkyl derivatives of
europium(+2) and ytterbium(+2). Crystal structures of Eu{C(SiMe3)3}2,
Yb{CC(SiMe3)2(SiMe2CH=CH2)}I.OH4 and Yb{CC(SiMe3)2(SiMe2OMe)}I.OH4.
Organometallics, 1996, 15 4783-4790.
A. I. Almansour, H. A. Abubishait, and C. Eaborn. 1,3-Si-toSi migration of a methyl group. Ratio
of rearranged and unrearranged products in the reactions of the iodide (Me3Si)3C(Si(CD3)2I
with ICl. J. Organomet. Chem., 1997, 531, 171-174.
175 C. Eaborn, Adam Farook, P.B. Hitchcock, and J.D. Smith.
Tris{dimethylamino)dimethylsilyl}methylmagnesium iodide. A Grignard reagent without a
carbon-magnesium bond? Organometallics, 1997, 16. 503-504.
176 Organometallic Compounds of the alkali metals with phenylsilyl substituents at the
carbanionic center. Crystal structure of LiC(SiMe3)2(SiMe2Ph).Et2O,
Na(SiMe3)2(SiMe2Ph).TMEDA, Na(SiMe3)(SiMe2Ph)2.TMEDA, {LiCH(SiMe2Ph)2}2,
RbC(SiMe2Ph)2}3, CsC(SiMe2Ph)2}3, (TMEDA = tetramethylethylenediamine). C. Eaborn,
W. Clegg, P. B. Hitchcock, M Hopman, K. Izod, P. N. O’Shaughnessy and J. D. Smith,
Organometallics, 1997, 16, 4728-4736.
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177 C. Eaborn, S. A Hawkes, P. B. Hitchcock and J. D. Smith. The first structurally characterised
solvent-free -bonded diorganocalcium, Ca[C(SiMe3)3]2. Chem. Communs., 1997, 19611962.
178 C. Eaborn, Adam Farook, P. B. Hitchcock and J. D. Smith. catena-Poly[[(1,4-dioxaneO1)iodolithium]--(1,4-dioxane-O1:O4)], Acta Cryst. Sect.C, 1997, 1387-1388.
179 J. R. Black, C. Eaborn, P. M. Garrity and D. A. R. Happer. The proportion of 1,3-migration
of a methyl group in the reactions of the iodide (Me3Si)3C(Si(CD3)2I with silver salts in
alcohols. Mechanistic implications. J. Chem. Soc., Perkin Trans. 2, 1997, 1633-1639.
180 C. Eaborn, T. Ganicz, P. B. Hitchcock, J. D. Smith, and S. E. Sözerli. Novel
Organolead(II) Species, the Plumbacycloalkane Derivative
[CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2CH2. Organometallics, 1997, 16, 5621-5622.
201 C. Eaborn, P. B. Hitchcock, J. D. Smith, and S. E. Sözerli. Synthesis and crystal structures of
the compounds [Sn{C(SiMe2Ph)3}Cl]2, [Pb{C(SiMe3)3}Cl]3 and
[M{C(SiMe3)2(SiMe2OMe)}Cl]2, M = Sn or Pb. Organometallics, 1997, 16, 5653-5658.
182 A. I. Almansour, C. Eaborn, S. A Hawkes, P. B. Hitchcock and J. D. Smith. An alkyllithium
compound with a free planar carbanion. The crystal structure of
[Li(THF)4][(C(SiMe2C6H4Me-o)3]. Organometallics, 1997, 16, 6035-6037.
183 W.-Y. Chen, C. Eaborn, I. B. Gorrell, P.B. Hitchcock, M. Hopman, and J.D. Smith. Lithium
trialkoxyo[tris(trimethylsilyl)methyl]aluminates, analogues of intermediates in reductions of
carbonyl compounds. Crystal structures of [Li(thf)2][AlR(OEt)3] and
{Li[AlR(OPri)2(OH))]}2, R = C(SiMe3)3 and thf = tetrahydrofuran. J. Chem. Soc., Dalton
Trans., 1997, 4689-4693.
184 W Clegg,., C Eaborn,., K Izod, P. N O’Shaughnessy and J. D. Smith. The first structurally
authenticated alkyl compound of samarium(II) and its reaction with benzophenone. Crystal
structures of {(Me3Si)2(Me2MeOSi)C}2Sm(THF) and {(Me3Si)2(Me2MeOSi)C}2Sm(OCPh2).
Angew. Chem. Int. Ed Engl.1997, 36, 2815-2817.
185 A novel molecular species incorporating a cyclic organolithate anion and a
disiloxane-solvated lithium cation. C. Eaborn, S. M. El-Hamruni, P. B. Hitchcock and J. D.
Smith. Chem. Commun., 1998, 1277-1278.
186 C. Eaborn, A. Farook, P. B. Hitchcock, and J. D. Smith A novel zwitterionic species
containing an Al(III) cation and a planar carbanion. Crystal structure of
[Et3AlNMe2SiMe2C(SiMe2NMe2)2AlEt2]C6H6 . Organometallics, 1998, 17, 3135.
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187 C. Eaborn, J. D. Smith, P. B. Hitchcock and S. E. Sözerli Crystal Structure of the
1,3-Disilacyclobutane Derivative (Me3Si)2CSiMe2C(SiMe3)2SiMe2. J. Chem Res.(S). 1998, 566567.
188 S. S.Al-Juaid, C. Eaborn, I. B. Gorrell, S. A. Hawkes, P. B. Hitchcock, and J. D. Smith.
Reactions of the alkylhydroaluminate {Li(thf)2[AlH3C(SiMe3)3]}2.Crystal structures of
[Li(tmen)2] [AlH3C(SiMe3)3], [AlBr2C(SiMe3)3.thf] [AlI2C(SiMe3)3.thf], [Li(thf)2(NHPh)2AlHC(SiMe3)3] and [Li(thf)4][Al(NHPh)3C(SiMe3)3] (thf = tetrahydrofuran) J. Chem.
Soc. Dalton Trans., 1998, 2411-2415.
189 S. S. Al-Juaid, C. Eaborn, M. Al-Rawi, P. B. Hitchcock, and J. D. Smith. Organotin
compounds containing a bulky (Me3Si)3C or related ligand. Crystal Structures of
{(Me3Si)3CMe(O2NO)Sn}2O, (PhMe2Si)3CSnMeCl2 and (PhMe2Si)3CSnCl3. J. Organomet.
Chem . 1998, 564, 215-226.
190 C Eaborn, P. B. Hitchcock, J. D. Smith, and S. E. Sözerli. An Unusual
Alkyltrihydroaluminate. Crystal Structures of
[AlH2{C(SiMe3)2(SiMe2OMe)}(-H)Li(THF)], [AlCl2{C(SiMe2OMe)(SiMe3)2}(THF)],
and [Li{C(SiMe2OMe)(SiMe3)2}(THF)2] (THF = tetrahydrofuran). Organometallics, 1998, 17,
4322-4325.
191 C. Eaborn, A. Kowalewska and W. A Stanczyk, 1,3-Migration of a phenyl group in the
conversion of (Me3Si)2(PhMe2Si)CSiMePhX into (Me3Si)2(Ph2MeSi)CSiMe2X species, J.
Organomet. Chem., 1998, 560, 41-46.
192 S. S. Al-Juaid, C. Eaborn, S.M. El-Hamruni, P. B. Hitchcock and J. D. Smith. Attachment of
the New Bulky Ligand (Me3Si)2(Me2NMe2Si)C to Li, Hg, Al, Ga and Sn. Crystal Structures
of [Li{C(SiMe3)2(SiMe2NMe2)}(THF)2], [Hg{C(SiMe3)2(SiMe2NMe2)}2],
[Al{C(SiMe3)2(SiMe2NMe2)}X2], X = Cl or Ph, and [Ga{C(SiMe3)2(SiMe2NMe2)}C12].
Organometallics, 1999, 18, 45-52.
193 C Eaborn, M S Hill, P. B. Hitchcock, J. D. Smith, S Zhang, and T Ganicz. Attachment of the
bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C to K, Zn, Sn, and Yb.
Crystal structures of LnM C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CMLn (MLn = K(C6H6)2,
K(THF)2, SnCl3,or SnMe2Cl) and
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CH2SiMe2C(SiMe3)2Zn C(SiMe3)2 SiMe2CH2 (THF = tetrahydrofuran), Organometallics,
1999, 18, 2342-2348.
194 A G Avent, D Bonafoux, C. Eaborn, S K Gupta, P B Hitchcock, and J D Smith. Reaction of
tris[(diphenylphosphino)dimethtylsilyl]methane with molybdenum hexacarbonyl and
deprotonation to give a salt with a planar carbanion. Crystal structures of (Ph2Me2Si)3CH and
[Li(tmen)2][C(SiMe3)2PPh2)3], tmen = N,N,N'',N''-tetramethylethane-1,2-diamine. J. Chem.
Soc., Dalton Trans., 1999, 831-834.
195 S S Al-Juaid, C Eaborn, S El-Hamruni, A Farook, P B Hitchcock, M Hopman, J D Smith, W
Clegg, K O Izod and P O'Shaughnessy. Tris(triorganosilyl)methyl derivatives of potassium
and lithium bearing dimethylamino or methoxy substituents at silicon Crystal structures of
KC(SiMe3)2(SiMe2NMe2), KC(SiMe2NMe2)3, and [LiC(SiMe3)2(SiMe2OMe)2]2. J. Chem.
Soc., Dalton Trans., 1999, 3267- 3273.
196 C. Eaborn, M. S. Hill, P. B. Hitchcock, D. Patel, J. D. Smith, and S. Zhang. Oxidative
addition to a monmeric stannylene to give four-coordinate tin compounds coataining the
bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal
structures of CH2SiMe2C(SiMe3)2SnC(SiMe3)2 SiMe2CH2,
CH2SiMe2C(SiMe3)2SnMe(OCOCF3)C(SiMe3)2 SiMe2CH2, and
(CF3COO)2MeSnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CSnMeOCOCF3)2.
Organometallics 2000, 19, 49-53.
197 C. Eaborn, S. M. El-Hamruni, M. S. Hill, P. B. Hitchcock, M. Hopman, A.Le Gouic and J.
D. Smith, Synthesis of some bulky alkylalanes and alkyltrihydroaluminates: crystal structures
of [Li(THF)2AlH3C(SiMe3)3}2, (Me3Si)3CAlH2.THF and the pyrazolato derivative
[LiAlH(C3H3N2)2C(SiMe3)3]2 (THF = Tetrahydrofuran). J. Organomet. Chem.2000, 597, 3-9.
198 C. Eaborn, P. B. Hitchcock, J. D. Smith, S. Zhang, W. Clegg, K Izod and P. O’Shaughnessy,
Manganese and cesium derivatives of the bulky bidentate ligand
C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal structures of
Li(THF)2.75(Et2O)0.25(-Cl)MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and
(C6H6)3C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3 Organometallics,2000, 19,
1190-1193.
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199 C. Eaborn, M. S. Hill, P. B. Hitchcock and J. D. Smith,. ‘The first structurally characterised
- bonded organonickel(I) compound. Crystal structures of Ni{C(SiMe3)2(SiMe2C5H4N2}(PPh3)],
[Ni{C(SiMe3)(SiMe2C5H4N-2)(SiMe2O)}]2 and [Pd(-Cl){C(SiMe3)2(SiMe2C5H4N-2)}]2.
Chem. Commun. 2000, 691-692.
200 A. G. Avent, D Bonafoux, C. Eaborn, M. S. Hill, P. B. Hitchcock and J. D. Smith,Crowded
organometallic compounds of the alkali metals with diphenyphosphino substituents in the
organic group. J. Chem. Soc., Dalton Trans., 2000, 2183-2190.
201
Y. Chen, C. Eaborn, I. B. Gorrell, P. B. Hitchcock and J. D. Smith, Syntheses and crystal
structures of some lithium di- and tri-(thiolato)[tris(trimethysilyl)methyl]aluminates. J. Chem.
Soc., Dalton Trans., 2000, 2313 -2317.
202 C. Eaborn, M. S. Hill, P. B. Hitchcock and J. D. Smith. Structural diversity in organolithium,
-sodium, and –potassium cyanocuprates. Organometallics, 2000, 19, 5780.