SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 1 of 8
Revision No: 2
Dated: MARCH 2011
Durastic Limited, Unit 47, Cuthbert Court, Bede Estate, Jarrow, Tyne & Wear, NE32 3HG
Telephone: (0191) 483 2299 Fax: (0191) 483 2295
THIS DATA SHEET SUMMARISES GENERAL SAFETY INFORMATION FOR THIS MATERIAL OR PRODUCT.
THE SUPPLIERS INFORMATION MUST SET OUT THE CONDITIONS NEEDED TO ENSURE THAT THE
SUBSTANCE IS SAFE, AND WITHOUT RISK TO HEALTH WHEN BEING USED, HANDLED, PROCESSED,
STORED AND TRANSPORTED, AND ON DISPOSAL. THIS DATA SHEET IS ISSUED FOR YOUR OWN
SAFETY, AND FOR THE SAFETY OF THOSE WHO WORK AROUND YOU. YOU MUST READ AND
UNDERSTAND IT.
IF IN DOUBT, REFER TO YOUR CONTRACTS MANAGER AND/OR TECHNICAL MANAGER.
2.
1. IDENTIFICATION OF SUBSTANCE/PREPARATION AND COMPANY
Product Name:
Description:
Chemical Nature:
Supplier:
Address:
Contact for Further Information:
Durastic Ltd Large FR Hardener
Hardener part of a two pack system
Aliphatic polyamine preparation
Durastic Limited
Unit 47, Cuthbert Court, Jarrow, Tyne & Wear,
NE32 3HG
John English - Technical Manager
Tel: 0191 483 22 99
Fax: 0191 483 22 95
E-mail: john.english@durastic.co.uk
HAZARD IDENTIFICATION
Causes burns. Harmful in contact with skin and if swallowed. May cause sensitization by skin.

5.
4.
3.
SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 2 of 8
Revision No: 2
Dated: MARCH 2011
COMPOSITION/INFORMATION ON INGREDIENTS
Contains
Polyoxypropyleneamine
Triethylenetetramine
Salicylic acid
%
70-82
12-20
2
– 8
CAS
39423-51-3
112-24-3
69-72-7
EEC Symbol R phrases
C
C
34-21/22-43
34-21-43
52/53
Xn R20/22 R41
FIRST AID MEASURES
Eye Contact:
Skin Contact:
Ingestion:
Inhalation:
Rinse immediately with water for at least 15 minutes and seek medical attention immediately.
Wash off with plenty of soap and water. Do not use organic solvents. In case of dermatitis get medical attention.
Immediately give plenty of water (if possible charcoal slurry). If a person vomits when lying on their back, place in the recovery position. Oxygen or artificial respiration if needed. Do not induce vomiting. Seek medical attention promptly.
Move affected person to fresh air. In case of irritation of respiratory system or mucous membranes, or if you feel unwell or in case of prolonged exposure, get medical attention.
FIREFIGHTING MEASURES
Suitable Extinguishing
Media:
Water spray, carbon dioxide (CO2); foam; dry powder.
Unsuitable Extinguishing
Media:
High pressure water jet.
Exposure hazards:
Protective equipment:
Further information
Thermal decomposition or burning, may release oxides of carbon, nitrogen and the other toxic gases and vapors. Do not release chemically contaminated water into drains, soil or surface water. Sufficient measures must be taken to retain water used for extinguishing. Dispose of contaminated water and soil according to local regulations.
Use full protective clothing and self-contained breathing apparatus.
See further information on Huntsman material safety data sheet.

SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 3 of 8
Revision No: 2
Dated: MARCH 2011
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Environmental Precautions:
Methods for Cleaning:
Do not breathe vapor/dust. Avoid ignition sources – No smoking. Avoid contact with skin, eyes and clothing.
Prevent contamination of soil, drains and surface waters.
Take up with absorbent, inert material and place in a hazardous waste container for disposal.
7. HANDLING AND STORAGE
Handling:
Advice on safe handling:
Storage:
Provide sufficient air exchange and/or exhaust in work rooms. Avoid formation of aerosol.
Ensure adequate ventilation. Handle and open container with care.
Keep away from food and drink and animal feeding stuffs. Store in the original container securely closed and at room temperature.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection:
Personal protective equipment
In case of insufficient ventilation wear suitable respiratory equipment.
Wear suitable gloves, e.g. nitrile
Wear suitable goggles or face protection
Wear protective overalls and closed safety footwear

9.
10.
SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 4 of 8
Revision No: 2
Dated: MARCH 2011
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odour:
Density:
Flashpoint:
Ignition: pH value:
Viscosity, dynamic:
Water solubility:
Boiling point/range:
Oxidizing properties:
Autoflammability:
Solubility in water:
Vapour pressure:
Partition:coeff:
Thermal decomposition:
STABILITY AND REACTIVITY
Conditions to avoid:
Hazardous Decomposition
Products:
Materials to avoid:
Clear light brown liquid
Yes, amine-like
0.99 - 1.005 Mg/m³
> 150
ºC Method: DDIN 51758 (Pensky-Martens closed cup)
Not available
11 at (20
ºC) 1:1 in water
160 – 200 mPa.s at 25ºC
At 20
ºC Note: party miscible
>200 ºC
Not available
Not available
Not available
< 100 Pa at 20 ºC
Not available
>200 ºC
Static discharges
Thermal decomposition or burning may release oxides of carbon and other toxic gases or vapours
Strong acids, strong bases and strong oxidizing agents. Carbon oxides. Nitrogen oxides.

SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 5 of 8
Revision No: 2
Dated: MARCH 2011
TOXICOLOGICAL INFORMATION 11.
12.
LD50 Acute oral toxicity in rats:
Eye irritation tested in rabbits:
>Approx. 265 mg/kg
Corrosive, Rabbit
Skin irritation tested in rabbits: Corrosive, Rabbit, dermal.
Skin sensitization in guinea pigs: May cause sensitization by skin contact. Sensitizing guinea pig
ECOLOGICAL INFORMATION
13.
Ecotoxicity effects
Further ecological information:
Avoid subsoil penetration. Prevent product from entering drains. Do not contaminate surface water.
DISPOSAL CONSIDERATION
Product:
Container:
Waste key Number: 070204
Must be incinerated, when in compliance with local regulations.
Empty containers can be land filled after cleaning, when in compliance with the
Environmental Protection (Duty of care) Regulations 1991.

RID
SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 6 of 8
Revision No: 2
Dated: MARCH 2011
14. TRANSPORT INFORMATION
Land Transport
ADR UN-No:
Class:
Classification Code:
Packaging Group
Risk No:
ADR/RID-Labels;
Proper Shipping Name:
Sea Transport
IMDG
Air Transport
IATA-DGR
UN-No:
Class:
Packaging Group:
Risk No:
ADR/RID-Labels:
Proper Shipping Name:
UN-No:
Class:
Packaging Group:
ADR/RID –Labels
MFAG:
EmS:
Proper Shipping Name:
UN/ID No:
Class:
Packaging Group
Packing instruction (cargo aircraft)
Max.Qty/Pack:
999.0=No limit)
Packing Instruction
(passenger aircraft)
Max.Qty/Pack:
(999.00=No limit)
ADR/RID-Labels:
Proper Shipping name:
3267
8
C7
III
80
8
CORROSIVE LIQUID,
BASIC,ORGANIC,N.O.S.
ALIPHATIC POLYAMINE
3267
8
III
80
8
CORROSIVE LIQUID,
BASIC,ORGANIC,N.O.S.
ALIPHATIC POLYAMINE
3267
8
III
8
F-A-S-B
CORROSIVE LIQUID,
BASIC,ORGANIC,N.O.S.
(ALIPHATIC POLYAMINE)
3267
8
III
820
60.00 L
818
5.00 L
8
CORROSIVE LIQUID,
BASIC,ORGANIC,N.O.S.
(ALIPHATIC POLYAMINE)

15.
SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 7 of 8
Revision No: 2
Dated: MARCH 2011
REGULATORY INFORMATION
EC Labelling as required in UK.
Symbol:
R34:
R21/22:
R43:
S26:
S36/37/39:
Hazardous components which must be list on the label:
C. Corrosive
Causes burns
Harmful in contact with skin and if swallowed
May cause sensitization by skin contact
In case of contact with eyes, rinse immediately for at least 15 minutes and seek medical attention.
Wear suitable gloves, protective clothing and eye/face protection
Polyoxypropylene triamine
Triethylenetetramine
EC-No.:203-950-6

SAFETY DATA SHEET
Product Name: Durastic Large FR Hardener
Sheet No: 8 of 8
Revision No: 2
Dated: MARCH 2011
16. OTHER INFORMATION
List of R-phrases (Section 3)
R20/22
R21
R21/22
R34
R41
R43
R52/53
Harmful by inhalation and if swallowed.
Harmful in contact with skin.
Harmful in contact with skin and if swallowed.
Causes burns.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Product use: S405 FR Hardener is used with epoxy resins.
The provision of Safety Data Sheets comes under Regulation 6 of CHIP* This is an addition to the Health and
Safety at Work etc. 1974 (HWSA)
Users of products supplied by Durastic Ltd. should take appropriate measures to ensure working practices are in accordance with the Control of Substances Hazardous to Health Regulations (COSHH)
CHIP* is the recognized abbreviation for the Chemicals (Hazard Information and Packaging) Regulations 1994.