POX-CIL process optimization for refractory gold

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POX-CIL process optimization for refractory gold-bearing concentrates
processing
Boldyrev A.V., Balikov S.V., Gudkov S.S., Bogorodskiy A.V., Emelyanov Yu.E.
OJSC Irgiredmet, Irkutsk, Russia, e-mail: ianayko@gmail.com
Currently, pressure oxidation (POX) is used for decomposing of sulphides locking fine-grained
gold and considered as a pretreatment step followed by a subsequent gold recovery using
cyanidation.
The studies were conducted on precious metal leaching with halogen solvents and solvent
precipitation onto an adsorbent directly during POX treatment of refractory gold-bearing
concentrates.
The research of an optimal halogen solvent showed, that the best possible solvent for POX-CIL
treatment of refractory gold-bearing concentrates was sodium chloride.
A series of tests were carried out in order to optimize POX-CIL treatment of a flotation concentrate,
which was produced during primary ores processing at a large deposit in the Amur region, with the
addition sodium chloride and activated carbon.
It was found, that the sufficient sodium chloride concentration for gold leaching was 5 g/L.
The major factor impacted on gold recovery completeness was the degree of sulphides oxidation.
POX-CIL treatment of the flotation concentrate with different activated carbon loadings
demonstrated, that the amount of the adsorbent should be not less than 6% of the concentrate mass.
The decrease in the activated carbon amount resulted in a decrease of gold and silver recovery.
The rates of sulphides oxidation in different tests were 67.7-99.8%. The maximum gold recovery
was 98.6%.The POX-CIL process is protected by patent №017438 of the Eurasian Patent
Organization – A method of precious metal and sulphide-bearing material processing.
KEYWORDS
Pressure Oxidation, Refractory Gold-Bearing Concentrates, Sulphides Oxidation, Gold Recovery,
Solvent
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