2022-09-25T04:42:40+03:00[Europe/Moscow] en true <p>from alkene to poly-alkene</p>, <p>from alkene to di-halogenoalkane </p>, <p>from alkene to alcohol</p>, <p>from alkene to alkane</p>, <p>from alkene to diol</p>, <p>from di-halogenoalkane to diol</p>, <p>from alkane to halogenoalkane</p>, <p>from alkene to halogenoalkane</p>, <p>from halogenoalkane to nitrile</p>, <p>from halogenoalkane to amine</p>, <p>from halogenoalkane to alcohol</p>, <p>from halogenoalkane to alkene</p>, <p>from alcohol to alkene </p>, <p>from alcohol to halogenoalkane</p>, <p>from alcohol (primary) to aldehyde</p>, <p>from alcohol (secondary) to ketone</p>, <p>from alcohol to ester</p>, <p>esters and amides can be hydrolysed by</p>, <p>from nitrile to carboxylic acid</p>, <p>from amine to 2nd degree/3rd degree amine</p>, <p>from amine to secondary amide</p>, <p>from nitrile to amine</p>, <p>from aldehyde to carboxylic acid</p>, <p>from aldehyde to alcohol</p>, <p>from aldehyde to hydroxynitrile</p>, <p>from ketone to hydroxynitrile</p>, <p>from ketone to alcohol</p>, <p>from carboxylic acid to acyl chloride</p>, <p>from carboxylic acid to ester</p>, <p>from carboxylic acid to alcohol</p>, <p>from acyl chloride to carboxylic acid</p>, <p>from acyl chloride to ester</p>, <p>from acyl chloride to secondary amide</p>, <p>from acyl chloride to primary amide</p>, <p>from primary amide to amine</p> flashcards
Organic Synthesis

Organic Synthesis

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  • from alkene to poly-alkene

    high pressure

    catalyst

    (polymerization)

  • from alkene to di-halogenoalkane

    Br2,Cl2

    room temp

    (electrophilic addition)

  • from alkene to alcohol

    H2O (g)

    catalyst ; conc. H3PO4

  • from alkene to alkane

    H2

    catalyst ; nickel

    (addition/reduction)

  • from alkene to diol

    KMnO4

    (oxidation)

  • from di-halogenoalkane to diol

    aqueous KOH

    heat under reflux

    (nucleophilic substitution)

  • from alkane to halogenoalkane

    Br2, Cl2

    UV light

    (free radical substitution)

  • from alkene to halogenoalkane

    HBr, HCl

    room temp

    electrophilic addition

  • from halogenoalkane to nitrile

    CN- and ethanol

    (nucleophilic substitution)

  • from halogenoalkane to amine

    alcoholic NH3

    heat under pressure

    (nucleophilic substitution)

  • from halogenoalkane to alcohol

    aqueous KOH

    heat under reflux

    (nucleophilic substitution)

  • from halogenoalkane to alkene

    alcoholic KOH

    heat under reflux

    (elimination)

  • from alcohol to alkene

    conc. H3PO4

    elimination

    (dehydration)

  • from alcohol to halogenoalkane

    PCl5, NaBr/H2SO4, P + I2

    heat under reflux

    (substitution)

  • from alcohol (primary) to aldehyde

    acidified K2Cr2O7

    heat gently

    distill partial oxidation

  • from alcohol (secondary) to ketone

    acidified K2Cr2O7

    heat under reflux

    (oxidation)

  • from alcohol to ester

    carboxylic acid + H2SO4

    heat

    esterification

  • esters and amides can be hydrolysed by

    NaOH and Acids

  • from nitrile to carboxylic acid

    heat with HCl

    (acid hydrolysis)

  • from amine to 2nd degree/3rd degree amine

    halogenoalkane

    (nucleophilic substitution)

  • from amine to secondary amide

    acyl chloride

    room temp

    (nucleophilic addition/ elimination)

  • from nitrile to amine

    LiAlH4

    (reduction)

  • from aldehyde to carboxylic acid

    excess acidified K2Cr2O7

    heat under reflux

    (oxidation)

  • from aldehyde to alcohol

    LiAlH4

    (Reduction)

  • from aldehyde to hydroxynitrile

    HCN + KCN

    (nucleophilic substitution)

  • from ketone to hydroxynitrile

    HCN +KCN

    (nucleophilic addition)

  • from ketone to alcohol

    LiAlH4

    (reduction)

  • from carboxylic acid to acyl chloride

    PCl5

  • from carboxylic acid to ester

    alcohol + H2SO4

    heat

    esterification

  • from carboxylic acid to alcohol

    LiAlH4

    (reduction)

  • from acyl chloride to carboxylic acid

    H2O

    room temp

  • from acyl chloride to ester

    alcohol

    room temp

  • from acyl chloride to secondary amide

    1st degree amine

    room temp

  • from acyl chloride to primary amide

    NH3

    Room temp

  • from primary amide to amine

    LiAlH4

    (reduction)