2021-05-17T16:36:57+03:00[Europe/Moscow] zh true alkene + h2o + acid, alkene/alkyne + x2, alkene + x2 + h2o, alkene + 1. hg(OAc)2, h2o 2. nabh4, alkene/alkyne + 1. bh3 2. h2o2, naoh, alkene + 1. OsO4 + h2o2 2. NaHSo3, h2o OR hio4 OR cold mno4-, h2o, ph 8>, hio4, alkene + 1. o3, 2. Me2S, alkene/alkyne + h2 + tr metal catalyst, alkene + 1. o3, 2. h2o2 OR kmno4/warm, alkyne + nanh2 , dibromo/chloroalkane + 1. 3NaNH3 2. H2O, alkene/alkyne + hx, alkyne + h2o + acid (h2so4) + hg(ii) salt, alkyne + 1. bh3 2. acetic acid, alkyne + h2 + na/li + nh3(l), tr alkene + 1. mcpba 2. h+/h20 flashcards
organic chemistry

organic chemistry

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  • alkene + h2o + acid
    adds oh group - mark - c+ rearrangement
  • alkene/alkyne + x2
    adds two halogens, alkane or alkene - anti stereo - optional inert solvent - first br makes bridged ion
  • alkene + x2 + h2o
    adds oh and x + en - oh on more stable, x on first - anti stereo
  • alkene + 1. hg(OAc)2, h2o 2. nabh4
    adds oh - no rearrangement - mark - anti stereo - hgoac bridged ion
  • alkene/alkyne + 1. bh3 2. h2o2, naoh
    adds oh (becomes enol --> ketone or aldehyde) - anti mark - syn stereo - no rearrangement
  • alkene + 1. OsO4 + h2o2 2. NaHSo3, h2o OR hio4 OR cold mno4-, h2o, ph 8>, hio4
    adds 2 oh - syn stereo - nasho3 disconnects the os from the two o that got added to form oh
  • alkene + 1. o3, 2. Me2S
    cleaves and oxidizes - not stereo
  • alkene/alkyne + h2 + tr metal catalyst
    makes alkane - not regiosel - syn stereo
  • alkene + 1. o3, 2. h2o2 OR kmno4/warm
    cleaves and fully oxidizes
  • alkyne + nanh2
    alkyne with one free end (c-)
  • dibromo/chloroalkane + 1. 3NaNH3 2. H2O
    alkyne (also allene)
  • alkene/alkyne + hx
    add x - mark (or on the one w an x already)
  • alkyne + h2o + acid (h2so4) + hg(ii) salt
    add oh (tautomer) - mark
  • alkyne + 1. bh3 2. acetic acid
    adds 2h - cis alkene (syn stereo) - 3 moles of reactants for each bh3
  • alkyne + h2 + na/li + nh3(l)
    trans alkene
  • tr alkene + 1. mcpba 2. h+/h20
    add 2 oh - both r groups are on same side