2024-09-16T20:59:16+03:00[Europe/Moscow] en true <p>Amplitude is the ___ and it determines ___</p>, <p>Wavelength is the ___ and it determines ___</p>, <p>Frequency (also velocity) is the ___ and it measures ___</p>, <p><strong>Total energy</strong> of an electromagnetic wave is equal to ___</p>, <p>Characteristics of a low energy wave <strong>(3)</strong></p>, <p>Characteristics of a high energy wave <strong>(3)</strong></p>, <p>Speed of light constant <strong>(c)</strong></p>, <p>Planck's constant <strong>(h)</strong></p>, <p><strong>Wavelength</strong> of light formula </p>, <p><strong>Frequency</strong> of light formula</p>, <p>Energy of a <strong>single photon</strong> formula</p>, <p>Energy of <strong>multiple photons</strong> formula</p>, <p>nm → m</p>, <p>What are the <strong>lowest frequencies</strong> of light <strong>below</strong> visible light</p>, <p>What are the <strong>highest frequencies</strong> of light <strong>above </strong>visible light</p>, <p>On an <strong>emission spectrum</strong>, electromagnetic radiation is ___ by ___ a photon and the electron transitions from a ___ energy level to a ___ one</p>, <p>On an absorption spectrum, electromagnetic radiation is ___ by ___ a photon and the electron transitions from a ___ energy level to a ___ one</p>, <p>What does <strong>quantized </strong>mean <strong>(2)</strong></p>, <p>Energy of a single electron constant <strong>(E)</strong></p>, <p><strong>Energy spectra of a hydrogen atom</strong> formula </p>, <p><strong>Energy of an electron transition in a hydrogen atom</strong> formula</p>, <p>What is an <strong>orbital (</strong>what is it determined by)</p>, <p><strong>Principal quantum number</strong> <strong>(<em>n</em>) </strong>determine the ___ and ___ of the orbital and can only be ___ numbers</p>, <p><strong>Angular momentum quantum number (ℓ)</strong> determines the ___ of the orbital and is equal to ___</p>, <p><strong>Magnetic quantum number (<em>m</em><sub>ℓ</sub>)</strong> specifies the ___ of the orbital and is equal to ___</p>, <p><strong>Spin quantum number (<em>m<sub>s</sub></em>)</strong> specifies the ___ of the electron and represents it as either ___ or ___</p>, <p>Level vs. sublevel of orbitals</p>, <p>s p d f notation of <strong>ℓ quantum numbers</strong></p>, <p>s orbitals have ___ orbitals and ___ electrons</p>, <p>p orbitals have ___ orbitals and ___ electrons</p>, <p>d orbitals have ___ orbitals and ___ electrons</p>, <p>f orbitals have ___ and ___ electrons</p>, <p>Higher energy levels contain orbitals that are ___ from the nucleus, lower energy levels contain orbitals that are ___ to the nucleus </p> flashcards

Chapter 2 - Quantum mechanics of the atom

Electromagnetic spectrum Waves, frequency, and energy Photons and energy Orbitals The shapes of atomic orbitals Atomic quantum numbers

  • Amplitude is the ___ and it determines ___

    - Height of a crest or trough

    - A lights intensity

  • Wavelength is the ___ and it determines ___

    - Distance between crests or troughs

    - A lights color

  • Frequency (also velocity) is the ___ and it measures ___

    - Number of waves that pass a point in a give time

    - Wave speed

  • Total energy of an electromagnetic wave is equal to ___

    total energy = the amplitude and frequency of the wave

  • Characteristics of a low energy wave (3)

    - Smaller amplitude

    - Longer waves

    - Lower frequency (longer waves = lower frequency)

  • Characteristics of a high energy wave (3)

    - Larger amplitude

    - Shorter waves

    - Higher frequency (shorter waves = higher frequency)

  • Speed of light constant (c)

    3.00x108 m/s

  • Planck's constant (h)

    6.626x10-34 J · s

  • Wavelength of light formula

    wavelength = speed of light ÷ velocity

  • Frequency of light formula

    Frequency (v) = speed of light ÷ wavelength

  • Energy of a single photon formula

    E = h · v

    - h is Planck's constant

    - v is speed of light ÷ wavelength (frequency formula)

  • Energy of multiple photons formula

    E = n · h · v

    - n is # of photons

    - h is Planck's constant

    - v is speed of light ÷ wavelength (frequency formula)

  • nm → m

    nm → m = multiply by 10-9m

    m → nm = divide by 10-9nm

  • What are the lowest frequencies of light below visible light

    - Radio (lowest)

    - Microwave

    - Infrared

  • What are the highest frequencies of light above visible light

    - Ultraviolet

    - X-ray

    - Gamma ray (highest)

  • On an emission spectrum, electromagnetic radiation is ___ by ___ a photon and the electron transitions from a ___ energy level to a ___ one

    - Electromagnetic radiation EMITTED by releasing a photon

    - Electron transitions from a higher energy level → a lower energy level

    (bright lines on a dark background)

  • On an absorption spectrum, electromagnetic radiation is ___ by ___ a photon and the electron transitions from a ___ energy level to a ___ one

    - Electromagnetic radiation ABSORBED by absorbing a photon

    - Electron transitions from a lower energy level → a higher energy level

    (dark lines on a bright background)

  • What does quantized mean (2)

    - To divide something into small but measurable increments that limit the values or states that it can occupy

    - Allows us to make discrete and measurable values

  • Energy of a single electron constant (E)

    E = - 2.178x10-18

  • Energy spectra of a hydrogen atom formula

    E = - 2.178x10-18 J · n2

  • Energy of an electron transition in a hydrogen atom formula

    E = - 2.178x10-18 J · (1/n2f - 1/n2i)

    - f is final energy state

    - i is initial energy state

  • What is an orbital (what is it determined by)

    - A probability distribution map of where an electron is likely to be found

    - Is determined by a set of quantum numbers

  • Principal quantum number (n) determine the ___ and ___ of the orbital and can only be ___ numbers

    - The size and energy of the orbital

    - Can only be in integers

  • Angular momentum quantum number (ℓ) determines the ___ of the orbital and is equal to ___

    - The shape of the orbital

    - Is = (n - ℓ)

  • Magnetic quantum number (m) specifies the ___ of the orbital and is equal to ___

    - The orientation of the orbital compared to other orbitals

    - Is = -ℓ...0...ℓ+ (all integers in-between)

  • Spin quantum number (ms) specifies the ___ of the electron and represents it as either ___ or ___

    - The orientation of the spin of the electron

    - (+1/2) = spin up

    - (-1/2) = spin down

  • Level vs. sublevel of orbitals

    Level (n) = refers to the total # of energy levels within an atom (contains all orbitals)

    Sublevel (s p d f) = Divides up each n level into s p d f levels (only refers to the orbitals within a single n level)

  • s p d f notation of ℓ quantum numbers

    - ℓ = 0 → s

    - ℓ = 1 → p

    - ℓ = 2 → d

    - ℓ = 3 → f

  • s orbitals have ___ orbitals and ___ electrons

    - 1 orbital

    - 2 electrons

  • p orbitals have ___ orbitals and ___ electrons

    - 3 orbitals

    - 6 electrons

  • d orbitals have ___ orbitals and ___ electrons

    - 5 orbitals

    - 10 electrons

  • f orbitals have ___ and ___ electrons

    - 7 orbitals

    - 14 electrons

  • Higher energy levels contain orbitals that are ___ from the nucleus, lower energy levels contain orbitals that are ___ to the nucleus

    higher energy levels = further away orbitals

    lower energy levels = closer orbitals