The Periodic Law

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Chapter14: Periodic Trends
Modern Chemistry; Holt, Rinehart, & Winston
Dmitri Mendeleev (1834-1907)



Russian chemist
Arranged his periodic table
according to atomic mass so that
elements with similar properties
were in the same group
Predicted the properties of
elements that had not yet been
discovered using his periodic table
Henry Moseley (1887-1915)


English chemist
Proved Mendeleev’s
arrangement of the periodic
table to be correct – only, the
periodic table was arranged
according to atomic number,
not atomic mass
The Periodic Law

States that when elements are arranged
in order of increasing atomic number,
their physical and chemical properties
show a periodic pattern
Atomic Radii

Atomic radius – the distance between
the center of the nucleus and the outer
most energy level
Atomic Radius
Distance between nuclei
Atomic Radius

Decreases across a row
Group Trends

Increase down a group
Which element has a larger
atomic radius?
Na or K?
Al or Cl?
K
Al
F or Sn?
Fr or O?
Sn
Fr
Ionization Energy

The energy required to remove one
electron from a neutral atom of an
element creating an ion
Ionization Energy

Increase across a period
Group Trends

Decrease down the group
Which element has a
greater ionization energy?
Ca or Br?
C or Ge?
Br
C
Ba or Cl?
Br or Pb?
Cl
Br
Electronegativity


A measure of the ability of an atom in a
chemical compound to attract a
bonding pair of electrons
A MEASURE OF GREEDINESS!
Electronegativity

Increase across a period

Decrease down a group

EXCEPTIONS: NOBLE GAS (GROUP 18).
They do not have an electronegativity
value because they do not form
chemical compounds.
Which element has a greater
electronegativity?
Mg and Ba?
Zn or Br?
Mg
Br
Xe or I?
Ge or Ne?
I
Ge
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