Key Learning: The number of valence electrons in an atom dictates its location on the periodic table as well as its chemical and physical properties. UEQ: What is the relationship between an elements location on the periodic table and its chemical and physical properties? Concept: Introduction to the Periodic Table Concept: Periodic Table and Electron Configuration UEQ: What is the relationship between an elements location on the periodic table and its chemical and physical properties? Concept: Introduction to Periodic Table Vocabulary: Non-metal Group/Family Halogens Period Noble Gas Metal Alkali Metals Metalloid Alkaline Earth Metals Transition Metal Lanthanide Actinide Concept: Introduction to Periodic Table LEQ: What is the general organization of the periodic table and how was it developed? Mendeleev “Father of Periodic Table” organized elements based on increasing atomic mass. Found similarities in chemical properties and published his first periodic table in 1869. Concept: Introduction to Periodic Table LEQ: What is the general organization of the periodic table and how was it developed? Moseley discovered while working with elements that they fit better into pattern when arranged by nuclear charge (number of protons-also known as atomic number). Concept: Introduction to Periodic Table LEQ: What is the general organization of the periodic table and how was it developed? Periodic Law states that physical and chemical properties of the elements are periodic functions of their atomic numbers. This means that when elements are arranged in order of increasing atomic number, elements with similar properties appear at regular intervals. Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Periods – rows across, horizontal Indicates number of energy levels (Principle Quantum Number) Groups/Families – down, columns 18 Indicate number of e- in outer most energy level (1-2, 13-18 main group elements) Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Metals Groups 1-12 (except H) and under stair-step groups 13 15 Form ionic and metallic bonds Good Conductors of heat and electricity because the outer electrons are not held tightly to the nucleus and move freely Solid at room temperature (except for Hg) Reflects light (luster) Malleable (hammered into sheets) Ductile (stretched/drawn into wires) Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Group 1 (ns1) Alkali metals Soft, silvery (pure state), highly reactive (reacts with O2 and H2O) Do not occur in nature in elemental form Stored in kerosene Lower melting points Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Group 2 (ns2) Alkaline Earth Metals Reactive; but, less than alkali Not found as free elements in nature Bright fireworks, aircraft Harder, denser, and stronger than alkali metals Higher melting points than alkali Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Transition Elements (d block, n-1) Groups 3-12 (elements in transition) Vary in reactivity and can be found as free elements Metal characteristics Form colored compounds Often occur in nature as uncombined elements Hg – mercury – liquid metal Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Inner Transitional Metals (f-block, n-2) ALL are radioactive and unstable Includes lanthanides (atomic number 58- 71) Shiny metals, similar in reactivity to alkaline earth metals and actinides (atomic number 90-103) First 4 are found on earth, the remaining are synthetic Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Nonmetals P block Gases or brittle solids at room temperature Form ionic and covalent bonds Not malleable Not ductile Most do not conduct heat or electricity Generally not shiny All, except H, are found on right of periodic table Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Group 17 “halogens” Most reactive non-metal Interact with alkali metals to form salts 7 electrons in outer energy level Bromine – only liquid nonmetal Group 18 “noble gases” Full outer energy level Relatively un-reactive Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Metalloids P-block Elements along stair-step line (except for Al) Can form ionic and covalent bonds with other elements Can have metallic and nonmetallic properties Semiconductors Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? Practice – looking for group number, period number and name of element [Xe] 6s1 [Kr] 5s2 [Ne] 3s2 3p2 [Ar] 3d104s24p5 [He] 2s22p3 Concept: Introduction to Periodic Table LEQ: How are the elements classified and arranged on the periodic table? BOOK WORK pg. 137 #’s 1 b and c, # 2 Pg. 149 # 2 Pg. 166 #’s 3, 4, 8, 9, 11-16a, 17-19 a-d UEQ: What is the relationship between an elements location on the periodic table and its chemical and physical properties? UEQ: What is the relationship between an elements location on the periodic table and its chemical and physical properties? Concept: Periodic Table and Electron Configuration Vocabulary Ion Cation Anion Valence electron Lewis-Dot structure Concept: Periodic Table and Electron Configuration LEQ: How do we relate the location of an element on the periodic table to its electron configuration? Group 1 = ns1 Group 2 = ns2 Groups 13-18 = np1-6 Groups 3-12 = n-1 (d)1-10 Lanthanides (period 6) and Actinide (period7) n-2 (f)1-14 Concept: Periodic Table and Electron Configuration LEQ: How does an elements location on the periodic table relate to its valence electrons? Valence Electrons The electrons in the outer most energy level that are available to chemically react Correlates to the group number for main group elements Groups 13-18 – subtract 10 from group number to get the number of valence electrons Concept: Periodic Table and Electron Configuration LEQ: How does an elements location on the periodic table relate to its valence electrons? Energy levels correlate to periods. Each energy level needs to have 8 electrons to make that level complete and stable (with exception to period 1) Period 1 = up to 2 electrons Period 2 = up to 8 electrons Period 3 = up to 18 electrons Period 4 = up to 32 electrons Concept: Periodic Table and Electron Configuration LEQ: How does an elements location on the periodic table relate to its valence electrons? Electron Cloud structure Lewis-Dot structure Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Atomic Radius (Angstrom) ½ the distance from the nuclei to another From the nucleus to edge of e- cloud Going down a group, Atomic radius increases because of the increasing number of energy levels Going across a period, atomic radius decreases because of the increase in positive charge in the nucleus Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Ionization is a process that results in the formation of an ion An ion is an atom or group of atoms that have a “+” or “-” charge Change is created by gain or loss of e Losing an e creates a “+” charge (cation) Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Losing the e- requires energy. Energy required to remove one e- from a neutral atom is called IONIZATION ENERGY (also known as 1st ionization energy) Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Ionization energy decreases as you go down a group because valence electrons are farther from the nucleus And increases as you go across a period because of the greater positive charge leads to greater attraction to electron Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Electron Affinity Gaining an electron results in an ion with a “-” charge (anion) When an atom gains an e- it causes an energy change. The energy change when a neutral atom gains an e- is the ELECTRON AFFINITY Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Electron affinity decreases as you move down a group Increases as you move across a period Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Electronegativity (0-4) Ability of an atom to attract (or remove) an e- from another atom Fluorine is most electronegative (4) Metals have Electronegativity of less than 2 Concept: Periodic Table and Electron Configuration LEQ: How do we use an elements location on the periodic table to determine its ionic charge? Electronegativity decreases as you go down a group because the electrons are farther from the nucleus Electronegativity increases as you go to the right because atoms are more inclined to gain electrons in order to gain a full shell Concept: Periodic Table and Electron Configuration Book Work Pg. 164 #’s 1 and 3 Pg. 167 #’s 22-24c, 25 a, 26 a, 27 a, 28-30 Pg. 168 #’s 40 and 42