Thermodynamic Property Methods

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Ref.1: Brill & Beggs, Two Phase Flow in Pipes, 6 th Edition, 1991.

Chapter 2.

Ref.2: Guo, Lyon & Ghalambor, Petroleum Production Engineering,

Elsevier Science & Technology, 2007, Chapter 1&2.

Introduction

A complete oil or gas production system consists of a reservoir , well , flowline , separators , pumps , and transportation pipelines .

Introduction

A ‘‘ reservoir ’’ is a porous and permeable underground formation containing an individual bank of hydrocarbons confined by impermeable rock or water barriers and is characterized by a single natural pressure system.

Hydrocarbon accumulations are classified as oil , gas condensate , and gas reservoirs.

Gas wells : GOR >100,000 scf/stbo Compositional model

Gas condensate wells : 5,000<GOR< 100,000 scf/stbo

Oil wells : GOR< 5,000 scf/stbo Black oil model

Black Oil Model

Gas Oil Ratio

‘‘Solution GOR’’ is defined as the amount of gas (in standard condition) that will dissolve in unit volume of oil when both are taken down to the reservoir at the prevailing pressure and temperature; that is,

R s

Gas volume in standard conditions

Oil volume in stock tank conditions standard condition is 14.7 psia and 60 o F

( scf )

( stbo )

R s remains constant at pressures above bubble-point pressure. It drops as pressure decreases in the pressure range below the bubble-point pressure.

Black Oil Model

Gas Oil Ratio

Lasater correlation (recommended for o API>15):

P ( psia

T

) g

1. Calculate o gd

( R ) g gd is sp. gr. of dissolved gas at sc.

2. Obtain y g from

Figure 2.2.

3. Obtain M o from

Figure 2.1.

4. Calculate R s

( 379 .

3 )( 350 )

M o g o

1

 y g y g

C

C is the tuning parameter (default value of C is 1.0).

Black Oil Model

Gas Oil Ratio

Standing correlation (recommended for o API<15):

Calculate

R s

 g gd

P ( psia

18

) 10

0 .

0125 o

API

10

0 .

00091 T ( o

F )

 1 .

2048

C

C is the tuning parameter (default value of C is 1.0).

Black Oil Model

Oil Formation Volume Factor

‘‘Oil formation volume factor’’ is defined as:

B o

Oil volume in reservoir conditions

Oil volume in stock tank conditions

( bbl )

( stbo )

B o is always greater than unity.

At a given reservoir temperature, B o remains nearly constant at pressures above bubble-point pressure. It drops as pressure decreases in the pressure range below the bubble point pressure.

Black Oil Model

Oil Formation Volume Factor

Standing correlation :

B o

0 .

972

0 .

000147

R s

 g g gd o



0 .

5

1 .

25 T ( o

F )

 1 .

175

C

C is the tuning parameter (default value of C is 0.0).

Res. Cond.: P, T

Free gas: m gf

(lbm)

Oil: F o

(bbl)

Density:

 o

(lbm/ft 3 )

Black Oil Model

Oil Density

Free gas: m gf

(lbm)

Dissolved gas: V gd

(scf)

Dissolved gas density:

 gd

(lbm/scf) = g gd

(0.0764)

S.C.

P =14.73 psia

T = 60 o F

Oil: L o

(stbo)

Oil density:

Lo

(lbm/scf) = g o

(62.4)

Mass Balance: m gf

5 .

614 F o

 o

 m gf

V gd

 gd

5 .

614 L o

Lo

  o

V gd

L o

5 .

614 gd

F o

5 .

614

L o

Lo   o

0 .

0136 R s g gd

B o

Fig. 2.18

62 .

4 g o

Black Oil Model

Specific Gravity of Free Gas

Gas Mass Balance:

Total produced gas at s.c. = Dissolved gas + Free gas

R p

L o

0 .

0764 g gt

R s

L o

0 .

0764 g gd

 

R p

R s

  o

0 .

0764 g gf

 g gf

R p g gt

R p

R s

R s g gd

,

0 .

56

 0 .

56

 g g gf gd

 g and gt g gt

 g gd

Where R p is the produced Gas Oil Ratio ( R p

≥ R s

).

Black Oil Model

Oil Viscosity

1- Viscosity of saturated oil (Beggs and Robinson):

A- Dead oil viscosity ( P =1.0 atm)

OD

10

X 

1 , X

10

( 3 .

0324

0 .

02023 o

API )

T

1 .

163

, T

 o

F

B- Live oil viscosity

 o

( cp )

A

B

OD

, A

R s

10 .

715

100

0 .

515

, B

R s

5 .

44

150

0 .

338

Black Oil Model

Oil Viscosity

2- Viscosity of undersaturated oil (Vazquez):

 o

  ob



P

P b

 m

, m

10

2 .

6 P

3 .

9

10

5

1 .

187

P

5 .

0

Procedure for calculating P b

:

Assume P b

= P and calculate R s

(from Standing or Lasater)

If R s

> R p the oil is undersaturated, otherwise the oil is saturated

For undersaturated oil, assume R s

= R p

Calculate P b from Standing or Lasater correlation.

Black Oil Model

Oil Viscosity

Standing Correlation:

A- Dead oil viscosity ( P =1.0 atm)

OD

 0 .

32

1 .

8

10

7 o

API

4 .

53





T

360

( o

F)

200



A

, A

10

0 .

43

8 .

33 o

API

B- Saturated oil viscosity

 o

( cp )

10 a b

0 .

68

10

8 .

62

10

5

R s

 b

OD

, a

R s

0 .

25

10

1 .

10

10

3

R s

2 .

2

10

7

R s

0 .

062

10

3 .

74

10

3

R s

7 .

4

10

4

C- Undersaturated oil viscosity

 o

  ob

0 .

001 ( P

P b

)

0 .

024

1 .

6 ob

0 .

38

0 .

56 ob

Black Oil Model

Gas-Oil Surface Tension

Baker and Swerdloff correlation:

1- Dead oil surface tension ( s

OD

): An estimate of oil surface tension at atmospheric pressure, can be obtained from

Figure 2.37

.

Note: Extrapolation beyond the temperature rang of [68 o F 100 o F] is not recommended.

2- Live oil surface tension ( s

O

): The surface tension of crude oil containing dissolved gas expressed as a percent of s

OD can be obtained from

Figure 2.38

.

Black Oil Model

Free Gas Density

1- Engineering Equation of state:

P V

 z n R T

  gf

P M gf z R T

M gf

M air g gf

  gf

P g gf

10 .

72

29 z T

  gf lbm ft

3

2 .

70 g gf

P ( psia ) z T ( o

R )

Black Oil Model

Free Gas Density

2- Gas formation volume factor ( B g

):

B g

V

V sc

 gf

 z n R T z sc n

P

R T sc

P sc

 gf sc

B g

0 .

0283 z T ( o

R )

P ( psia )

 air sc

B g g gf

  gf lbm ft

3

0 .

0764

γ gf

B g

Black Oil Model

Free Gas Compressibility Factor

1Standing and Katz

correlation: ,

pr

T pc pr

P pc

Figure 2.21

2Brill and Beggs correlation: z

A

( 1

A ) e

B 

C

D

P pr

A

1 .

39 ( T pr

0 .

92 )

0 .

5 

0 .

36 T pr

0 .

1

B

( 0 .

62

0 .

23 T pr

) P pr

T pr

0 .

066

0 .

86

0 .

037

2

P pr

0 .

32 P

6 pr

10

9 ( T p r

1 )

C

0 .

132

0 .

32 log

10

( T pr

)

D

10

( 0 .

3106

0 .

49 T p r

0 .

1824 T

2 p r

)

Black Oil Model

Free Gas Pseudocritical Properties

1Brown et al.

correlation: Figure 2.20

Valid for H

2

S < 3%, N

2

< 5%, and total content of inorganic compounds less than 7%.

P pc

( psia )

709 .

604

58 .

718 g gf

T pc

( o

R )

170 .

491

307 .

344 g gf

2Ahmed correlation:

P pc

( psia )

T pc

( o

R )

678

50 ( g gf

326

315 .

7 ( g gf

0 .

5 )

206 .

7 y

N

2

0 .

5 )

240 y

N

2

440 y

CO

2

83 .

3 y

CO

2

606 .

7 y

H

2

S

133 .

3 y

H

2

S

Black Oil Model

Free Gas Viscosity

1Carr et al. correlation:

A- Gas viscosity at atmospheric pressure (

1

): Figure 2.35

Valid for 40 < T ( o F) < 400

B- Viscosity ratio (

/

1

): Figure 2.36

Valid for 1.0 < P pr

< 20.0

C- Free gas viscosity:

 gf

( cp )



1



1

Black Oil Model

Free Gas Viscosity

2Lee et al. correlation:

 gf

( cp)

1

10

4

K exp

X

( 2 .

4

0 .

2 X gf

)

K

( 9 .

4

0 .

02 M gf

209

19 M gf

) T

T

1 .

5

X

3 .

5

Where T

986

0 .

01 M gf

T

 o

F and

 gf 

 gr cm

3 

0 .

0433 g gf

P ( psia ) z T ( o

R )

Black Oil Model

Water (Brine) Density

A- Water formation volume factor ( B w

):

Figure 2-13

B w

B w

'  y

B w

Figure 2-14

Figure 2-11

B- Water density (

 w

):

  w

 w sc

B w

Figure 2-19

Black Oil Model

Water Viscosity

A- Viscosity of pure water ( Van Wingen correlation):

 w

:

Figure 2.32

B- Viscosity of brine ( Frick correation):

 w

(cp) =

 w

’ Ratio

, Ratio :

Figure 2.33

Compositional Model

The critical properties of components that are usually found in gas

and gas condensate wells are shown in this Table

.

The components that are heavier than n-Hexane are usually shown as a pesudocomponent (C

7

+ ).

For calculating the properties of gas and gas condensate wells, the compositional model is recommended.

Many gas or gas condensate wells exhibit retrograde condensation , phenomena in which condensation occurs during pressure reduction (shaded region within the two-phase envelope of

Figure

).

Compositional Model

Flash Calculation

Free gas flowrate: V

Composition: y i

Res. Cond.: P, T

Composition: Z i for i =

1, … , n

Mole flowrate : F

Equilibrium

Flash

K i

= y i

/ x i

Condensate flowrate: L

Composition: x i

At equilibriu

By definition

Therefore m : f i v

: f i v

: K i

 y i x i f i l y i

P

 i v

,

 i l

 i v f i l  x i

P

 i l

SRK or PR

Compositional Model

Gas and Liquid Density

Once the compressibilities of each phase is determined, the gas and liquid densities can be determined from:

V

P M

V

Z

V

R T

, M

V

 i n 

1 y i

M i

L

P M

L

Z

L

R T

, M

L

 i n 

1 x i

M i

Other properties can be calculated based on the composition of liquid and gas phases ( GPSA, Engineering Data Book , 11 th edition, 1998, Chapter 23 ).

Compositional Model

Pesudocomponents

If you like to use compositional model for oil wells, the oil must defined as some pesudocomponents based on distillation curve.

There are several methods of measuring and reporting distillation curves of crude oil and petroleum fractions:

1- ASTM D 86

2- True Boiling Point (TBP)

3- Simulated Distillation by GC (ASTM D 2887)

4- Equilibrium Flash Vaporization (EFV)

5- Distillation at Reduced Pressures (ASTM D 1160)

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