Oxford High School Honors Chemistry Mr. Urig Chapter 26 HW Packet I. Name or draw the structural formulas for the following 1. Name the halocarbon with the following condensed structural formula: CH2ClCHClCH2CH3 2. Name the halocarbon with the following condensed structural formula: CH2FCHBr(CH2)4CH3 3. Name the halocarbon with the following condensed structural formula: CH2FCH2CHF(CH2)3CH3 4. Provide the condensed structural formula for 2-chlorobutane. 5. Provide the condensed structural formula for 3-bromohexane 6. Provide the condensed structural formula for 2,3-difluoropentane 7. What is the name and type of the alcohol described by the condensed structural formula CH3CHOH(CH2)6CH3 8. What is the name and type of the alcohol described by the condensed structural formula CH2OHCH(CH3)CH3 9. What is the name and type of the alcohol described by the condensed structural formula CH2OHCH2CH3 10. Provide the condensed structural formula for 4-ethyl-3-heptanol. What type of alcohol is it? 11. Provide the condensed structural formula for 2-methyl-2-butanol. What type of alcohol is it? 12. Provide the condensed structural formula for 2-heptanol. What type of alcohol is it? 13. Give the IUPAC name and common name for the ether with the following condensed structural formula: CH3OCH3 14. An ether has the IUPAC name ethoxybutane. What is its common name? 15. An ether has the IUPAC name propoxypentane. What is its common name? 16. Give the IUPAC and the common name for the ether with the following condensed structural formula: CH3CH2O(CH2)5CH3 17. Give the IUPAC and common name for the ether with the following condensed structural formula: CH3O(CH2)2CH3 18. An ether has the IUPAC name propoxyheptane. What is its common name? 19. An ether has the IUPAC name propoxypropane. What is its common name? 20. Give the IUPAC and the common name for the ether with the following condensed structural formula: CH3(CH2)2O(CH2)5CH3 21. Name the molecule represented by the following structural formula: 22. Name the molecule represented by the following condensed structural formula: CH3(CH2)5CHO 23. Name the molecule represented by the following structural formula: H O H H H C H C C C H H H 24. Name the molecule represented by the following structural formula: 25. Write the condensed structural formula for pentanal. 26. Name the molecule represented by the following condensed structural formula: CH3CH2CO(CH2)5CH3 27. Write the condensed structural formula for hexanal. 28. Name the molecule represented by the following condensed structural formula: CH3(CH2)6CHO 29. Write the condensed structural formula for 3-heptanone. 30. Name the molecule represented by the following condensed structural formula:CH3(CH2)7CHO 31. Name the carboxylic acid with the following condensed structural formula: CH3(CH2)5COOH 32. Name the carboxylic acid with the following condensed structural formula: CH3CH2CH(CH3)(CH2)2COOH 33. Name the carboxylic acid with the following condensed structural formula: CH3(CH2)2CH(CH3)(CH2)3COOH 34. Write the condensed structural formula for propanoic acid. 35. Write the condensed structural formula for octanoic acid. 36. Name the carboxylic acid with the following condensed structural formula: CH3CH(CH3)COOH 37. Name the carboxylic acid with the following condensed structural formula: CH3(CH2)3COOH 38. Write the condensed structural formula for nonanoic acid. 39. Give the IUPAC name for lactic acid, which has a condensed structural formula CH3CH(OH)COOH (Hint: use the prefix hydroxyl for the extra OH) 40. Write the condensed structural formula for decanoic acid 41. What is the name of the ester derived from the reaction between ethanol and butanoic acid? 42. What is the name of the ester derived from the reaction between propanol and pentanoic acid? 43. What is the name of the ester derived from the reaction between methanol and ethanoic acid? 44. What is the name of the ester derived from the reaction between ethanol and octanoic acid? 45. Write the condensed structural formula for butyl propanoate 46. What is the name of the ester derived from the reaction between methanol and methanoic acid? 47. Write a condensed structural formula for propyl butanoate. 48. What is the name of the ester derived from the reaction between ethanol and propanoic acid? 49. What is the name of the ester derived from the reaction between methanol and heptanoic acid? 50. What is the name of the ester derived from the reaction between butanol and pentanoic acid? 51. Name the compound CH3(CH2)7NH2 52. Name the compound CH3CH2CH(NH2)(CH2)3CH3 53. Name the compound CH3(CH2)CH(NH2)(CH2)4CH3 54. Name the compound CH3CH(NH2)CH2CH3 55. Name the compound CH3(CH2)5NH2 56. Write the condensed structural formula for 2-pentanamine 57. Write the condensed structural formula for 3-octanamine 58. Write the condensed structural formula for methanamine 59. Write the condensed structural formula for nonanamine 60. Write the condensed structural formula for 4-decanamine 61. Write the condensed structural formula for nonanamide 62. Write the condensed structural formula for 2-methylbutanamide 63. Write the condensed structural formula for octanamide 64. Write the condensed structural formula for decanamide 65. Write the condensed structural formula for 3-methylhexanamide. 66. Name the amide CH3CH2CONH2 67. Name the amide CH3(CH2)8CONH2 68. Name the amide CHONH2 69. Name the amide CH3(CH2)5CONH2 70. Name the amide CH3CH(CH3)CH2CH2CONH2 II. Matching 71. _____ hydrocarbon 72. _____ hydrocarbon derivative 73. _____ functional group 74. _____ halocarbon 75. _____ hydroxyl group 76. _____ alcohol 77. _____ ether 78. _____ diol III. 79. 80. 81. 82. 83. 84. 85. 86. 87. 88. 89. 90. 91. 92. 93. 94. 95. 96. 97. 98. 99. a. hydrocarbon in which one or more hydrogen atoms have been replaced by a halogen. b. portion of a compound that determines the properties of the hydrocarbon derivative c. hydrocarbon that contains an oxygen atom between two carbon atoms d. compound that contains additional atoms other than carbon and hydrogen e. hydrocarbon in which one or more hydrogens have been replaced by a hydroxyl group f. –OH g. compound that consists of only hydrogen and carbon h. alcohol that contains two hydroxyl groups True or False – correct false answers _____ A primary alcohol has a hydroxyl group on the interior of the hydrocarbon chain. _____ The common name for ethanol is grain alcohol. _____ Alcohols have a lower boiling points than the hydrocarbon from which they were derived. _____ A hydrocarbon in which the functional group consists of bromine is an ether. _____ Halocarbons are nonpolar. _____ Ethers have a higher boiling point than alcohols. _____ Aldehydes and ketones are less polar than hydrocarbons. _____ Aldehydes and ketones have lower melting points and boiling points than alcohols. _____Hydrocarbons have stronger intermolecular forces than aldehydes and ketones. _____ The simplest ketone is acetone. _____ Ethanol is the IUPAC name for formaldehyde. _____ The hydrogen atom in a carboxyl group is an acidic hydrogen. _____ The carboxyl end of a carboxylic acid is electron rich. _____ Carboxylic acids are less soluble in water than hydrocarbons. _____ Esters are capable of forming hydrogen bonds. _____ The simplest carboxylic acid is acetic acid. _____ The ester is formed between a carboxylic acid and a hydrocarbon. _____ Esters have lower boiling points than alcohols. _____ The boiling point of an amine is lower than the boiling point of an alcohol. _____ Amines act as strong bases. _____ Amines are less polar than alcohols. 100. 101. IV. An amide bond is also called a peptide bond. An amino group is polar. Fill in the Blank carbonyl group carboxyl group carboxylic acid organic acid fatty acid ester formic acid acetic acid 102. Another name for a carboxylic acid is __________________. 103. The functional group for a carboxylic acid is _____________________. 104. A(n) _________________ contains a hydrocarbon, rather than hydrogen, in its functional group. 105. A carboxylic acid that has been extracted from animal fat is called ___________. 106. A(n) _____________ is identified by the presence of a carboxyl group. V. Essays 107. Explain why benzoic acid is more soluble in water than octane. Use diagrams and words. 108. What gives alcohols their strong intermolecular forces? Use diagrams and words.