How do I read the equipment? What is the Volume? Reading Graduated Equipment (ie. grad cylinders, thermometers…) See skills sheet •Read one value better than the markings •Estimate between markings Measurement: 5.22 cm ________ •If on the mark, include a zero after last value recorded Measurement: 1.70 mL ________ Significant Figures (Sig Figs) Quantity includes all known digits plus one estimated digit = last digit of # Indicates precision 500 vs 500.01 Rule 1: All digits recorded from a lab measurement are called significant figures. Now the ZEROS!!!! Rule 2: All non-zero digits are considered significant. measurement 96 g 61.4 g 0.52 g number of sig figs 2 _________ 3 _________ 2 _________ Rule 3: Middle zeros are always significant. SANDWICH RULE measurement 5.029 m 306 cm 410.0 g number of sig figs 4 _________ 3 _________ 4 _________ Rule 4: A leading zero is never significant. The zeros are place holders only. measurement number of sig figs 1 .0007 g ________ 3 0.00783 kg ________ 6 5.00783 kg ________ Rule 5: Trailing zeros are significant only when to the right of decimal point. measurement number of sig figs 3 47200 km ________ 5 4.7200 km ________ 3 82.0 m ________ 820. M _________ Rule 6: All significant figures include units. Rule 7: All numbers multiplied by 10 in scientific notation are considered significant. measurement number of sig figs 4 3.600 x 103 m _________ 3 1.02 x 10-9 g _________ SAME RULES: SHORT CUT “The Arrow Rule”: Draw an arrow to the first significant digit and count significant figures. Atlantic Ocean Pacific Ocean decimal Present measurement decimal Absent # sig figs measurement # sig figs 61.4 g ____ 3 306 cm ____ 3 0.52 g 2 ____ 7 000 g 1 ____ 82.0 m 3 ____ 5 50 002 pennies ____ 3 0.00783 kg ____ Practice: how many sig figs in each quantity? 45.35 km 6.2100 dag 1.22 us 8 000 000 m/s 0.034567 ML 4 5 3 1 5 # of sig figs in answer is based on # sig figs in least precise measurement Which is the least precise, 7.22 m or 7.22555 m? _______ 7.22 m Rules for multiplication and division: 1) Count the # of sig figs in each measurement. 2) Use least # sig figs for # of digits in answer. Examples: 4.5 cm X 2.54 cm X 3.215 cm = 36.74745 37 cm3 answer w/ sig figs ______________ 4.62 g = 0.308 g/cm3 15.00 cm3 0.308 g/cm3 answer w/ sig figs __________ 2 2.124 mm X 65mm = 138.06 mm answer w/ sig figs _____________________________ 140 mm2 or 1.4 x 102 mm2 Data Analysis Accuracy & Precision “Numerical precision is the very soul of science.” Precision How reproducible (repeatable) how consistently that measurement is made Smaller the range = more precise To find Precision calculate percent error. % error = Avg experimental – accepted Value value Accepted value x 100 Which is most precise? …least precise? most least Most precise instrument for liquid volume measurement Volumetric flask Which is most precise? Equipment had markings every 2 or more mL 19 ml Equipment had markings every 1 mL 19.5 ml 19.50 ml Equipment had markings every 0.1 mL Estimated digit More digits means more divisions (markings on the equipment) Find % error Average = 3.8 Accepted = 2.2 % error = [3.8 - 2.2] x 100 2.2 = 73% Accuracy How close to the correct value (accepted value) To find accuracy, compare average to accepted value Sum of experimental values Average = # of values Which set of values is more accurate if 7.6 is correct? Set One 7.0 Avg = 8.3 8.1 9.8 Set Two 6.3 8.0 7.9 Avg = 7.4 Which ones are precise? #1 Precise #2 Precise #3 NOT Precise Which ones are accurate? #1 #2 #3 Accurate NOT accurate NOT accurate & precise But precise Or precise! Which one is the most precise? a b c Which one is the most accurate? Need to know how long a real meter is! Try this one! Trial 1 Trial 2 Trial 3 Average Range % error Actual Density Density 3.6 g/ml 4.1 g/ml 3.8 g/ml 3.8 g/ml 3.6 to 4.1 73% 2.2 g/ml Data Analysis cont NUMBERS “Numerical precision is the very soul of science.” SCIENTIFIC NOTATION EASY, right? Change to sci not: Diam of the sun: 1,392,000 km 1.392 x 106 km Density of sun’s atoms: 0.000000028 g/cm3 2.8 x 10-8 g/cm3 Change back: 1.7 x 10-7 kg -2.6 x 105 m 0.00000017 kg -260,000 m Rules for Scientific Notation Move the decimal so that only one nonzero digit is to the left of decimal No non-significant zeros at end or before nonzero digits Remember sig figs Multiply by 10n where n = # places moved – – n is + when decimal moves left (into sci not) n is - when decimal moves right (into sci not) Quantity SI Base Units can be measured – A number AND a unit! UNITS ARE IMPORTANT!!!!!!!!!!! SI Units (Systeme Internationale d’Unites) are standard – Time = second = s Length = meter = m Mass = kilogram= kg Temp = kelvin = K “Which one of these is not like the others?” Conversions btw. Units M Secret Worlds: The Universe Within k h dk BASE d c m (compared to base unit) BASE X 109 = giga = G BASE X 106 = mega = M BASE X 103 = kilo = k BASE X 10-2 = centi = c BASE X 10-3 = milli = m BASE X 10-6 = micro = BASE X 10-9 = nano = n BASE X 10-12 = pico = p n p Give an example of something that would best be measured using each prefix + grams and meters. 5 x 10-2 Ex: 5 cm = ______m_ Derived Units 1 cm3 What is mL = _______? formed by a combination of units 1 dm3 = 1 L Density = mass = g = g volume cm3 L 1L 1 mL Factor Label Conversion AKA Dimensional Analysis Conversion factor – 2 quantities that are equal to each other and arranged as a fraction When Converting using factor labels Start with what you are given Always write your units Denominator is unit trying to get rid of Numerator is unit trying to change to Cross units out as they divide & cancel out Example 12 inches = 1 foot Conversion factors = 12 in 1 ft •How many inches are in 15 feet? 12 in 15 ft Or = 180 in x 1 ft 1 ft 12 in Example #2 Butterfly wings: 1 wing has a mass of 00.56g Conversion factors: If you pulled the wings off of 28 butterflies, what will be the total mass of wings you have. (more than 1 step?)