Chapter 10 States of Matter Section 1: The Kinetic-Molecular Theory of Matter Standard 4.b. Students know the random motion of molecules explains the diffusion of gases. Objectives We will list the five assumptions of the kinetic- molecular theory of gases and describe the properties of gases. KMT This is based on the idea that particles of matter are always in motion. How it relates to gases: Ideal gas = a hypothetical gas that perfectly fits all the assumptions of KMT. No ideal gas actually exists; but some do come close. 5 Assumptions Gases consist of large numbers of tiny particles that are far apart relative to their size. Collisions between gas particles and between particles and container walls are elastic collisions (no net loss of total kinetic energy) Gas particles are in continuous, rapid, random motion. Thus, they have kinetic energy. 5 Assumptions Cont. There are no forces of attraction between gas particles. This is why they have no set shape The temperature of the gas depends on the average kinetic energy of the particles of the gas. Standard 4.b. Students know the random motion of molecules explains the diffusion of gases. Objectives We will list the five assumptions of the kinetic- molecular theory of gases and describe the properties of gases. Properties of Gases No definite shape Can be compressed No definite volume smaller Diffusion Effusion Ability to flow (fluid) Low density Real Gases A gas that does not behave completely according to the assumptions of KMT. Noble gases and non-polar diatomic gases behave most like an ideal gas, as well as gases at high temperatures and low pressures. Standard 4.b. Students know the random motion of molecules explains the diffusion of gases. Objectives We will list the five assumptions of the kinetic- molecular theory of gases and describe the properties of gases. Section 2 & 3: Liquids and Solids Standard 4.a. Students know the random motion of molecules and their collisions with a surface create the observable pressure on that surface. Objectives We will describe the properties of liquids and discuss the processes of how liquids change. We will describe the properties of solids and distinguish between the two types of solids. Properties of Liquids No definite shape Surface tension Higher density Evaporation Mostly incompressible Boiling so definite volume Diffusion Can form solids Properties of Solids Definite shape High density Definite volume Incompressible Defined melting Low rate of point diffusion Types of Solids Crystalline Solids: exist as single crystals or groups of crystals fused together. Ionic Crystals Covalent Network Crystals Metallic Crystals Covalent Molecular Crystals Types of Solids Amorphous Solids: are not arranged in a regular pattern. Glass and Plastic Standard 4.a. Students know the random motion of molecules and their collisions with a surface create the observable pressure on that surface. Objectives We will describe the properties of liquids and discuss the processes of how liquids change. We will describe the properties of solids and distinguish between the two types of solids. Chapter 10.4 Changes of State Standard 7.c. Students know energy is released when a material condenses or freezes & is absorbed when a material evaporates or melts. Objectives We will describe the processes that occur to cause a change of state. We will interpret phase diagrams. Matter on earth can exist in any state— gas, liquid, or solid—and can change from one state to another. Energy and Changes of State When a substance changes from one state to another, energy is always involved. The change will either be exothermic (releases heat) or endothermic (absorbs heat). Changes of State Change of State Process Example SolidLiquid Melting IceWater SolidGas Sublimation Dry IceCO2 LiquidSolid Freezing WaterIce LiquidGas Vaporization WaterSteam GasSolid Deposition SteamIce GasLiquid Condensation SteamWater Endo or Exo? Standard 7.c. Students know energy is released when a material condenses or freezes & is absorbed when a material evaporates or melts. Objectives We will describe the processes that occur to cause a change of state. We will interpret phase diagrams. Phase Diagrams Phase Diagram: a graph of pressure versus temperature that shows the conditions under which the phases of a substance exist. Tells you what state a substance will be in at a certain temperature and pressure. Triple point: the temperature and pressure conditions at which the three phases can coexist at equilibrium Critical Point: the highest temperature and pressure that a substance can exist as a liquid. Critical Temperature: the temperature above which the substance cannot exist as a liquid. Critical Pressure: the lowest pressure at which the substance can exist as a liquid. Name that state… Temperature Pressure 70°C 2.0 atm 100°C 0.5 atm 0°C 1.0 atm State Name that state… Temperature Pressure State 70°C 2.0 atm Liquid 100°C 0.5 atm Gas 0°C 1.0 atm Solid Standard 7.c. Students know energy is released when a material condenses or freezes & is absorbed when a material evaporates or melts. Objectives We will describe the processes that occur to cause a change of state. We will interpret phase diagrams. Homework Pg 332 #2, 3 Pg 336 #4, 5 Pg 341 #2 Pg 348 #6 Chapter 10.5 Water Standard 7.c. Students know energy is released when a material condenses or freezes & is absorbed when a material evaporates or melts. Objectives We will describe the structure of the water molecule and its properties. We will calculate the amount of energy absorbed or released when water changes state. Structure of Water Recall: Water has 2 Hydrogen and 1 Oxygen and has a bent structure. Ice forms a hexagonal pattern Look at Fig 19 on pg 350 The empty spaces result in ices low density and are why it floats. Properties of Water Pure water is transparent, odorless, tasteless and almost colorless. Any odor or taste is caused by impurities. Water freezes and ice melts at 0°C and 1 atm. Molar enthalpy of fusion is 6.009 kJ/mol Water boils at 100°C and 1 atm. Molar enthalpy of vaporization is 40.79 kJ/mol Going from ice to water requires energy. Going from water to ice releases energy. Going from water to steam requires energy. Going from steam to water releases energy. The amount of energy is the same, it is just either required or released. Standard 7.c. Students know energy is released when a material condenses or freezes & is absorbed when a material evaporates or melts. Objectives We will describe the structure of the water molecule and its properties. We will calculate the amount of energy absorbed or released when water changes state. Calculating Amount of Energy What quantity of energy is released when 804 g of water vapor condenses? Convert from grams to moles Multiply moles by 40.79 kJ/mol (Vaporization) Moles cancel out, units are kJ Answer = 1820 kJ Calculating Mass from Energy What mass of ice is required to release 2000 kJ of energy when melting? Divide kJ by 6.009 kJ/mol (fusion) kJ cancel out so you have moles. Convert moles to grams. Answer = 6000 g H2O Standard 7.c. Students know energy is released when a material condenses or freezes & is absorbed when a material evaporates or melts. Objectives We will describe the structure of the water molecule and its properties. We will calculate the amount of energy absorbed or released when water changes state. Homework Pg 351 #4, 6 and practice problem #1, 2